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US3896045A Expired / Lapsed US ⏱️ 0.0 years remaining

Decontamination process for radio-active liquids

Assignee: Belgonucleaire SA
•
Filing: 1972-12-21
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Granted: 1975-07-22
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Expires: 1992-12-21
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Abstract

Abstract Radio-active liquids and the products thereof are decontaminated by contacting the radio-active liquid with a sorbent in a sulfate-containing medium selected from the group consisting of a barium salt and a barium salt mixed with up to 50 percent of a metal ferrocyanide.

Inventors

  • 👤 Karel J A Peeters
  • 👤 De Voorde Norbert L C Van

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 04:22
CPC Classifications
G; G21; G21F; G21F9/00; G21F9/04; G21F9/06; G21F9/12

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 53 words
A METHOD FOR EXTRACTING RADIOACTIVE IONS PRESENT IN TRACER QUANTITIES FROM A CONTAMINATED LIQUID WHICH COMPRISES CONTACTING SAID LIQUID WITH A MIXED SORBENT OF AN INSOLUBLE BARIUM SALT SELECTED FROM THE GROUP CONSISTING OF BARIUM SULFATE AND BARIUM CARBONATE, MIXED WITH UP TO 50 PERCENT OF A METAL FERROCYANIDE IN A SULFATE-CONTAINING MEDIUM.
Claim 2
Independent Claim 53 words
A METHOD FOR EXTRACTING RADIOACTIVE IONS PRESENT IN TRACER QUANTITIES FROM A CONTAMINATED LIQUID WHICH COMPRISES CONTACTING SAID LIQUID WITH A MIXED SORBENT OF AN INSOLUBLE BARIUM SALT SELECTED FROM THE GROUP CONSISTING OF BARIUM SULFATE AND BARIUM CARBONATE, MIXED WITH UP TO 50 PERCENT OF A METAL FERROCYANIDE IN A SULFATE-CONTAINING MEDIUM.
Claim 3
Dependent Claim 24 words
The method of claim 1 wherein the barium salt is barium sulfate and has a ratio of 3 barium ions to 1 sulfate ion.
Claim 4
Dependent Claim 33 words
The method of claim 1 wherein sodium nitrate is added to the barium sulfate in an amount such that the resulting mixture has 1 sodium ion for from 1 to 24 barium ions.
Claim 5
Dependent Claim 16 words
The method of claim 1 wherein said mixed sorbent contains at least 2 percent metal ferrocyanide.
Claim 6
Dependent Claim 21 words
The method of claim 4 wherein the metal ferrocyanide is copper ferrocyanide, manganese ferrocyanide, cobalt ferrocyanide, nickel ferrocyanide or zinc ferrocyanide.
Claim 7
Dependent Claim 33 words
The method of claim 5 wherein the sorbent is from 85-98 percent barium salt which has an excess of barium cations And from 15-2 percent of a metal ferrocyanide in a sulfate-containing medium.
Claim 8
Dependent Claim 46 words
The method of claim 5 wherein said barium salt is barium sulfate having a ratio of 3 barium ions to 1 sulfate ion, and wherein said metal ferrocyanide is copper ferrocyanide having a ratio of 1 copper ion to 1 ferrocyanide ion in a sulfate-containing medium.
Claim 9
Dependent Claim 19 words
The method of claim 6 wherein said mixed sorbent is barium carbonate and copper ferrocyanide in a sulfate-containing medium.
Claim 10
Dependent Claim 30 words
The method of claim 4 wherein said mixed sorbent additionally contains sodium nitrate in an amount such that there is one sodium ion for from 1 to 24 barium ions.
Claim 11
Dependent Claim 30 words
The method of claim 4 wherein said mixed sorbent additionally contains calcium chloride in an amount such that there is 1 calcium ion for from 1 to 20 barium ions.
Claim 12
Dependent Claim 16 words
The method of claim 4 wherein at least 90% of the mixed sorbent is barium carbonate.
Claim 13
Dependent Claim 23 words
The method of claim 1 wherein the contaminated liquids are the regeneration liquids from an ion exchanger previously used for decontaminating radioactive effluents.
Claim 14
Dependent Claim 23 words
The method of claim 4 wherein the contaminated liquids are the regeneration liquids from an ion exchanger previously used for decontaminating radioactive effluents.

References Cited (Backward Citations)

US2766204A Cited
US2769780A Cited
US2952640A Cited
US3013978A Cited
US3128247A Cited
US3449065A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-07-21 1979-01-20 1979-07-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-07-21 1983-01-20 1983-07-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-07-21 1987-01-20 1987-07-22 $7700.00 Window Closed / Lapsed

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