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US3893935A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrographic toner and developer composition

Assignee: Organization World Intellectual Property
•
Filing: 1973-09-20
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Granted: 1975-07-08
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Expires: 1993-09-20
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Abstract

Abstract The present invention relates to the use of certain quaternary ammonium salts as useful charge control agents for an electrostatic toner composition.

Inventors

  • 👤 Thomas A Jadwin
  • 👤 Alec N Mutz
  • 👤 Bruce J Rubin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:58
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/097; G03G9/09733; G03G9/09741

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 31 words
A DRY PARTICULATE ELECTROSCOPIC TONER COMPOSITION FOR USE IN DEVELOPING ELECTROSTATIC CHARGE PATTERNS COMPRISING FINELYDIVIDED PARTICLES COMPRISING A RESIN INCORPORATED THEREIN A QUATERNARY AMMONIUM CHARGE CONTROL AGENT HAVING THE FOLLOWING FORMULA:
Claim 2
Dependent Claim 31 words
A DRY PARTICULATE ELECTROSCOPIC TONER COMPOSITION FOR USE IN DEVELOPING ELECTROSTATIC CHARGE PATTERNS COMPRISING FINELYDIVIDED PARTICLES COMPRISING A RESIN INCORPORATED THEREIN A QUATERNARY AMMONIUM CHARGE CONTROL AGENT HAVING THE FOLLOWING FORMULA:
Claim 3
Dependent Claim 64 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles having a particle size of from about 0.1 micron to about 100 microns, said particles comprising a resin having a melting point within the range of from about 65* to about 200*C. and having incorporated in said resin a quaternary ammonium charge control agent having the following formula:
Claim 4
Dependent Claim 64 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles having a particle size of from about 0.1 micron to about 100 microns, said particles comprising a resin having a melting point within the range of from about 65* to about 200*C. and having incorporated in said resin a quaternary ammonium charge control agent having the following formula:
Claim 5
Dependent Claim 26 words
The invention as described in claim 2 wherein said toner composition comprises a pigment or a dyestuff in an amount effective to color said toner composition.
Claim 6
Dependent Claim 79 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles having a particle size of from about 1.0 to about 30 microns, said particles comprising a styrene-containing resin having a melting point within the range of from about 65*C. to about 120*C. and having incorporated in said resin (a) a pigment or dyestuff in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 7
Dependent Claim 79 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles having a particle size of from about 1.0 to about 30 microns, said particles comprising a styrene-containing resin having a melting point within the range of from about 65*C. to about 120*C. and having incorporated in said resin (a) a pigment or dyestuff in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 8
Dependent Claim 43 words
The invention as described in claim 4 wherein R1, R2, R3 and R4 represent an alkyl group having from 1 to about 7 carbon atoms and wherein X is an anionic function selected from the group consisting of halides, phosphates, acetates and nitrates.
Claim 9
Dependent Claim 32 words
The invention as described in claim 4 wherein R1, R2, R3, and R4 are straight-chain alkyl groups having from about 3 to about 7 carbon atoms and wherein X is a halide.
Claim 10
Dependent Claim 32 words
The invention as described in claim 4 wherein R1, R2, R3, and R4 are straight-chain alkyl groups having from about 3 to about 7 carbon atoms and wherein X is a chloride.
Claim 11
Dependent Claim 77 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles of from about 0.1 micron to about 100 microns, said particles comprising a polycarbonate-containing resin having a glass transition temperature within the range of from about 60*C. to about 120*C. and having incorporated in said resin (a) a dyestuff or pigment in an amount effective to color said resin and (b) a quaternary ammoniUm charge control agent having the following formula:
Claim 12
Dependent Claim 77 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles of from about 0.1 micron to about 100 microns, said particles comprising a polycarbonate-containing resin having a glass transition temperature within the range of from about 60*C. to about 120*C. and having incorporated in said resin (a) a dyestuff or pigment in an amount effective to color said resin and (b) a quaternary ammoniUm charge control agent having the following formula:
Claim 13
Dependent Claim 43 words
The invention as described in claim 8 wherein R1, R2, R3 and R4 represent an aliphatic group having from 1 to about 7 carbon atoms and wherein X is an anionic function selected from the group consisting of halides, phosphates, acetates and nitrates.
Claim 14
Dependent Claim 32 words
The invention as described in claim 8 wherein R1, R2, R3 and R4 represent an alkyl group having from about 3 to about 7 carbon atoms and wherein X is a halide.
Claim 15
Dependent Claim 146 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles of from about 1.0 to about 30 microns, said particles comprising a styrene-containing resin having a melting point within the range of from about 65*C. to about 120*C., said resin containing from about 40 to about 100 percent by weight of styrene units, from 0 to about 45 percent by weight of alkyl acrylate or alkyl methacrylate units having from 1 to about 3 carbon atoms in the alkyl moiety, and from about 5 to about 50 percent by weight of alkyl acrylate or alkyl methacrylate units having from about 6 to about 20 carbon atoms in the alkyl moiety, said resin having incorporated therein (a) a pigment or dyestuff in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 16
Dependent Claim 146 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles of from about 1.0 to about 30 microns, said particles comprising a styrene-containing resin having a melting point within the range of from about 65*C. to about 120*C., said resin containing from about 40 to about 100 percent by weight of styrene units, from 0 to about 45 percent by weight of alkyl acrylate or alkyl methacrylate units having from 1 to about 3 carbon atoms in the alkyl moiety, and from about 5 to about 50 percent by weight of alkyl acrylate or alkyl methacrylate units having from about 6 to about 20 carbon atoms in the alkyl moiety, said resin having incorporated therein (a) a pigment or dyestuff in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 17
Dependent Claim 43 words
The invention as described in claim 11 wherein R1, R2, R3 and R4 represent an aliphatic group having from 1 to about 7 carbon atoms and wherein X is an anionic function selected from the group consisting of halides, acetates, phosphates, and nitrates.
Claim 18
Dependent Claim 16 words
The invention as described in claim 11 wherein said particles contain carbon black as a pigment.
Claim 19
Dependent Claim 32 words
The invention as described in claim 11 wherein R1, R2, R3 and R4 represent an alkyl group having from about 3 to about 7 carbon atoms and wherein X is a halide.
Claim 20
Dependent Claim 21 words
An electrographic developing composition comprising particulate magnetic carrier particles having electrostatically attractable thereto a toner composition as described in claim 1.
Claim 21
Dependent Claim 97 words
An electrographic developer composition comprising ferromagnetic carrier particles having a particle size within the range of from about 30 to about 1200 microns and having electrostatically attractable thereto dry, finely-divided toner particles having a particle size within the range of about 1.0 to about 30 microns, said toner particles comprising a resin having a melting point within the range of from about 65* to about 200*C. and having incorporated in said resin (a) a dyestuff or pigment in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 22
Dependent Claim 97 words
An electrographic developer composition comprising ferromagnetic carrier particles having a particle size within the range of from about 30 to about 1200 microns and having electrostatically attractable thereto dry, finely-divided toner particles having a particle size within the range of about 1.0 to about 30 microns, said toner particles comprising a resin having a melting point within the range of from about 65* to about 200*C. and having incorporated in said resin (a) a dyestuff or pigment in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 23
Dependent Claim 38 words
The invention as described in claim 16 wherein said resin is a styrene-containing resin having a melting point within the range of about 65* to about 120*C. and wherein said toner particles comprise carbon black as a pigment.
Claim 24
Dependent Claim 40 words
The invention as described in claim 16 wherein said resin is a poly(carbonate)-containing resin having a glass transition temperature within the range of from about 60* to about 120*C. and wherein said toner particles comprise carbon black as a pigment.

References Cited (Backward Citations)

US3320169A Cited
US3565654A Cited
US3502582A Cited
US3647696A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-07-07 1979-01-06 1979-07-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-07-07 1983-01-06 1983-07-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-07-07 1987-01-06 1987-07-08 $7700.00 Window Closed / Lapsed

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