US3893935A
Expired / Lapsed
US
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Electrographic toner and developer composition
Assignee: Organization World Intellectual Property
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Filing: 1973-09-20
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Granted: 1975-07-08
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Expires: 1993-09-20
Abstract
Abstract The present invention relates to the use of certain quaternary ammonium salts as useful charge control agents for an electrostatic toner composition.
Inventors
- 👤 Thomas A Jadwin
- 👤 Alec N Mutz
- 👤 Bruce J Rubin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 11:58
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/097; G03G9/09733; G03G9/09741
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
31 words
A DRY PARTICULATE ELECTROSCOPIC TONER COMPOSITION FOR USE IN DEVELOPING ELECTROSTATIC CHARGE PATTERNS COMPRISING FINELYDIVIDED PARTICLES COMPRISING A RESIN INCORPORATED THEREIN A QUATERNARY AMMONIUM CHARGE CONTROL AGENT HAVING THE FOLLOWING FORMULA:
Claim 2
Dependent Claim
31 words
A DRY PARTICULATE ELECTROSCOPIC TONER COMPOSITION FOR USE IN DEVELOPING ELECTROSTATIC CHARGE PATTERNS COMPRISING FINELYDIVIDED PARTICLES COMPRISING A RESIN INCORPORATED THEREIN A QUATERNARY AMMONIUM CHARGE CONTROL AGENT HAVING THE FOLLOWING FORMULA:
Claim 3
Dependent Claim
64 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles having a particle size of from about 0.1 micron to about 100 microns, said particles comprising a resin having a melting point within the range of from about 65* to about 200*C. and having incorporated in said resin a quaternary ammonium charge control agent having the following formula:
Claim 4
Dependent Claim
64 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles having a particle size of from about 0.1 micron to about 100 microns, said particles comprising a resin having a melting point within the range of from about 65* to about 200*C. and having incorporated in said resin a quaternary ammonium charge control agent having the following formula:
Claim 5
Dependent Claim
26 words
The invention as described in claim 2 wherein said toner composition comprises a pigment or a dyestuff in an amount effective to color said toner composition.
Claim 6
Dependent Claim
79 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles having a particle size of from about 1.0 to about 30 microns, said particles comprising a styrene-containing resin having a melting point within the range of from about 65*C. to about 120*C. and having incorporated in said resin (a) a pigment or dyestuff in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 7
Dependent Claim
79 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles having a particle size of from about 1.0 to about 30 microns, said particles comprising a styrene-containing resin having a melting point within the range of from about 65*C. to about 120*C. and having incorporated in said resin (a) a pigment or dyestuff in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 8
Dependent Claim
43 words
The invention as described in claim 4 wherein R1, R2, R3 and R4 represent an alkyl group having from 1 to about 7 carbon atoms and wherein X is an anionic function selected from the group consisting of halides, phosphates, acetates and nitrates.
Claim 9
Dependent Claim
32 words
The invention as described in claim 4 wherein R1, R2, R3, and R4 are straight-chain alkyl groups having from about 3 to about 7 carbon atoms and wherein X is a halide.
Claim 10
Dependent Claim
32 words
The invention as described in claim 4 wherein R1, R2, R3, and R4 are straight-chain alkyl groups having from about 3 to about 7 carbon atoms and wherein X is a chloride.
Claim 11
Dependent Claim
77 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles of from about 0.1 micron to about 100 microns, said particles comprising a polycarbonate-containing resin having a glass transition temperature within the range of from about 60*C. to about 120*C. and having incorporated in said resin (a) a dyestuff or pigment in an amount effective to color said resin and (b) a quaternary ammoniUm charge control agent having the following formula:
Claim 12
Dependent Claim
77 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles of from about 0.1 micron to about 100 microns, said particles comprising a polycarbonate-containing resin having a glass transition temperature within the range of from about 60*C. to about 120*C. and having incorporated in said resin (a) a dyestuff or pigment in an amount effective to color said resin and (b) a quaternary ammoniUm charge control agent having the following formula:
Claim 13
Dependent Claim
43 words
The invention as described in claim 8 wherein R1, R2, R3 and R4 represent an aliphatic group having from 1 to about 7 carbon atoms and wherein X is an anionic function selected from the group consisting of halides, phosphates, acetates and nitrates.
Claim 14
Dependent Claim
32 words
The invention as described in claim 8 wherein R1, R2, R3 and R4 represent an alkyl group having from about 3 to about 7 carbon atoms and wherein X is a halide.
Claim 15
Dependent Claim
146 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles of from about 1.0 to about 30 microns, said particles comprising a styrene-containing resin having a melting point within the range of from about 65*C. to about 120*C., said resin containing from about 40 to about 100 percent by weight of styrene units, from 0 to about 45 percent by weight of alkyl acrylate or alkyl methacrylate units having from 1 to about 3 carbon atoms in the alkyl moiety, and from about 5 to about 50 percent by weight of alkyl acrylate or alkyl methacrylate units having from about 6 to about 20 carbon atoms in the alkyl moiety, said resin having incorporated therein (a) a pigment or dyestuff in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 16
Dependent Claim
146 words
A dry particulate electroscopic toner composition for use in developing electrostatic charge patterns comprising finely-divided particles of from about 1.0 to about 30 microns, said particles comprising a styrene-containing resin having a melting point within the range of from about 65*C. to about 120*C., said resin containing from about 40 to about 100 percent by weight of styrene units, from 0 to about 45 percent by weight of alkyl acrylate or alkyl methacrylate units having from 1 to about 3 carbon atoms in the alkyl moiety, and from about 5 to about 50 percent by weight of alkyl acrylate or alkyl methacrylate units having from about 6 to about 20 carbon atoms in the alkyl moiety, said resin having incorporated therein (a) a pigment or dyestuff in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 17
Dependent Claim
43 words
The invention as described in claim 11 wherein R1, R2, R3 and R4 represent an aliphatic group having from 1 to about 7 carbon atoms and wherein X is an anionic function selected from the group consisting of halides, acetates, phosphates, and nitrates.
Claim 18
Dependent Claim
16 words
The invention as described in claim 11 wherein said particles contain carbon black as a pigment.
Claim 19
Dependent Claim
32 words
The invention as described in claim 11 wherein R1, R2, R3 and R4 represent an alkyl group having from about 3 to about 7 carbon atoms and wherein X is a halide.
Claim 20
Dependent Claim
21 words
An electrographic developing composition comprising particulate magnetic carrier particles having electrostatically attractable thereto a toner composition as described in claim 1.
Claim 21
Dependent Claim
97 words
An electrographic developer composition comprising ferromagnetic carrier particles having a particle size within the range of from about 30 to about 1200 microns and having electrostatically attractable thereto dry, finely-divided toner particles having a particle size within the range of about 1.0 to about 30 microns, said toner particles comprising a resin having a melting point within the range of from about 65* to about 200*C. and having incorporated in said resin (a) a dyestuff or pigment in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 22
Dependent Claim
97 words
An electrographic developer composition comprising ferromagnetic carrier particles having a particle size within the range of from about 30 to about 1200 microns and having electrostatically attractable thereto dry, finely-divided toner particles having a particle size within the range of about 1.0 to about 30 microns, said toner particles comprising a resin having a melting point within the range of from about 65* to about 200*C. and having incorporated in said resin (a) a dyestuff or pigment in an amount effective to color said resin and (b) a quaternary ammonium charge control agent having the following formula:
Claim 23
Dependent Claim
38 words
The invention as described in claim 16 wherein said resin is a styrene-containing resin having a melting point within the range of about 65* to about 120*C. and wherein said toner particles comprise carbon black as a pigment.
Claim 24
Dependent Claim
40 words
The invention as described in claim 16 wherein said resin is a poly(carbonate)-containing resin having a glass transition temperature within the range of from about 60* to about 120*C. and wherein said toner particles comprise carbon black as a pigment.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-07-07 | 1979-01-06 | 1979-07-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-07-07 | 1983-01-06 | 1983-07-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-07-07 | 1987-01-06 | 1987-07-08 | $7700.00 | Window Closed / Lapsed |