US3891722A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for manufacture of impact-resistant polymerizates of olefinic nitriles and diene rubbers
Assignee: Standard Oil Co
•
Filing: 1970-02-16
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Granted: 1975-06-24
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Expires: 1990-02-16
Abstract
Abstract Impact-resistant polymers having low permeability to gases and vapors are prepared by polymerizing an olefinic nitrile, such as acrylonitrile, optionally with an olefinic ester, such as ethyl acrylate, or a monoolefin, such as isobutylene, in an aqueous medium in the presence of a diene rubber using a delayed addition of polymer modifier to the polymerization medium.
Inventors
- 👤 William J Miloscia
- 👤 John J Weisz
- 👤 Paul E Planz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 08:42
CPC Classifications
C; C08; C08F; C08F236/00; C08F236/02; C08F236/04; C08F279/00; C08F279/02; C08F36/00
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
52 words
IN THE PROCESS FOR PREPARING AN IMPACT-RESISTANT RESINOUS POLYMER COMPRISING POLYMERIZING IN AN AQUEOUS MEDIUM IN THE SUBSTANTIAL ABSENCE OF OXYGEN AND IN THE PRESENCE OF A POLYMERIZATION INITATOR AND A POLYMER MODIFIER 100 PARTS BY WEIGHT OF A. AT LEAST 50% BY WEIGHT OF AT LEAST ONE NITRILE HAVING THE STRUCTURE
Claim 2
Dependent Claim
52 words
IN THE PROCESS FOR PREPARING AN IMPACT-RESISTANT RESINOUS POLYMER COMPRISING POLYMERIZING IN AN AQUEOUS MEDIUM IN THE SUBSTANTIAL ABSENCE OF OXYGEN AND IN THE PRESENCE OF A POLYMERIZATION INITATOR AND A POLYMER MODIFIER 100 PARTS BY WEIGHT OF A. AT LEAST 50% BY WEIGHT OF AT LEAST ONE NITRILE HAVING THE STRUCTURE
Claim 3
Dependent Claim
5 words
AN ESTER HAVING THE STRUCTURE
Claim 4
Dependent Claim
5 words
AN ESTER HAVING THE STRUCTURE
Claim 5
Dependent Claim
12 words
The process of claim 1 wherein the nitrile is acrylonitrile or methacrylonitrile.
Claim 6
Dependent Claim
5 words
an alpha-olefin having the structure
Claim 7
Dependent Claim
5 words
an alpha-olefin having the structure
Claim 8
Dependent Claim
5 words
AN ALPHA-OLEFIN HAVING THE STRUCTURE
Claim 9
Dependent Claim
5 words
AN ALPHA-OLEFIN HAVING THE STRUCTURE
Claim 10
Dependent Claim
14 words
The process of claim 2 wherein the ester is methyl acrylate or methyl methacrylate.
Claim 11
Dependent Claim
11 words
The process of claim 3 wherein the conjugated diene is butadiene.
Claim 12
Dependent Claim
42 words
The process of claim 4 wherein the polymer modifier is a member selected from the group consisting of primary, secondary, and tertiary alkyl mercaptans containing from 4 to 16 carbon atoms, limonene dimercaptan and the tetra ester of pentaerythritol and beta-mercapto-propionic acid.
References Cited (Backward Citations)
US3428712A
Cited
US3426102A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-06-23 | 1978-12-23 | 1979-06-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-06-23 | 1982-12-23 | 1983-06-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-06-23 | 1986-12-23 | 1987-06-24 | $7700.00 | Window Closed / Lapsed |