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US3888943A Expired / Lapsed US ⏱️ 0.0 years remaining

Powder coating compositions comprising a blend of coreactive polymers - i

Assignee: EIDP Inc
•
Filing: 1973-12-19
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Granted: 1975-06-10
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Expires: 1993-12-19
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Abstract

Abstract Powder coating compositions are dissolved which comprise a blend of qualitatively-monofunctional, quantitatively-polyfunctional, coreactive copolymers. One polymer of the blend is an epoxyfunctional copolymer of about 5 to about 20 weight percent of a glycidyl ester of a monoethylenically unsaturated acid and about 80 to about 95 weight percent of monoethylenically unsaturated, quantitatively and qualitatively-monofunctional monomers. The second polymer of the blend is a copolymer of about 5 to about 20 weight percent of an anhydride of an olefinically-unsaturated dicarboxylic acid and about 80 to 95 weight percent of monoethylenically unsaturated, quantitatively and qualitativelymonofunctional monomers. The epoxy-functional copolymer and the anhydride-functional copolymer are blended in such proportions as to provide about 0.4 to about 1 anhydride group per epoxy group.

Inventors

  • 👤 Santokh S Labana
  • 👤 Ares N Theodore

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 02:59
CPC Classifications
C; C09; C09D; C09D163/00; C09D133/00; C09D133/04; C09D133/06; C09D133/062; C09D133/068; C08; C08L; C08L33/00; C08L33/04; C08L33/06; C08L33/062; C08L33/064; Y; Y10; Y10S; Y10S260/00; Y10S260/15; Y10S260/16; Y10S260/17; Y10S260/19; Y10S525/00; Y10S525/913

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 19 words
A THERMOSETTABLE POWDER COATING COMPRISING WHICH EXCLUSIVE OF PIGMENTS AND OTHER NON-REACTIVE COMPONENTS COMPRISES OF A COREACTIVE MIXTURE OF
Claim 2
Dependent Claim 19 words
A THERMOSETTABLE POWDER COATING COMPRISING WHICH EXCLUSIVE OF PIGMENTS AND OTHER NON-REACTIVE COMPONENTS COMPRISES OF A COREACTIVE MIXTURE OF
Claim 3
Dependent Claim 59 words
EPOXY-FUNCTIONAL COPOLYMER OF ABOUT 5 TO ABOUT 20 WEIGHT PERCENT OF A GLYCIDYL ESTER OF A MONOETHYLENICALLY UNSATURATED CARBOXYLIC ACID AND ABOUT 80 TO ABOUT 95 WEIGHT PERCENT OF MONOETHYLENICALLY UNSATURATED, QUANTITATIVELY-MONOFUNCTIONAL MONOMERS, AND HAVING AVERAGE MOLECULAR WEIGHT IN THE RANGE OF ABOUT 1500 TO ABOUT 15,000 WITH NO MORE THAN 5 PERCENT THEREOF HAVING MOLECULAR WEIGHT ABOVE 20,000.
Claim 4
Dependent Claim 59 words
EPOXY-FUNCTIONAL COPOLYMER OF ABOUT 5 TO ABOUT 20 WEIGHT PERCENT OF A GLYCIDYL ESTER OF A MONOETHYLENICALLY UNSATURATED CARBOXYLIC ACID AND ABOUT 80 TO ABOUT 95 WEIGHT PERCENT OF MONOETHYLENICALLY UNSATURATED, QUANTITATIVELY-MONOFUNCTIONAL MONOMERS, AND HAVING AVERAGE MOLECULAR WEIGHT IN THE RANGE OF ABOUT 1500 TO ABOUT 15,000 WITH NO MORE THAN 5 PERCENT THEREOF HAVING MOLECULAR WEIGHT ABOVE 20,000.
Claim 5
Dependent Claim 85 words
AN ANHYDRIDE-FUNCTIONAL COPOLYMER OF ABOUT 5 TO ABOUT 20 WEIGHT PERCENT OF AN ANHYDRIDE OF AN OLEFINICALLYUNSATURATED DICARBOXYLIC ACID AND ABOUT 80 TO ABOUT 95 WEIGHT PERCENT OF MONETHYLENICALLY UNSATURATED, QUANTITATIVELY-MONOFUNCTIONAL MONOMERS AND HAVING AVERAGE MOLECULAR WEIGHT IN THE RANGE OF ABOUT 1500 TO ABOUT 15,000 WITH NO MORE THAN 5 PERCENT THEREOF HAVING MOLECULAR WEIGHT ABOUT 20,000, SAID ANHYDRIDE-FUNCTIONAL COPOLYMER BEING PRESENT IN AN AMOUNT SUCH AS TO PROVIDE ABOUT 0.4 TO ABOUT 1 ANHYDRIDE GROUP PER EPOXY GROUP IN THE EPOXY-FUNCTIONAL COPOLYMER, SAID
Claim 6
Dependent Claim 85 words
AN ANHYDRIDE-FUNCTIONAL COPOLYMER OF ABOUT 5 TO ABOUT 20 WEIGHT PERCENT OF AN ANHYDRIDE OF AN OLEFINICALLYUNSATURATED DICARBOXYLIC ACID AND ABOUT 80 TO ABOUT 95 WEIGHT PERCENT OF MONETHYLENICALLY UNSATURATED, QUANTITATIVELY-MONOFUNCTIONAL MONOMERS AND HAVING AVERAGE MOLECULAR WEIGHT IN THE RANGE OF ABOUT 1500 TO ABOUT 15,000 WITH NO MORE THAN 5 PERCENT THEREOF HAVING MOLECULAR WEIGHT ABOUT 20,000, SAID ANHYDRIDE-FUNCTIONAL COPOLYMER BEING PRESENT IN AN AMOUNT SUCH AS TO PROVIDE ABOUT 0.4 TO ABOUT 1 ANHYDRIDE GROUP PER EPOXY GROUP IN THE EPOXY-FUNCTIONAL COPOLYMER, SAID
Claim 7
Dependent Claim 46 words
A thermosettable powder coating composition in accordance with claim 1 wherein said epoxy-functional copolymer contains about 8 to about 15 weight percent of said glycidyl ester of a monoethylenically unsaturated carboxylic acid and about 85 to about 92 weight percent of said monoethylenically unsaturated, quantitatively-monofunctional monomers.
Claim 8
Dependent Claim 84 words
an anhydride-functional copolymer of about 5 to about 20 weight percent of an anhydride of an olefinically-unsaturated dicarboxylic acid and about 80 to about 95 weight percent of monoethylenically unsaturated, quantitatively-monofunctional monomers and having average molecular weight in the range of about 1500 to about 15,000 with no more than 5 percent thereof having molecular weight about 20,000, said anhydride-functional copolymer.being present in an amount such as to provide about 0.4 to about 1 anhydride group per epoxy group in the epoxy-functional copolymer, and
Claim 9
Dependent Claim 84 words
an anhydride-functional copolymer of about 5 to about 20 weight percent of an anhydride of an olefinically-unsaturated dicarboxylic acid and about 80 to about 95 weight percent of monoethylenically unsaturated, quantitatively-monofunctional monomers and having average molecular weight in the range of about 1500 to about 15,000 with no more than 5 percent thereof having molecular weight about 20,000, said anhydride-functional copolymer.being present in an amount such as to provide about 0.4 to about 1 anhydride group per epoxy group in the epoxy-functional copolymer, and
Claim 10
Dependent Claim 18 words
a polymeric flow control agent forming at least about 0.5 to about 4.0 weight percent of the mixture.
Claim 11
Dependent Claim 18 words
a polymeric flow control agent forming at least about 0.5 to about 4.0 weight percent of the mixture.
Claim 12
Dependent Claim 17 words
A thermosettable powder coating composition in accordance with claim 1 wherein said glycidyl ester is glycidyl methacrylate.
Claim 13
Dependent Claim 18 words
A POLYMERIC FLOW CONTROL AGENT FORMING AT LEAST ABOUT 0.5 TO ABOUT 4.0 WEIGHT PERCENT OF THE MIXTURE.
Claim 14
Dependent Claim 18 words
A POLYMERIC FLOW CONTROL AGENT FORMING AT LEAST ABOUT 0.5 TO ABOUT 4.0 WEIGHT PERCENT OF THE MIXTURE.
Claim 15
Dependent Claim 17 words
A thermosettable powder coating composition in accordance with claim 1 wherein said glycidyl ester is glycidyl acrylate.
Claim 16
Dependent Claim 45 words
A thermosettable powder coating composition in accordance with claim 1 wherein said anhydride-functional copolymer contains about 8 to about 15 weight percent of said anhydride of an olefinically unsaturated dicarboxylic acid and about 85 to about 92 weight percent of said monoethylenically unsaturated, quantitatively-monofunctional monomers.
Claim 17
Dependent Claim 23 words
A thermosettable powder coating composition in accordance with claim 1 wherein said olefinically unsaturated dicarboxylic acid is an alpha-beta olefinically unsaturated dicarboxylic acid.
Claim 18
Dependent Claim 22 words
A thermosettable powder coating composition in accordance with claim 1 wherein said anhydride of said olefinically unsaturated dicarboxylic acid is maleic anhydride.
Claim 19
Dependent Claim 32 words
A thermosettable powder coating composition in accordance with claim 1 wherein said epoxy-functional copolymer and said anhydride-functional copolymer each have average molecular weight in the range of about 2,500 to about 6,000.

References Cited (Backward Citations)

US3070564A Cited
US3222419A Cited
US3514419A Cited
US3595944A Cited
US3808114A Cited
US3781379A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-06-09 1978-12-09 1979-06-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-06-09 1982-12-09 1983-06-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-06-09 1986-12-09 1987-06-10 $7700.00 Window Closed / Lapsed

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