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US3888684A Expired / Lapsed US ⏱️ 0.0 years remaining

Algicidal roofing granules

Assignee: GAF Chemicals Corp
•
Filing: 1972-10-25
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Granted: 1975-06-10
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Expires: 1992-10-25
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Abstract

Abstract The continued effectiveness of algicidal roofing granules in retarding the growth of algae and/or fungi over extended periods of time when employed in roofing surfaces exposed to atmospheric weathering conducive to the growth of such algae and/or fungi is enhanced by the provision of two fully water insolubilized silicate-clay coatings each containing algicidal compounds, with the inner insolubilized coating having a greater algicidal content than the outer insolubilized coating. The algicidal compounds employed are zinc algicides, copper algicides or mixtures thereof. Advantageously, the inner coating will have an algicidal content of at least about twice the algicidal content of the outer coating. The desired toxic effect in inhibiting the biological growth of algae and/or fungi is enhanced by employing both copper and zinc algicides in the overall algicidal content of the coatings. The release of the zinc and copper ions during periods of rain and dew, and the consequent leaching of such ions from the color coatings, produces a bimetallic toxic effect that is particularly useful in enhancing the resistance of roofing surfaces containing such granules to unsightly algae and/or fungi discoloration. The fully insolubilized coatings provide highly desirable weathering characteristics without undesired loss of algicidal material, but are sufficiently moisture permeable so that the desired leaching of algicidal ions, particularly a combination of zinc and copper ions, is achieved at a highly effective rate that nevertheless permits the desired leaching of algicidal ions to continue at an effective rate over the extended periods of time required for acceptable discoloration prevention over the anticipated life of the roofing surface.

Inventors

  • 👤 David C Little

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 23:00
CPC Classifications
A; A01; A01N; A01N25/00; A01N25/26

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 306 words
ALGICIDAL ROOFING GRANULES HAVING AN ENHANCED ABILITY, OVER AN EXTENDED PERIOD OF TIME, TO LEACH ALGICIDAL IONS TO PREVENT OR INHIBIT THE GROWTH OF DISCOLORING ALGAE AND FUNGI ORGANISMS UPON ATMOSPHERIC EXPOSURE OF ROOFING SURFACES CONTAINING SICH GRANULES, COMPRISING A. BASE MINERAL GRANULES; B. AN INNER, MOISTURE PERMEABLE, DURABLE, WATER INSOLUBILIZED, PIGMENTED, FIRED, IORGANIC ALKALI METAL SILICATECLAY COATING, SAID COATING CONTAINING A MIXTURE OF ZINC AND COPPER ALGICIDES; AND C. AN OUTER, MOISTURE PERMEABLE, DURABLE, WATER INSOLUBILIZED, PIGMENTED, FIRED, INORGANIC ALKALI METAL SILICATECLAY COATING, SAID COATING CONTAINING A MIXTURE OF ZINC AND COPPER ALGICIDES, THE TOTAL ZINC ALGICICAL CONTENT OF SAID INNER AND OUTER COATINGS BEING IN THE RANGE OF FROM ABOUT 0.05 TO ABOUT 0.5 PERCENT BY WEIGHT BASED ON THE TOTAL WEIGHT OF SAID BASE GRANULES, THE TOTAL COPPER ALGICIDAL CONTENT OF SAID INNER AND OUTER COATINGS BEING IN THE RANGE OF FROM ABOUT 0.05 TO ABOUT 0.5 PERCENT BY WEIGHT BASED ON THE TOTAL WEIGHT OF SAID BASE GRANULES AND THE TOTAL ALGICIDAL CONTENT OF SAID OUTER COATING BEING LESS THAN THAT OF SAID INNER COATING, WHEREBY WHEN SAID COATED GRANULES ARE INCORPORATED INTO ROOFING COMPOSITIONS AND EXPOSED TO ATMOSPHERIC WEATHERING AGICIDAL IONS ARE SLOWLY LEACHED FROM THE OUTER COATING DURING PERIODS OF RAIN AND DEW TO RETARD THE GROWTH OF ALGAE AND FUNGI, SAID INNER COATING SERVING AS A RESERVOIR OF ALGICIDAL IONS, THUS ASSURING THE CONTINUED LEACHING OF ALGICIDAL IONS FROM SAID GRANULES DURING USE OVER AN EXTENDED PERIOD OF TIME AND ASSURING THE EFFECTIVE UNTILZATION OF THE ALGICIDAL CONTENT OF THE OVERALL GRANULE COATING, SAID INNER COATING ALSO TENDING TO FILL IN VOIDS IN THE BASE MINERAL GRANULES SO AS TO ASSURE A MORE UNIFORM OUTER COATING, ENHANCING THE UNIFORMITY OF THE RESISTANCE OF ROOFING SURFACES CONTAINING SAID GRANULES TO DISCOLORATION DURING SUCH EXTENDED PERIODS OF EXPOSURE TO ATMOSPHERIC WEATHERING.
Claim 2
Dependent Claim 306 words
ALGICIDAL ROOFING GRANULES HAVING AN ENHANCED ABILITY, OVER AN EXTENDED PERIOD OF TIME, TO LEACH ALGICIDAL IONS TO PREVENT OR INHIBIT THE GROWTH OF DISCOLORING ALGAE AND FUNGI ORGANISMS UPON ATMOSPHERIC EXPOSURE OF ROOFING SURFACES CONTAINING SICH GRANULES, COMPRISING A. BASE MINERAL GRANULES; B. AN INNER, MOISTURE PERMEABLE, DURABLE, WATER INSOLUBILIZED, PIGMENTED, FIRED, IORGANIC ALKALI METAL SILICATECLAY COATING, SAID COATING CONTAINING A MIXTURE OF ZINC AND COPPER ALGICIDES; AND C. AN OUTER, MOISTURE PERMEABLE, DURABLE, WATER INSOLUBILIZED, PIGMENTED, FIRED, INORGANIC ALKALI METAL SILICATECLAY COATING, SAID COATING CONTAINING A MIXTURE OF ZINC AND COPPER ALGICIDES, THE TOTAL ZINC ALGICICAL CONTENT OF SAID INNER AND OUTER COATINGS BEING IN THE RANGE OF FROM ABOUT 0.05 TO ABOUT 0.5 PERCENT BY WEIGHT BASED ON THE TOTAL WEIGHT OF SAID BASE GRANULES, THE TOTAL COPPER ALGICIDAL CONTENT OF SAID INNER AND OUTER COATINGS BEING IN THE RANGE OF FROM ABOUT 0.05 TO ABOUT 0.5 PERCENT BY WEIGHT BASED ON THE TOTAL WEIGHT OF SAID BASE GRANULES AND THE TOTAL ALGICIDAL CONTENT OF SAID OUTER COATING BEING LESS THAN THAT OF SAID INNER COATING, WHEREBY WHEN SAID COATED GRANULES ARE INCORPORATED INTO ROOFING COMPOSITIONS AND EXPOSED TO ATMOSPHERIC WEATHERING AGICIDAL IONS ARE SLOWLY LEACHED FROM THE OUTER COATING DURING PERIODS OF RAIN AND DEW TO RETARD THE GROWTH OF ALGAE AND FUNGI, SAID INNER COATING SERVING AS A RESERVOIR OF ALGICIDAL IONS, THUS ASSURING THE CONTINUED LEACHING OF ALGICIDAL IONS FROM SAID GRANULES DURING USE OVER AN EXTENDED PERIOD OF TIME AND ASSURING THE EFFECTIVE UNTILZATION OF THE ALGICIDAL CONTENT OF THE OVERALL GRANULE COATING, SAID INNER COATING ALSO TENDING TO FILL IN VOIDS IN THE BASE MINERAL GRANULES SO AS TO ASSURE A MORE UNIFORM OUTER COATING, ENHANCING THE UNIFORMITY OF THE RESISTANCE OF ROOFING SURFACES CONTAINING SAID GRANULES TO DISCOLORATION DURING SUCH EXTENDED PERIODS OF EXPOSURE TO ATMOSPHERIC WEATHERING.
Claim 3
Dependent Claim 28 words
The algicidal roofing granules of claim 1 in which the algicidal content of said inner coating is at least about twice the algicidal content of said outer coating.
Claim 4
Dependent Claim 54 words
The algicidal roofing granules of claim 2 in which said zinc algicide is present in said inner coating in an amount at least about twice the zinc algicide content of said outer coating, said copper algicide being present in said inner coating in an amount in excess of that employed in said outer coating.
Claim 5
Dependent Claim 14 words
The algicidal roofing granules of claim 3 in which said zinc algicide comprises ZnO.
Claim 6
Dependent Claim 14 words
The algicidal roofing granules of claim 4 in which said copper algicide comprises Cu2O.
Claim 7
Dependent Claim 20 words
The algicidal roofing granules of claim 4 in which said copper algicide comprises a mixture of cuprous and cupric algicides.
Claim 8
Dependent Claim 21 words
The algicidal roofing granules of claim 6 in which said cuprous algicide comprises Cu2O and said cupric oxide comprises copper sulfate.
Claim 9
Dependent Claim 39 words
The algicidal roofing granules of claim 7 in which said copper algicide in said outer coating consists essentially of copper sulfate and said copper algicide in said inner coating consists essentially of a mixture of copper sulfate and Cu2O.
Claim 10
Dependent Claim 61 words
The algicidal roofing granules of claim 8 in which said outer coating cOntains about 2 lbs. of copper sulfate and about 1 lb. of ZnO per ton of base mineral granules, and in which said inner coating contains about 2 lbs. of Cu2O, about 2 lbs. of copper sulfate and about 3 lbs. of ZnO per ton of said base granules.
Claim 11
Dependent Claim 48 words
The algicidal roofing granules of claim 5 in which said outer coating contains about 1 lb. of ZnO per ton of base mineral granules, and in which said inner coating contains about 5 lbs. of Cu2O and about 3 lbs. of ZnO per ton of said base granules.

References Cited (Backward Citations)

US3528842A Cited
US3507676A Cited
US3476577A Cited
US3494727A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-06-09 1978-12-09 1979-06-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-06-09 1982-12-09 1983-06-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-06-09 1986-12-09 1987-06-10 $7700.00 Window Closed / Lapsed

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