US3887453A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for obtaining oil, gas and byproducts from pyrobituminous shale or other solid materials impregnated with hydrocarbons
Assignee: Petroleo Brasileiro SA Petrobras
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Filing: 1972-09-01
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Granted: 1975-06-03
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Expires: 1992-09-01
Abstract
Abstract An ''''Improved process for obtaining oil, gas and byproducts from pyrobituminous shale or other solid materials impregnated with hydrocarbons'''' under such conditions that a mist is permitted to form at the output of the reactor, resulting from the extraction of recycling gases passing in countercurrent with the downwardly moving shale. The improvement results in lower costs, higher amounts of extracted material, higher rentability and, accordingly, better economy.
Inventors
- 👤 Seiki Ueta
- 👤 Osmar Chaves Ivo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 17:55
CPC Classifications
C; C10; C10G; C10G1/00; C10G1/02
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
195 words
A NON-COMBUSTION PROCESS FOR OBTAINING MINERAL OIL AND OTHER DERIVATIVES FROM PYROBITUMINOUS SHALE OR OTHER SOLID MATERIALS IMPREGNATED WITH HYDROCARBONS, THE SAID PROCESS BEING NON-COMBUSTIVE AND CARRIED OUT IN A VERTICAL DISTILLATION RETORT, WHEREIN THE MINED SHALE OR OTHER SOLID MATERIALS IS CONTINOUSLY FED AT THE TOP OF SAID RETORT THROUGH AN INERT GAS SEALED VALVE, WHEREFROM SAID MINED SHALE OR OTHER SOLID MATERIALS ARE EVENLY DISTRIBUTED TO THE RETORTING ZONE AND THEN DESCENT TO A COOLING ZONE BELOW THE RETORTING ZONE, THE RETORTING BEING CARRIED OUT AT SUPER-ATMOSPHERIC PRESSURE BY A MIXTURE OF SUBSTANTIALLY OXYGEN-FREE RECYCLING GASES PREVIOUSLY AND INDIRECTLY HEATED OUTSIDE THE RETORT, SAID HEATED RECYCLING GASES BEING INTRODUCED INTO THE BOTTOM OF SAID RETORTING ZONE OF SAID RETORT AT A HIGHER TEMPERATURE THAN THE RETORTING TEMPERATURE, AND OF SUBSTANTIALLY OXYGEN-FREE RECYCLING GASES INTRODUCED COLD AT THE BOTTOM OF SAID RETORT INTO THE COOLING ZONE WHICH IN UPWARDLY FLOW THROUGH THE COOLING ZONE EXCHANGE SENSIBLE HEAT WITH SAID RETORT SHALE OR OTHER SOLID MATERIALS THAT IS CONTINUOUSLY WITHDRAWN FROM THE BOTTOM OF SAID RETORT THROUGH AN INERT GAS SEALED VALVE, THE LIQUID AND GASEOUS, RETORTING PRODUCTS BEING WITHDRAWN FROM TOP OF SAID RETORT.
Claim 2
Dependent Claim
195 words
A NON-COMBUSTION PROCESS FOR OBTAINING MINERAL OIL AND OTHER DERIVATIVES FROM PYROBITUMINOUS SHALE OR OTHER SOLID MATERIALS IMPREGNATED WITH HYDROCARBONS, THE SAID PROCESS BEING NON-COMBUSTIVE AND CARRIED OUT IN A VERTICAL DISTILLATION RETORT, WHEREIN THE MINED SHALE OR OTHER SOLID MATERIALS IS CONTINOUSLY FED AT THE TOP OF SAID RETORT THROUGH AN INERT GAS SEALED VALVE, WHEREFROM SAID MINED SHALE OR OTHER SOLID MATERIALS ARE EVENLY DISTRIBUTED TO THE RETORTING ZONE AND THEN DESCENT TO A COOLING ZONE BELOW THE RETORTING ZONE, THE RETORTING BEING CARRIED OUT AT SUPER-ATMOSPHERIC PRESSURE BY A MIXTURE OF SUBSTANTIALLY OXYGEN-FREE RECYCLING GASES PREVIOUSLY AND INDIRECTLY HEATED OUTSIDE THE RETORT, SAID HEATED RECYCLING GASES BEING INTRODUCED INTO THE BOTTOM OF SAID RETORTING ZONE OF SAID RETORT AT A HIGHER TEMPERATURE THAN THE RETORTING TEMPERATURE, AND OF SUBSTANTIALLY OXYGEN-FREE RECYCLING GASES INTRODUCED COLD AT THE BOTTOM OF SAID RETORT INTO THE COOLING ZONE WHICH IN UPWARDLY FLOW THROUGH THE COOLING ZONE EXCHANGE SENSIBLE HEAT WITH SAID RETORT SHALE OR OTHER SOLID MATERIALS THAT IS CONTINUOUSLY WITHDRAWN FROM THE BOTTOM OF SAID RETORT THROUGH AN INERT GAS SEALED VALVE, THE LIQUID AND GASEOUS, RETORTING PRODUCTS BEING WITHDRAWN FROM TOP OF SAID RETORT.
Claim 3
Dependent Claim
195 words
A non-combustion process for obtaining mineral oil and other derivatives from pyrobituminous shale or other solid materials impregnated with hydrocarbons, the said process being non-combustive and carried out in a vertical distillation retort, wherein the mined shale or other solid materials is continuously fed at the top of said retort through an inert gas sealed valve, wherefrom said mined shale or other solid materials are evenly distributed to the retorting zone and then descend to a cooling zone below the retorting zone, the retorting being carried out at super-atmospheric pressure by a mixture of substantially oxygen-free recycling gases previously and indirectly heated outside the retort, said heated recycling gases being introduced into the bottom of the retorting zone of said retort at a higher temperature than the retorting temperature, and of substantially oxygen-free recycling gases introduced cold at the bottom of said retort into the cooling zone which in upwardly flow through the cooling zone exchange sensible heat with said retorted shale or other solid materials that is continuously withdrawn from the bottom of said retort through an inert gas sealed valve, the liquid and gaseous retorting products being drawn from top of said retort.
Claim 4
Dependent Claim
195 words
A non-combustion process for obtaining mineral oil and other derivatives from pyrobituminous shale or other solid materials impregnated with hydrocarbons, the said process being non-combustive and carried out in a vertical distillation retort, wherein the mined shale or other solid materials is continuously fed at the top of said retort through an inert gas sealed valve, wherefrom said mined shale or other solid materials are evenly distributed to the retorting zone and then descend to a cooling zone below the retorting zone, the retorting being carried out at super-atmospheric pressure by a mixture of substantially oxygen-free recycling gases previously and indirectly heated outside the retort, said heated recycling gases being introduced into the bottom of the retorting zone of said retort at a higher temperature than the retorting temperature, and of substantially oxygen-free recycling gases introduced cold at the bottom of said retort into the cooling zone which in upwardly flow through the cooling zone exchange sensible heat with said retorted shale or other solid materials that is continuously withdrawn from the bottom of said retort through an inert gas sealed valve, the liquid and gaseous retorting products being drawn from top of said retort.
Claim 5
Dependent Claim
56 words
The process according to claim 1 wherein the gases produced in the retorting process are separated from liquid components and from solid material in suspension by means of a system of cyclones and electrostatic precipitators in series, and then part of said gases is heated prior to its injection into the bottom of said retorting zone.
Claim 6
Dependent Claim
29 words
The process according to claim 1 wherein said heated part of substantially oxygen-free recycling gases is indirectly heated in a furnace outside the retort to a temperature between 900*-1300*F.
Claim 7
Dependent Claim
37 words
The process according to claim 1 wherein said part of substantially oxygen-free recycling gases without previous heating or cooling is introduced into the bottom of said retort at a temperature of about 212*F as so-called cold gases.
Claim 8
Dependent Claim
17 words
The process according to claim 1 wherein the optimum temperature of retorting is between 800* - 1,000*F.
Claim 9
Dependent Claim
23 words
The process according to claim 1 wherein the retorting is accomplished in the retort at an internal pressure between 7.1 and 21.3 psig.
Claim 10
Dependent Claim
30 words
The process according to claim 1 wherein the size of the pieces of said mined shale fed to said retort is between 5.3 and 200 millimeters (0.25 and 8.00 inches).
References Cited (Backward Citations)
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US3526586A
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US3503869A
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US3484364A
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US3551322A
Cited
US3619405A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-06-02 | 1978-12-02 | 1979-06-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-06-02 | 1982-12-02 | 1983-06-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-06-02 | 1986-12-02 | 1987-06-03 | $7700.00 | Window Closed / Lapsed |