← Back to Patent Explorer
US3885903A Expired / Lapsed US ⏱️ 0.0 years remaining

Reduction of pollutants in gaseous hydrocarbon combustion products

Assignee: Aqua Chem Inc
•
Filing: 1972-10-30
•
Granted: 1975-05-27
•
Expires: 1992-10-30
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Fuel and less than the amount of air for stoichiometric combustion are injected into a combustion chamber so that the fuel rich mixture burns as a core in the combustion chamber. The balance of the air for substantially stoichiometric combustion is injected coaxially and rotationally as a sheath or vortex which surrounds the core. Where the core is hot and rich, there is little mixing of the sheath air and core gases and the available oxygen combines preferentially with fuel components other than nitrogen so that little nitrogen oxides are produced. After some heat is extracted from the gases in the core, more complete mixing of the sheath air and core gases occurs. Under these lean and cool combustion conditions, production of nitrogen oxides is also unsubstantial. Means for mixing the gas streams may be disposed adjacent the exit end of the combustion chamber when necessary to promote turbulence and further mixing of the air and hot gases for bringing about complete combustion of any residual combustibles. In the larger combustion systems within long furnaces means of promoting turbulence may not be required to complete combustion.

Inventors

  • 👤 Haye Paul G La

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 05:50
CPC Classifications
F; F23; F23C; F23C6/00; F23C6/04

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 195 words
A METHOD OF BURNING FUEL IN A MANNER TO REDUCE THE NITROGEN OXIDES, CARBON MONOXIDE, AND UNBURNED HYDROCARBONS AND CARBONACEOUS PARTICULATES IN THE EXHAUST GASES THEREFROM, COMPRISING: A. DEVELOPING IN A CONTINUOUS COMBUSTION ZONE IN IGNITED CORE STREAM CONSTITUTING A FUEL-RICH MIXTURE OF FUEL AND SUBSTANTIALLY LESS THAN THE AMOUNT OF AIR REQUIRED FOR STOICHIOMETRIC COMBUSTION, B. INTRODUCING INTO SAID CONTINUOUS COMBUSTION ZONE A SHEATH OF AIR WHICH SURROUNDS AND INTERFACES DIRECTLY WITH SAID CORE STREAM AND WHICH FLOWS THEREALONG WITHOUT DISCONTINUITY, THE QUANTITY OF AIR INTRODUCED AS SAID SHEATH BEING AT LEAST THE ENTIRE QUANTITY OF ADDITIONAO L AIR AND NOT SUBSTANTIALLY MORE THAN THE ADDITIONAL AIR REQUIRED TO MAKE UP THE STOICHIOMETRIC AMOUNT OF FOR COMPLETE COMBUSTION OF SAID FUEL, C. PASSING SAID SHEATH IN A HEAT EXCHANGE RELATION WITH COOLING MEANS FOR EXTRACTING SOME HEAT PERMANENTLY FROM SAID CORE STREAM, AND THEN D. ALLOWING THE INCOMPLETELY OXIDIZED GASEOUS COMBUSTION PRODUCTS AND SAID SHEATH AIR TO MIX IN NON-DISCRETE STAGES IN SAID COMBUSTION ZONE AND EFFECT FURTHER COMBUSTION OF SOME OF THE THERETOFORE INCOMPLETELY OXIDIZED COMPONENTS OF SAID FUEL AT A LOW ENOUGH TEMPERATURE TO AVOID PRODUCTION OF SUBSTANTIAL QUANTITIES OF NITROGEN OXIDES.
Claim 2
Independent Claim 195 words
A METHOD OF BURNING FUEL IN A MANNER TO REDUCE THE NITROGEN OXIDES, CARBON MONOXIDE, AND UNBURNED HYDROCARBONS AND CARBONACEOUS PARTICULATES IN THE EXHAUST GASES THEREFROM, COMPRISING: A. DEVELOPING IN A CONTINUOUS COMBUSTION ZONE IN IGNITED CORE STREAM CONSTITUTING A FUEL-RICH MIXTURE OF FUEL AND SUBSTANTIALLY LESS THAN THE AMOUNT OF AIR REQUIRED FOR STOICHIOMETRIC COMBUSTION, B. INTRODUCING INTO SAID CONTINUOUS COMBUSTION ZONE A SHEATH OF AIR WHICH SURROUNDS AND INTERFACES DIRECTLY WITH SAID CORE STREAM AND WHICH FLOWS THEREALONG WITHOUT DISCONTINUITY, THE QUANTITY OF AIR INTRODUCED AS SAID SHEATH BEING AT LEAST THE ENTIRE QUANTITY OF ADDITIONAO L AIR AND NOT SUBSTANTIALLY MORE THAN THE ADDITIONAL AIR REQUIRED TO MAKE UP THE STOICHIOMETRIC AMOUNT OF FOR COMPLETE COMBUSTION OF SAID FUEL, C. PASSING SAID SHEATH IN A HEAT EXCHANGE RELATION WITH COOLING MEANS FOR EXTRACTING SOME HEAT PERMANENTLY FROM SAID CORE STREAM, AND THEN D. ALLOWING THE INCOMPLETELY OXIDIZED GASEOUS COMBUSTION PRODUCTS AND SAID SHEATH AIR TO MIX IN NON-DISCRETE STAGES IN SAID COMBUSTION ZONE AND EFFECT FURTHER COMBUSTION OF SOME OF THE THERETOFORE INCOMPLETELY OXIDIZED COMPONENTS OF SAID FUEL AT A LOW ENOUGH TEMPERATURE TO AVOID PRODUCTION OF SUBSTANTIAL QUANTITIES OF NITROGEN OXIDES.
Claim 3
Dependent Claim 32 words
The method set forth in claim 1 and introducing the air forming said sheath entirely from the one end of the combustion zone proximate to the upstream end of said core stream.
Claim 4
Dependent Claim 38 words
The method set forth in claim 1 including the step of increasing the velocity of said mixture to promote turbulence in said mixture and effect more complete mixing thereof and enhance oxidation of residual combustibles other than nitrogen.
Claim 5
Dependent Claim 60 words
The method set forth in claim 1 and including the step of: a. rotating said sheath of air around at least an upstream portion of said core stream whereby said rotation will tend to retard mixing of said streams and substantially prevent air becoming available for complete combustion of combustibles or for significant oxidation of nitrogen in said core stream.
Claim 6
Dependent Claim 26 words
The method set forth in claim 1 and passing said core stream through a combustion zone in a substantially straight line path and without helical motion.
Claim 7
Dependent Claim 36 words
The method set forth in claim 1 wherein the heat extracted from said sheath is dissipated by said cooling means elsewhere than to the gases derived from said core stream and sheath in said combustion zone.
Claim 8
Dependent Claim 41 words
The method set forth in claim 1 wherein said incompletely oxidized combustion products and air sheath is progressively mixed to effect the progressive combustion of said incompletely oxidized fuel and combustion products at under 2600* F everywhere in said combustion zone.
Claim 9
Dependent Claim 60 words
The method set forth in claim 7 and including the step of: a. rotating said sheath of air around at least an upstream portion of said core stream whereby said rotation will tend to retard mixing of said streams and substantially prevent air becoming available for complete combustion of combustibles or for significant oxidation of nitrogen in said core stream.
Claim 10
Dependent Claim 26 words
The method set forth in claim 7 and passing said core stream through a combustion zone in a substantially straight line path and without helical motion.
Claim 11
Dependent Claim 33 words
The method set forth in claim 1 and including the step of dissipating the heat extracted from said sheath by said cooling means to additional heat absorbing means outside of said combustion zone.
Claim 12
Dependent Claim 55 words
The method set forth in claim 10 and rotating said sheath of air around at least an upstream portion of said core stream whereby said rotation will tend to retard mixing of said streams and substantially prevent air becoming available for complete combustion of combustibles or for significant oxidation of nitrogen in said core stream.
Claim 13
Dependent Claim 35 words
The method set forth in claim 11 including the step of increasing the velocity of said mixture to promote turbulence and more complete mixing thereof whereby to enhance oxidation of residual combustibles other than nitrogen.
Claim 14
Dependent Claim 42 words
The method set forth in claim 12 including: a. maintaining the temperature of said gaseous mixture at least above 1800* F to substantially oxidize residual carbon monoxide, hydrocarbons and carbonaceous particulates and below about 2400* F to avoid oxidation of substantial nitRogen.
Claim 15
Independent Claim 183 words
A method of burning fuel in a manner to reduce nitrogen oxides, carbon monoxide, unburned hydrocarbons and carbonaceous particulates in the exhaust gases therefrom, comprising: a. injecting into a continuous combustion zone fuel and substantially less than the amount of air required for stoichiometric combustion of said fuel to produce an ignited fuel-rich core stream directed from the input upstream end generally toward the output downstream end of said combustion zone, and b. flowing into said continuous combustion zone in direct contact with said core stream from said input end toward said output end additional air to sheath said core stream and progressively intermix therewith in non-discrete stages while at the same time absorbing heat from said sheath air and said mixture with cooling means that dissipate said heat permanently to heat absorbing means outside of said combustion zone and other than to air that is introduced to said zone, the quantity of said additional air being at least equal to and not substantially greater than that required to make up the stoichiometric amount for complete combustion of all of the injected fuel.
Claim 16
Independent Claim 183 words
A method of burning fuel in a manner to reduce nitrogen oxides, carbon monoxide, unburned hydrocarbons and carbonaceous particulates in the exhaust gases therefrom, comprising: a. injecting into a continuous combustion zone fuel and substantially less than the amount of air required for stoichiometric combustion of said fuel to produce an ignited fuel-rich core stream directed from the input upstream end generally toward the output downstream end of said combustion zone, and b. flowing into said continuous combustion zone in direct contact with said core stream from said input end toward said output end additional air to sheath said core stream and progressively intermix therewith in non-discrete stages while at the same time absorbing heat from said sheath air and said mixture with cooling means that dissipate said heat permanently to heat absorbing means outside of said combustion zone and other than to air that is introduced to said zone, the quantity of said additional air being at least equal to and not substantially greater than that required to make up the stoichiometric amount for complete combustion of all of the injected fuel.
Claim 17
Independent Claim 235 words
A method of burning non-solid fuel characterized by the steps of: a. projecting into a combustion zone fuel and air for forming an ignited core stream that is propagated in an axial direction in said zone, the amount of air admitted with the fuel being substantailly less than that required for stoichiometric combustion of the fuel, b. flowing additional air into said zone from the input end in surrounding relationship to the core stream initially and intermixing said core stream and air in non-discrete stages and in a continuous and progressive manner by mutually generally radially outward movement of the core stream gaseous products and generally inward movement of said additional air as the gaseous core stream products and air progress in the axial direction of the combustion zone, the quantity of additional air being at least equal to but not substantially greater than the air required to make up the quantity for stoichiometric combustion of the fuel, and c. transferring heat from at least the radially outward portions of the gases flowing in said combustion zone to heat absorbing means extending from near said input end of said zone to a substantial distance in the axial direction from said input end, said absorbing means extracting heat permanently from said combustion zone whereby the temperature of the gases in said combustion zone is maintained below that at which substantial quantities of nitrogen oxides are produced.
Claim 18
Independent Claim 235 words
A method of burning non-solid fuel characterized by the steps of: a. projecting into a combustion zone fuel and air for forming an ignited core stream that is propagated in an axial direction in said zone, the amount of air admitted with the fuel being substantailly less than that required for stoichiometric combustion of the fuel, b. flowing additional air into said zone from the input end in surrounding relationship to the core stream initially and intermixing said core stream and air in non-discrete stages and in a continuous and progressive manner by mutually generally radially outward movement of the core stream gaseous products and generally inward movement of said additional air as the gaseous core stream products and air progress in the axial direction of the combustion zone, the quantity of additional air being at least equal to but not substantially greater than the air required to make up the quantity for stoichiometric combustion of the fuel, and c. transferring heat from at least the radially outward portions of the gases flowing in said combustion zone to heat absorbing means extending from near said input end of said zone to a substantial distance in the axial direction from said input end, said absorbing means extracting heat permanently from said combustion zone whereby the temperature of the gases in said combustion zone is maintained below that at which substantial quantities of nitrogen oxides are produced.
Claim 19
Dependent Claim 43 words
The method set forth in claim 15 including: a. maintaining the temperature of said gaseous mixture at least above about 1800* F to substantially oxidize residual carbon monoxide, hydrocarbons and carbonaceous particulates and below about 2400* F to avoid oxidation of substantial nitrogen.
Claim 20
Dependent Claim 50 words
The method set forth in claim 15 including the step of inducing turbulence and additional mixing of the gaseous combustion products hear the output end of said zone whereby to enhance burning of residual combustibles in said products at a temperature below that at which substantial nitrogen oxides are produced.
Claim 21
Independent Claim 219 words
A method of burning fuel in a manner to reduce the nitrogen oxides, carbon monoxide, and unburned hydrocarbons and carbonaceous particulates in the exhaust gases therefrom, comprising: a. developing in a continuous combustion zone an ignited core stream constituting a fuel-rich mixture of fuel and substantially less than the amount of air required for stoichiometric combustion, b. introducing into said continuous combustion zone a sheath of air which surrounds and interfaces directly with said core stream and which flows therealong without discontinuity, the quantity of air introduced as said sheath being at least the entire quantity of additional air and not substantially more than the additional air required to maKe up the stoichiometric amount for complete combustion of said fuel, c. passing said sheath in a heat exchange relation with cooling means for extracting some heat permanently from said core stream, and then d. allowing the incompletely oxidized gaseous combustion products and said sheath air to mix in non-discrete stages in said combustion zone and effect further combustion of some of the theretofore incompletely oxidized components of said fuel at a low enough temperature to avoid production of substantial quantities of nitrogen oxides, and e. increasing the velocity of said mixture to promote turbulence and more complete mixing thereof whereby to enhance oxidation of residual combustibles other than nitrogen.
Claim 22
Independent Claim 219 words
A method of burning fuel in a manner to reduce the nitrogen oxides, carbon monoxide, and unburned hydrocarbons and carbonaceous particulates in the exhaust gases therefrom, comprising: a. developing in a continuous combustion zone an ignited core stream constituting a fuel-rich mixture of fuel and substantially less than the amount of air required for stoichiometric combustion, b. introducing into said continuous combustion zone a sheath of air which surrounds and interfaces directly with said core stream and which flows therealong without discontinuity, the quantity of air introduced as said sheath being at least the entire quantity of additional air and not substantially more than the additional air required to maKe up the stoichiometric amount for complete combustion of said fuel, c. passing said sheath in a heat exchange relation with cooling means for extracting some heat permanently from said core stream, and then d. allowing the incompletely oxidized gaseous combustion products and said sheath air to mix in non-discrete stages in said combustion zone and effect further combustion of some of the theretofore incompletely oxidized components of said fuel at a low enough temperature to avoid production of substantial quantities of nitrogen oxides, and e. increasing the velocity of said mixture to promote turbulence and more complete mixing thereof whereby to enhance oxidation of residual combustibles other than nitrogen.
Claim 23
Dependent Claim 40 words
The method set forth in claim 18 including: a. maintaining the temperature of said gaseous mixture at least 1800* F to substantially oxidize residual carbon monoxide, hydrocarbons and carbonaceous particulates and below 2400* F to avoid oxidation of substantial nitrogen.

References Cited (Backward Citations)

US3175361A Cited
US3736747A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-26 1978-11-25 1979-05-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-26 1982-11-25 1983-05-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-26 1986-11-25 1987-05-27 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag