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US3884871A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for coating pigment particles with organic polymers

Assignee: Kronos Inc
•
Filing: 1973-06-29
•
Granted: 1975-05-20
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Expires: 1993-06-29
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Abstract

Abstract Dispersed solid particles of titanium dioxide pigment in water containing a dispersing agent are treated with an anchoring agent which is adsorbed on the pigment surface and is capable of copolymerization with other vinyl monomers. The desired monomer or mixture of monomers is added with a polymerization catalyst and heated to effect polymerization. Among the monomers employed are the acrylates, methacrylates, styrene, acrylonitrile, and vinyl sulfonate. The process provides for the coating of individual pigment particles without the undesirable coating of pigment agglomerates. Pigments coated by the process exhibit good dispersion and wetting properties when incorporated in vehicles such as paints and plastics.

Inventors

  • 👤 Daniel F Herman
  • 👤 Dominic Simone

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:20
CPC Classifications
C; C08; C08F; C08F292/00; C08F2/00; C08F2/44; C09; C09C; C09C1/00; C09C1/36; C09C1/3607; C09C1/3676; C01; C01P; C01P2004/00; C01P2004/80; C01P2004/82; C01P2004/84

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 214 words
A PROCESS FOR THE COATING OF TITANIUM DIOXIDE PIGMENT PARTICLES TO FORM DISCRETE PIGMENT PARTICLES INDIVIDUALLY COATED WITH ORGANIC POLYMERS WHICH COMPRISES THE STEPS OF: A. ADDING TO A WATER SLURRY OF TITANIUM DIOXIDE PIGMENT PARTICLES WHEREIN SAID PARTICLE COMPRISE 70% BY WEIGHT OF SAID SLURRY, A POLYANIONIC DISPERSING AGENT SELECTED FROM THE GROUP CONSISTING OF SODIUM HEXAMETAPHOSPHATE, POTASSIUM TRIPOLYPHOSPHATE, AND SODIUM SALT OF POLYCARBOXYLIC ACID IN AN AMOUNT EQUIVALENT TO THE DISPERSANT DEMAND OF THE PARTICLES TO FORM A WATER DISPERSION WHEREIN THE DISPERSANAT DEMAND IS FROM A WATER DISPERSION WEIGHT PERCENT OF THE AMOUNT OF PARTICLES AND THEREBY MAINTAINING SAID DISPERSANT AT A MINIMUM VISCOSITY; B. DILUTING SAID WATER DISPERSION WITH AN AQUEOUS MEDIUM UNTIL SAID PARTICLES COMPRISE FROM 15 TO 30% BY WEIGHT OF SAID DISPERSION; C. ADDING AN ANCHORING AGENT TO SAID DISPERSION; SAID ANCHORING AGENT COMPRISING AN ORGANIC VINYL MONOMER CONTAINING POLAR GROUPS WHICH ARE ADSORBED ON THE SURFACE OF SAID PARTICLES; SAID ANCHORING AGENT BEING CAPABLE OF POLYMERIZATION WITH VINYL MONOMERS; D. ADDING AN ORGANIC VINYL MONOMER TO SAID DISPERSION; E. POLYMERIZING SAID MONOMER AND SAID ANCHORING AGENT IN THE PRESENCE OF A POLYMERIZATION CATALYST THEREBY COATING SAID INDIVIDUAL AND DISCRETE PIGMENT PARTICLES WITH THE FORMED ORGANIC POLYMERS; F. AND FILTERING AND DRYING THE PRODUCT OF STEP (E).
Claim 2
Dependent Claim 214 words
A PROCESS FOR THE COATING OF TITANIUM DIOXIDE PIGMENT PARTICLES TO FORM DISCRETE PIGMENT PARTICLES INDIVIDUALLY COATED WITH ORGANIC POLYMERS WHICH COMPRISES THE STEPS OF: A. ADDING TO A WATER SLURRY OF TITANIUM DIOXIDE PIGMENT PARTICLES WHEREIN SAID PARTICLE COMPRISE 70% BY WEIGHT OF SAID SLURRY, A POLYANIONIC DISPERSING AGENT SELECTED FROM THE GROUP CONSISTING OF SODIUM HEXAMETAPHOSPHATE, POTASSIUM TRIPOLYPHOSPHATE, AND SODIUM SALT OF POLYCARBOXYLIC ACID IN AN AMOUNT EQUIVALENT TO THE DISPERSANT DEMAND OF THE PARTICLES TO FORM A WATER DISPERSION WHEREIN THE DISPERSANAT DEMAND IS FROM A WATER DISPERSION WEIGHT PERCENT OF THE AMOUNT OF PARTICLES AND THEREBY MAINTAINING SAID DISPERSANT AT A MINIMUM VISCOSITY; B. DILUTING SAID WATER DISPERSION WITH AN AQUEOUS MEDIUM UNTIL SAID PARTICLES COMPRISE FROM 15 TO 30% BY WEIGHT OF SAID DISPERSION; C. ADDING AN ANCHORING AGENT TO SAID DISPERSION; SAID ANCHORING AGENT COMPRISING AN ORGANIC VINYL MONOMER CONTAINING POLAR GROUPS WHICH ARE ADSORBED ON THE SURFACE OF SAID PARTICLES; SAID ANCHORING AGENT BEING CAPABLE OF POLYMERIZATION WITH VINYL MONOMERS; D. ADDING AN ORGANIC VINYL MONOMER TO SAID DISPERSION; E. POLYMERIZING SAID MONOMER AND SAID ANCHORING AGENT IN THE PRESENCE OF A POLYMERIZATION CATALYST THEREBY COATING SAID INDIVIDUAL AND DISCRETE PIGMENT PARTICLES WITH THE FORMED ORGANIC POLYMERS; F. AND FILTERING AND DRYING THE PRODUCT OF STEP (E).
Claim 3
Dependent Claim 33 words
The process of claim 1 wherein said aqueous medium contains up to 50% by weight of an alcohol selected from the group consisting of methyl alcohol, ethyl alcohol, propyl alcohol and isopropyl alcohol.
Claim 4
Dependent Claim 27 words
The process of claim 1 wherein said anchoring agent and said vinyl monomer are added simultaneously to said water dispersion; said particles preferentially adsorbing said anchoring agent.
Claim 5
Dependent Claim 31 words
The process of claim 1 wherein a crosslinking agent is added with said vinyl monomer to said dispersion in an amount from 5 to 20% of the weight of said monomer.
Claim 6
Dependent Claim 18 words
The process of claim 1 wherein said pigment particles are titanium dioxide pigment particles treated with hydrous oxides.
Claim 7
Dependent Claim 29 words
The process of claim 1 wherein said anchoring agent is selected from the group consisting of methacrylic acid, sodium methacrylate, acrylic acid, sodium acrylate, hydroxyethylmethacrylate and sodium vinyl sulfonate.
Claim 8
Dependent Claim 51 words
The process of claim 1 wherein said organic vinyl monomer is selected from the group consisting of sodium acrylate, sodium methacrylate, acrylic acid, methacrylic acid, alkyl acrylates, alkyl methacrylates, amino acrylates, amino methacrylates, styrene, 2-methyl styrene, styrene sulfonic acid, sodium vinyl sulfonate, acrylonitrile, methacrylonitrile, vinyl chloride, vinylidene chloride and mixtures thereof.

References Cited (Backward Citations)

US3133893A Cited
US3471439A Cited
US3519593A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-19 1978-11-18 1979-05-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-19 1982-11-18 1983-05-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-19 1986-11-18 1987-05-20 $7700.00 Window Closed / Lapsed

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