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US3884650A Expired / Lapsed US ⏱️ 0.0 years remaining

Waste disposal from oxidative dehydrogenation

Assignee: Texas Petrochemicals Corp
•
Filing: 1973-07-11
•
Granted: 1975-05-20
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Expires: 1993-07-11
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Abstract

Abstract Reducing carbonyl compounds in waste water by stripping an overhead, enriched in carbonyls, condensing an aqueous portion of the overhead which contains the predominate amount of the carbonyls in the overhead, and destroying the carbonyl concentrate. Operating the stripping unit under vacuum essentially eliminates fouling of the stripping unit, caused by aldehyde polymer formation.

Inventors

  • 👤 Rudolph C Woerner
  • 👤 Lloyd D Tschopp
  • 👤 Carl O Oelze

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 21:32
CPC Classifications
C; C07; C07C; C07C11/00; C07C11/12; C07C11/16; C07C11/167; C07C7/00; C07C7/11

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 275 words
IN A PROCESS FOR PREPARATION OF BUTADIENE - 1,3 COMPRISING OXIDATIVELY DEHYDROGENATING A STREAM HAVING BUTENE-2 AS THE MAJOR HYDROCARBON COMPONENT, IN THE PRESENCE OF AIR AND STREAM, PRODUCING A PRODUCT STREAM COMPRISING FROM 8 TO 65 MOL PERCENT BUTADINE -1,3, FROM 0.1 TO 40 MOL PERCENT BUTENE, FROM 40 TO 75 MOL PERCENT NITROGEN, AND FROM 0.03 TO 0.30 MOL PERCENT CARBONYL COMPOUNDS EXCLUSIVE OF WATER, CONTACTING SAID PRODUCT STREAM WITH AN AQUEOUS MEDIUM HAVING A PH OF 10 TO 12, RECOVERING AN AQUEOUS STREAM CONTAINING THE PRINCIPAL AMOUNT OF CARBONYL COMPOUNDS FROM SAID PRODUCT STREAM, REMOVING A PORTION OF SAID HYDROCARBONS FROM SAID AQUEOUS STREAM, AND, FEEDING SAID AQUEOUS STREAM TO A STEAM STRIPPING ZONE, WHEREIN THE IMPROVEMENT COMPRISES SAID AQUEOUS STREAM HAVING FROM 0.045 TO 0.06 MOL PERCENT CARBONYL COMPOUNDS, FROM 0.036 TO 0.042 MOL PERCENT HYDROCARBONS AND FROM 99.86 TO 99.88 MOL PERCENT WATER, SAID STRIPPING ZONE OPERATING AT A TEMPERATURE IN THE RANGE OF 80* TO 179*F AT 2.5 PSIA, ADJUSTING THE TEMPERATURE OF SAID AQUEOUS STREAM PRIOR TO FEEDING INTO SAID STRIPPING ZONE TO A TEMPERATURE LESS THAN THE OPERATING TEMPERATURE OF SAID STRIPPER, MAINTAINING CONDITIONS IN SAID STRIPPING ZONE, INTERNAL REFLUX OF THE MATERIAL THEREIN, WITHDRAWING A GASEOUS OVERHEAD FROM SAID STRIPPING ZONE, SAID OVERHEAD CONTAINING AT LEAST 80 PERCENT OF THE CARBONYL COMPOUNDS FEE FED INTO SAID STRIPPING ZONE IN SAID STREAM, CONDENSING AN AQUEOUS PORTION OF SAID GASEOUS OVERHEAD, SAID CONDENSED PORTION CONTAINING THE MAJOR AMOUNT OF CARBONYL COMPOUNDS IN SAID GASEOUS OVERHEAD, AND WITHDRAWING A LIQUID BOTTOMS, COMPRISING THE MAJOR AMOUNT OW WATER IN SAID STREAM AND HAVING SUBSTANTIALLY LESS CARBONYL COMPOUNDS THAN SAID STREAM.
Claim 2
Dependent Claim 275 words
IN A PROCESS FOR PREPARATION OF BUTADIENE - 1,3 COMPRISING OXIDATIVELY DEHYDROGENATING A STREAM HAVING BUTENE-2 AS THE MAJOR HYDROCARBON COMPONENT, IN THE PRESENCE OF AIR AND STREAM, PRODUCING A PRODUCT STREAM COMPRISING FROM 8 TO 65 MOL PERCENT BUTADINE -1,3, FROM 0.1 TO 40 MOL PERCENT BUTENE, FROM 40 TO 75 MOL PERCENT NITROGEN, AND FROM 0.03 TO 0.30 MOL PERCENT CARBONYL COMPOUNDS EXCLUSIVE OF WATER, CONTACTING SAID PRODUCT STREAM WITH AN AQUEOUS MEDIUM HAVING A PH OF 10 TO 12, RECOVERING AN AQUEOUS STREAM CONTAINING THE PRINCIPAL AMOUNT OF CARBONYL COMPOUNDS FROM SAID PRODUCT STREAM, REMOVING A PORTION OF SAID HYDROCARBONS FROM SAID AQUEOUS STREAM, AND, FEEDING SAID AQUEOUS STREAM TO A STEAM STRIPPING ZONE, WHEREIN THE IMPROVEMENT COMPRISES SAID AQUEOUS STREAM HAVING FROM 0.045 TO 0.06 MOL PERCENT CARBONYL COMPOUNDS, FROM 0.036 TO 0.042 MOL PERCENT HYDROCARBONS AND FROM 99.86 TO 99.88 MOL PERCENT WATER, SAID STRIPPING ZONE OPERATING AT A TEMPERATURE IN THE RANGE OF 80* TO 179*F AT 2.5 PSIA, ADJUSTING THE TEMPERATURE OF SAID AQUEOUS STREAM PRIOR TO FEEDING INTO SAID STRIPPING ZONE TO A TEMPERATURE LESS THAN THE OPERATING TEMPERATURE OF SAID STRIPPER, MAINTAINING CONDITIONS IN SAID STRIPPING ZONE, INTERNAL REFLUX OF THE MATERIAL THEREIN, WITHDRAWING A GASEOUS OVERHEAD FROM SAID STRIPPING ZONE, SAID OVERHEAD CONTAINING AT LEAST 80 PERCENT OF THE CARBONYL COMPOUNDS FEE FED INTO SAID STRIPPING ZONE IN SAID STREAM, CONDENSING AN AQUEOUS PORTION OF SAID GASEOUS OVERHEAD, SAID CONDENSED PORTION CONTAINING THE MAJOR AMOUNT OF CARBONYL COMPOUNDS IN SAID GASEOUS OVERHEAD, AND WITHDRAWING A LIQUID BOTTOMS, COMPRISING THE MAJOR AMOUNT OW WATER IN SAID STREAM AND HAVING SUBSTANTIALLY LESS CARBONYL COMPOUNDS THAN SAID STREAM.
Claim 3
Dependent Claim 34 words
The process according to claim 1 wherein said aqueous stream comprises from 0.03 to 0.07 mol percent carbonyl compounds, from 0.003 to 0.004 mol percent hydrocarbons and from 99.92 to 99.97 mol percent water.
Claim 4
Dependent Claim 34 words
The process according to claim 2 wherein the gaseous overhead comprises from 0.2 to 3.8 mol percent carbonyl compounds, from 0.008 to 0.5 mol percent hydrocarbons, and from 95.7 to 99.8 mol percent water.
Claim 5
Dependent Claim 26 words
The process according to claim 3 wherein said aqueous concentrate is prepared by cooling and contains substantially all of the carbonyl compounds in the gaseous overhead.
Claim 6
Dependent Claim 16 words
The process according to claim 4 wherein said aqueous concentrate is subjected to a second stripping.

References Cited (Backward Citations)

US3174262A Cited
US3073752A Cited
US3679764A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-19 1978-11-18 1979-05-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-19 1982-11-18 1983-05-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-19 1986-11-18 1987-05-20 $7700.00 Window Closed / Lapsed

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