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US3883623A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for controlling end-point density of sintered uranium dioxide nuclear fuel bodies and product

Assignee: General Electric Co
•
Filing: 1972-10-17
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Granted: 1975-05-13
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Expires: 1992-10-17
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Abstract

Abstract A process for controlling the end-point density of a sintered uranium dioxide nuclear fuel body and the resulting product. Uranium dioxide powder having a size ranging up to 10 microns is admixed with a precursor to uranium dioxide, such as ammonium diuranate, having an average agglomerated particle size ranging from about 20 microns to 1 millimeter and the mixture is formed into a pressed compact or green body. The precursor to uranium dioxide has a density lower than that of the uranium dioxide powder and is used in an amount which results in discrete low density regions in the green body which range from about 5% to 25% by volume of the green body. The green body is sintered to decompose the precursor and produce a sintered body having discrete low density porous regions which reduce the end-point density of the sintered body by at least 2%. The sintered body has an end-point density ranging from 85% to 95% of theoretical.

Inventors

  • 👤 Kenneth W Lay

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 15:28
CPC Classifications
G; G21; G21C; G21C3/00; G21C3/42; G21C3/58; G21C3/62; G21C3/623; C; C01; C01G; C01G43/00; C01G43/01; C01G43/025; C01P; C01P2004/00; C01P2004/01; C01P2004/03; C01P2004/50; C01P2004/60; C01P2004/61; C01P2004/62; C01P2006/00; C01P2006/10; Y; Y02; Y02E; Y02E30/00; Y02E30/30; Y10; Y10S; Y10S376/00; Y10S376/90; Y10S376/901

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 249 words
A PROCESS FOR CONTROLLING END-POINT DENSITY OF A SINTERED URANIUM DIOXIDE NNUCLEAR FUEL BODY BY FORMING DISCRETE LOW DENSITY POROUS REGIONS THEREIN COMPRISNG THE STEPS OF PROVIDING URANIUM DIOXIDE POWDER HAVING AN OXYGEN TO URANIUM ATOMIC RATIO RANGING FROM ABOUT 2.00 TO 2.25 AND RANGING IN SIZE UP TO ABOUT 10 MICRONS, ADMIXING SAID URANIUM DIOXIDE POWDER WITH A PRECURSOR TOO URANIUM DIOXIDE HAVING AN AVERAGE AGGLOMERATED PARTICLE SIZE SIGNIFICANTLY LARGER THAN THAT OF THE URANIUM DIOXIDE POWDER AND RANGING FROM ABOUT 20 MICRONS TO ONE MILLIMETER, SAID PRECURSOR BEING A SOLID AND HAVING A DENSITY LOWER THAN THAT OF URANIUM DIOXIDE, FORMING THE RESULTING MIXTURE INTO A GREEN BODY HAVING A DENSITY RANGING FROM ABOUT 30% TO 70% OF THEORETICAL, SAID GREEN BODY HAS A STRUCTURE COMPOSED OF A SUBSTANTIALLY UNIFORM MATRIX OF THE URANIUM DIOXIDE POWDER WITH DISCRETE LOW DENSITY REGIONS OF SAID PRECURSOR THEREIN, SAID PRECURSOR BEING USED IN AN AMOUNT WHICH RESULTS IN SAID DISCRETE LOW DENSITY REGIONS IN THE GREEN BODY RANGING FROM ABOUT 5% TO 25% BY VOLUME OF SAID GREEN BODY, HEATING SAID GREEN BODY TO DECOMPOSE SAID PRECURSOR BEFORE REACHING SINTERING TEMPERATURE,AND SINTERING THE BODY TO PRODUCE A SINTERED BODY HAVING DISCRETE LOW DENSITY POROUS REGIONS WITH A DENSITY SIGNIFICANTLY LOWER THAN THAT OF THE SURROUNDING SINTERED URANIUM DIOXIDE, SAID DISCRETE LOW DENSITY POROUS REGIONS REDUCING THE END-POINT DENSITY OF SAID SINTERED BODY BY AT LEAST 2%, SAID SINTERED BODY HAVING AN END-POINT DENSITY RANGING FROM 85% TO 95% OF THEORETICAL.
Claim 2
Dependent Claim 249 words
A PROCESS FOR CONTROLLING END-POINT DENSITY OF A SINTERED URANIUM DIOXIDE NNUCLEAR FUEL BODY BY FORMING DISCRETE LOW DENSITY POROUS REGIONS THEREIN COMPRISNG THE STEPS OF PROVIDING URANIUM DIOXIDE POWDER HAVING AN OXYGEN TO URANIUM ATOMIC RATIO RANGING FROM ABOUT 2.00 TO 2.25 AND RANGING IN SIZE UP TO ABOUT 10 MICRONS, ADMIXING SAID URANIUM DIOXIDE POWDER WITH A PRECURSOR TOO URANIUM DIOXIDE HAVING AN AVERAGE AGGLOMERATED PARTICLE SIZE SIGNIFICANTLY LARGER THAN THAT OF THE URANIUM DIOXIDE POWDER AND RANGING FROM ABOUT 20 MICRONS TO ONE MILLIMETER, SAID PRECURSOR BEING A SOLID AND HAVING A DENSITY LOWER THAN THAT OF URANIUM DIOXIDE, FORMING THE RESULTING MIXTURE INTO A GREEN BODY HAVING A DENSITY RANGING FROM ABOUT 30% TO 70% OF THEORETICAL, SAID GREEN BODY HAS A STRUCTURE COMPOSED OF A SUBSTANTIALLY UNIFORM MATRIX OF THE URANIUM DIOXIDE POWDER WITH DISCRETE LOW DENSITY REGIONS OF SAID PRECURSOR THEREIN, SAID PRECURSOR BEING USED IN AN AMOUNT WHICH RESULTS IN SAID DISCRETE LOW DENSITY REGIONS IN THE GREEN BODY RANGING FROM ABOUT 5% TO 25% BY VOLUME OF SAID GREEN BODY, HEATING SAID GREEN BODY TO DECOMPOSE SAID PRECURSOR BEFORE REACHING SINTERING TEMPERATURE,AND SINTERING THE BODY TO PRODUCE A SINTERED BODY HAVING DISCRETE LOW DENSITY POROUS REGIONS WITH A DENSITY SIGNIFICANTLY LOWER THAN THAT OF THE SURROUNDING SINTERED URANIUM DIOXIDE, SAID DISCRETE LOW DENSITY POROUS REGIONS REDUCING THE END-POINT DENSITY OF SAID SINTERED BODY BY AT LEAST 2%, SAID SINTERED BODY HAVING AN END-POINT DENSITY RANGING FROM 85% TO 95% OF THEORETICAL.
Claim 3
Dependent Claim 30 words
A process according to claim 1 wherein said precursor to uranium dioxide is selected from the group consisting of ammonium diuranate, U3O8, uranyl nitrate, and ion exchange resins containing uranium.
Claim 4
Dependent Claim 15 words
A process according to claim 2 wherein said precursor to uranium dioxide is ammonium diuranate.
Claim 5
Dependent Claim 98 words
A process according to claim 1 wherein said uranium dioxide powder has a particle size ranging from about 0.02 to 0.5 micron, said precursor to uranium dioxide is ammonium diuranate having an average agglomerated particle size of about 105 microns, said low density regions in said green body comprise about 12% by volume of said body, the density of said green bodY is about 50% of theoretical, said discrete low density porous regions reduce the end-point density of the sintered body by at least 3% and said sintered body has an end-point density of about 91% of theoretical.

References Cited (Backward Citations)

US3094377A Cited
US3342562A Cited
US3431329A Cited
US3579390A Cited
US3609095A Cited
US3683975A Cited
US3761546A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-12 1978-11-11 1979-05-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-12 1982-11-11 1983-05-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-12 1986-11-11 1987-05-13 $7700.00 Window Closed / Lapsed

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