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US3883409A Expired / Lapsed US ⏱️ 0.0 years remaining

Gold alloy electroplating bath

Assignee: Evonik Operations GmbH
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Filing: 1973-07-09
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Granted: 1975-05-13
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Expires: 1993-07-09
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Abstract

Abstract An improved bath for the electrolytic deposition of gold or gold alloys on electrically conductive objects contains an alkali metal gold sulfite, a gold alloy metal, an electrically conductive salt, a chelating agent, a water soluble salt of cadmium, a water soluble salt of copper, a water soluble salt of nickel, and a specified organic phosphorus compound. The bath is useful for depositing white gold on conductive objects.

Inventors

  • 👤 Andre Olivier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 21:05
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/56; C25D3/62; C25D3/48

Claims Analysis

Total Claims: 30
Claim 1
Independent Claim 285 words
IN AN IMPROVED AQUEOUS BATH FOR THE ELECTROLYTIC DEPOSITION OF GOLD OR GOLD ALLOYS ON ELECTRICALLY CONDUCTIVE OBJECTS, SAID BATH CONTAINING AT LEAST ONE CHELATING AGENT, AN ALKALI METAL GOLD SULFITE, AT LEAST ONE GOLD ALLOYING METAL, AND ABOUT 0.5-100 G/L OF AT LEAST ONE ELECTRICALLY CONDUCTIVE SALT OTHER THAN SAID ALKALI METAL GOLD SULFITE, SAID GOLD ALLOYING METAL AND SAID CHELATING AGENT, THE IMPROVEMENT WHEREIN WHITE GOLD IS DEPOSITED ON SAID OBJECT AND WHEREIN SAID AT LEAST ONE GOLD ALLOYING METAL IS AT LEAST ONE WATER SOLUBLE SALT OF CADMIMUM, AT LEAST ONE WATER SOLUBLE SALT OF COPPER, AT LEAST WATER SOLUBLE SALT OF NICKEL, AND ADDITIONALLY THERE IS INCORPORATED IN SAID BATH AN ORGANIC PHOSPHORUS COMOUND OF EITHER A. A COMPOUND OF THE FORMULA (R1-)(3-N)-N(-R-P(=O)(-OH)2)N IN WHICH R1 IS A HYDROGEN ATOM OR ABOUT A C1-C6 LOWER ALKYL RADICAL, R IS ABOUT A C1-C8 ALKYLENE RADICAL, AND N IS A WHOLE NUMBER OF ABOUT 1-3, OR B. AN ALKYLENE DIAMINO TETRA-(METHYLPHOSPHONIC ACID) OR A L-(HYDROXYALKYLIDENE-1,1-DIPHOSPHONIC ACID, THE ALKYLENE AND ALKYLIDENE GROUPS OF WHICH CONTAIN ABOUT 1-12 CARBON ATOMS, OR C. A WATER SOLUBLE SALT OF COMPOUNDS OF A OR B, SAID BATH HAVING A PH OF ABOUT 8.5-11, AND FURTHER WHEREIN SAID BATH CONTAINS GOLD IN AN AMOUNT OF ABOUT 1-8 G/L, CADMIUM IN AN AMOUNT OF ABOUT 0.1-30 G/L, COPPER IN AN AMOUNT OF ABOUT 0.001-0.5 G/L, NICKEL IN AN AMOUNT OF ABOUT 0.001 -10 G/L AND THE ORGANIC PHOSPHROUS COMPOUNDS IN AN AMOUNT OF ABOUT 0.01-10 G/L, WHEREIN SAID AT LEAST ONE CHELATING AGENT IS OTHER THAN A, B AND C AND IS PRESENT IN AN AMOUNT SUFFICIENT TO SUBSTANTIALLY COMPLETELY COMPLEX ALL OF THE METALS PRESENT IN THE PLATING BATH.
Claim 2
Dependent Claim 285 words
IN AN IMPROVED AQUEOUS BATH FOR THE ELECTROLYTIC DEPOSITION OF GOLD OR GOLD ALLOYS ON ELECTRICALLY CONDUCTIVE OBJECTS, SAID BATH CONTAINING AT LEAST ONE CHELATING AGENT, AN ALKALI METAL GOLD SULFITE, AT LEAST ONE GOLD ALLOYING METAL, AND ABOUT 0.5-100 G/L OF AT LEAST ONE ELECTRICALLY CONDUCTIVE SALT OTHER THAN SAID ALKALI METAL GOLD SULFITE, SAID GOLD ALLOYING METAL AND SAID CHELATING AGENT, THE IMPROVEMENT WHEREIN WHITE GOLD IS DEPOSITED ON SAID OBJECT AND WHEREIN SAID AT LEAST ONE GOLD ALLOYING METAL IS AT LEAST ONE WATER SOLUBLE SALT OF CADMIMUM, AT LEAST ONE WATER SOLUBLE SALT OF COPPER, AT LEAST WATER SOLUBLE SALT OF NICKEL, AND ADDITIONALLY THERE IS INCORPORATED IN SAID BATH AN ORGANIC PHOSPHORUS COMOUND OF EITHER A. A COMPOUND OF THE FORMULA (R1-)(3-N)-N(-R-P(=O)(-OH)2)N IN WHICH R1 IS A HYDROGEN ATOM OR ABOUT A C1-C6 LOWER ALKYL RADICAL, R IS ABOUT A C1-C8 ALKYLENE RADICAL, AND N IS A WHOLE NUMBER OF ABOUT 1-3, OR B. AN ALKYLENE DIAMINO TETRA-(METHYLPHOSPHONIC ACID) OR A L-(HYDROXYALKYLIDENE-1,1-DIPHOSPHONIC ACID, THE ALKYLENE AND ALKYLIDENE GROUPS OF WHICH CONTAIN ABOUT 1-12 CARBON ATOMS, OR C. A WATER SOLUBLE SALT OF COMPOUNDS OF A OR B, SAID BATH HAVING A PH OF ABOUT 8.5-11, AND FURTHER WHEREIN SAID BATH CONTAINS GOLD IN AN AMOUNT OF ABOUT 1-8 G/L, CADMIUM IN AN AMOUNT OF ABOUT 0.1-30 G/L, COPPER IN AN AMOUNT OF ABOUT 0.001-0.5 G/L, NICKEL IN AN AMOUNT OF ABOUT 0.001 -10 G/L AND THE ORGANIC PHOSPHROUS COMPOUNDS IN AN AMOUNT OF ABOUT 0.01-10 G/L, WHEREIN SAID AT LEAST ONE CHELATING AGENT IS OTHER THAN A, B AND C AND IS PRESENT IN AN AMOUNT SUFFICIENT TO SUBSTANTIALLY COMPLETELY COMPLEX ALL OF THE METALS PRESENT IN THE PLATING BATH.
Claim 3
Dependent Claim 22 words
Improved bath according to claim 1 in which the organic phosphorus compound is in an amount of about 0.5 - 2 g/l.
Claim 4
Dependent Claim 15 words
Improved bath according to claim 2 in which the pH is about 9.5 - 10.2.
Claim 5
Dependent Claim 49 words
Improved bath according to claim 2 in which the amount of gold is about 3 - 5 g/l, the amount of cadmium is about 8 - 14 g/l, the amount of copper is about 0.01 - 0.08 g/l and the amount of nickel is about 4 - 6 g/l.
Claim 6
Dependent Claim 18 words
Improved bath according to claim 1 in which the water soluble gold alloying metal salts are metal sulfates.
Claim 7
Dependent Claim 17 words
Improved bath according to claim 5 in which the alkali metal gold sulfite is sodium gold sulfite.
Claim 8
Dependent Claim 29 words
Improved bath according to claim 1 in which the organic phosphorus compound is an alkylene diamino tetra-(methylphosphonic acid) in which the alkylene group has about 1 -6 carbon atoms.
Claim 9
Dependent Claim 28 words
Improved bath according to claim 1 in which the organic phosphorus compound is a 1-hydroxyalkylidene-1,1-diphosphonic acid the alkylidene group of which contains about 1 - 6 carbon atoms.
Claim 10
Dependent Claim 15 words
Improved bath according to claim 1 in which the organic phosphorus compound is 1-hydroxyethylidene-1,1-diphosphonic acid.
Claim 11
Dependent Claim 15 words
Improved bath according to claim 1 in which the pH is about 9.5 - 10.2.
Claim 12
Dependent Claim 27 words
Improved bath according to claim 1 in which the bath contains a wetting agent in an amount sufficient to reduce the surface tension of the plating bath.
Claim 13
Dependent Claim 18 words
Improved bath according to claim 1 in which the amount of gold is about 3 - 5 g/l.
Claim 14
Dependent Claim 18 words
Improved bath according to claim 1 in which the amount of cadmium is about 8 - 14 g/l.
Claim 15
Dependent Claim 18 words
Improved bath according to claim 1 in which the amount of copper is about 0.01 - 0.08 g/l.
Claim 16
Dependent Claim 18 words
Improved bath according to claim 1 in which the amount of nickel is about 4 - 6 g/l.
Claim 17
Dependent Claim 22 words
Improved bath according to claim 1 wherein said bath contains about 0.01 - 10 g/l of a water soluble salt of indium.
Claim 18
Dependent Claim 22 words
Improved bath according to claim 1 wherein said bath contains about 0.01 - 10 g/l of a water soluble salt of cobalt.
Claim 19
Dependent Claim 22 words
Improved bath according to claim 1 wherein said bath contains about 0.01 - 10 g/l of a water soluble salt of iron.
Claim 20
Dependent Claim 37 words
Improved bath according to claim 1 wherein said bath contains a water soluble salt of indium, cobalt and iron in an amount of about 0.01 - 10 g/l calculated on the basis of metal in the bath.
Claim 21
Dependent Claim 23 words
Improved bath according to claim 1 in which the organic phosphorous compound is ethylene diamino tetra-(methylphosphonic acid) or hexamethylene diamino tetra-(methyl phosphonic acid).
Claim 22
Dependent Claim 222 words
In an improved aqueous bath for the electrolytic deposition of gold or gold alloys on electrically conductive objects, said bath containing at least one chelating agent, an alkali metal gold sulfite, at least one gold alloying metal, and about 0.5 -100 g/l of at least one electrically conductive salt other than said alkali metal gold sulfite, said gold alloying metal and said chelating agent, the improvement wherein there is incorporated in said bath at least one water soluble salt of cadmium, at least one water soluble salt of copper, at least one water soluble salt of nickel, and additionally a 1-hydroxyalkylidene-1,1-diphosphonic acid, the alkylidene group of which contains 1 - 12 carbon atoms, or a water soluble salt of the diphosphonic acid; said bath having a pH of about 8.5 - 11, and further wherein said bath contains gold in an amount of about 1 - 8 g/l, cadmium in an amount of about 0.1 - 30 g/l, copper in an amount of about 0.001 - 0.5 g/l, nickel in an amount of about 0.001 - 10 g/l and the organic phosphorous compounds in an amount of about 0.01 - 10 g/l; said at least one chelating agent being other than said diphosphonic compound and present in an amount sufficient to substantially completely complex all of the metals in the plating bath.
Claim 23
Dependent Claim 222 words
In an improved aqueous bath for the electrolytic deposition of gold or gold alloys on electrically conductive objects, said bath containing at least one chelating agent, an alkali metal gold sulfite, at least one gold alloying metal, and about 0.5 -100 g/l of at least one electrically conductive salt other than said alkali metal gold sulfite, said gold alloying metal and said chelating agent, the improvement wherein there is incorporated in said bath at least one water soluble salt of cadmium, at least one water soluble salt of copper, at least one water soluble salt of nickel, and additionally a 1-hydroxyalkylidene-1,1-diphosphonic acid, the alkylidene group of which contains 1 - 12 carbon atoms, or a water soluble salt of the diphosphonic acid; said bath having a pH of about 8.5 - 11, and further wherein said bath contains gold in an amount of about 1 - 8 g/l, cadmium in an amount of about 0.1 - 30 g/l, copper in an amount of about 0.001 - 0.5 g/l, nickel in an amount of about 0.001 - 10 g/l and the organic phosphorous compounds in an amount of about 0.01 - 10 g/l; said at least one chelating agent being other than said diphosphonic compound and present in an amount sufficient to substantially completely complex all of the metals in the plating bath.
Claim 24
Dependent Claim 22 words
Improved bath according to claim 21 in which the organic phosphorus compound is in an amount of about 0.01 - 10 g/l.
Claim 25
Dependent Claim 15 words
Improved bath according to claim 22 in which the pH is about 9.5 - 10.2.
Claim 26
Dependent Claim 49 words
Improved bath according to claim 23 in which the amount of gold is about 3 - 5 g/l, the amount of cadmium is about 8 - 14 g/l, the amount of copper is about 0.01 - 0.08 g/l and the amount of nickel is about 4 - 6 g/l.
Claim 27
Dependent Claim 28 words
Improved bath according to claim 24 in which the water soluble gold alloying metal salts are metal sulfates and the alkali metal gold sulfite is sodium gold sulfite.
Claim 28
Dependent Claim 17 words
Improved bath according to claim 25 in which the alkylidene group contains 1 - 6 carbon atoms.
Claim 29
Dependent Claim 14 words
Improved bath according to claim 26 in which the phosphorous compound has the formula:
Claim 30
Dependent Claim 37 words
Improved bath according to claim 24 wherein said bath contains a water soluble salt of indium, cobalt and iron in an amount of about 0.01 - 10 g/l calculated on the basis of metal in the bath.

References Cited (Backward Citations)

US3057789A Cited
US3475292A Cited
US3672969A Cited
US3666640A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-12 1978-11-11 1979-05-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-12 1982-11-11 1983-05-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-12 1986-11-11 1987-05-13 $7700.00 Window Closed / Lapsed

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