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US3882223A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus for catalytically decomposing a solution for generating oxygen therefrom

Assignee: Acorn Associates Inc
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Filing: 1973-08-06
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Granted: 1975-05-06
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Expires: 1993-08-06
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Abstract

Abstract In the catalytic decomposition of hydrogen peroxide, nitric acid or acetic acid is added to the hydrogen peroxide in order to minimize catalyst degradation and to provide an improved oxygen production rate. For use in the areation of water in aquariums or minnow buckets, means are provided for adjusting the rate of oxygen production in accordance with temperature.

Inventors

  • 👤 Paul W Reinhardt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 01:31
CPC Classifications
C; C01; C01B; C01B13/00; C01B13/02; C01B13/0203; C01B13/0211; C01B13/0214

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 108 words
A METHOD OF GENERATING OXYGEN COMPRISING PROVIDING A WATER-BASED SOLUTION OF HYDROGEN PEROXIDE AND AN ACID WHICH REACTS WITH LEAD OXIDE TO FORM A REACTION PRODUCT SELECTED FROM THE GROUP CONSISTING OF WATER SOLUBLE LEAD SALTS, WATER, GASES INNOCUOUS TO ANIMAL LIFE AND MIXTURES THEREOF; PLACING A HYDROGEN PEROXIDE DECOMPOSITION CATLAYST COMPRISING AN EFFECTIVE QUANTITY OF CATALYTICALLY ACTIVE ELEMENTAL LEAD IN CONTACT WITH THE SOLUTION; RECOVERING OXYGEN FROM THE SOLUTION; AND MINIMIZING DEGRADATION OF CATALYST PERFORMANCE COMPRISING THE CONCURRENT STEPS OF REACTING THE CATALYTIC ELEMENTAL LEAD WITH PRODUCED OXYGEN TO FORM LEAD OXIDE AND REMOVING THE LEAD OXIDE FROM THE CATALYST BY REACTING THE SAME WITH THE ACID.
Claim 2
Independent Claim 108 words
A METHOD OF GENERATING OXYGEN COMPRISING PROVIDING A WATER-BASED SOLUTION OF HYDROGEN PEROXIDE AND AN ACID WHICH REACTS WITH LEAD OXIDE TO FORM A REACTION PRODUCT SELECTED FROM THE GROUP CONSISTING OF WATER SOLUBLE LEAD SALTS, WATER, GASES INNOCUOUS TO ANIMAL LIFE AND MIXTURES THEREOF; PLACING A HYDROGEN PEROXIDE DECOMPOSITION CATLAYST COMPRISING AN EFFECTIVE QUANTITY OF CATALYTICALLY ACTIVE ELEMENTAL LEAD IN CONTACT WITH THE SOLUTION; RECOVERING OXYGEN FROM THE SOLUTION; AND MINIMIZING DEGRADATION OF CATALYST PERFORMANCE COMPRISING THE CONCURRENT STEPS OF REACTING THE CATALYTIC ELEMENTAL LEAD WITH PRODUCED OXYGEN TO FORM LEAD OXIDE AND REMOVING THE LEAD OXIDE FROM THE CATALYST BY REACTING THE SAME WITH THE ACID.
Claim 3
Dependent Claim 11 words
The method of claim 1 wherein the acid is nitric acid.
Claim 4
Dependent Claim 19 words
The method of claim 2 wherrein the nitric acid is in the range 10-500 ppm by weight hydrogen peroxide.
Claim 5
Dependent Claim 27 words
The method of claim 3 wherein the catalyst is 6-7% sb, balance lead and the nitric acid is in the range 20-110 ppm by weight hydrogen peroxide.
Claim 6
Dependent Claim 11 words
The method of claim 1 wherein the acid is acetic acid.
Claim 7
Dependent Claim 20 words
The method of claim 5 wherein the acetic acid is in the range of 5-200 ppm by weight hydrogen peroxide.
Claim 8
Dependent Claim 25 words
The method of claim 5 wherein the catalyst is Wood''s metal and the acetic acid is in the range 5-50 ppm by weight hydrogen peroxide.
Claim 9
Dependent Claim 22 words
The method of claim 1 wherein the acid is selected from the group consisting of acetic acid, nitric acid and mixtures thereof.
Claim 10
Independent Claim 97 words
A method of generating oxygen comprising providing a catalytically decomposable water-based hydrogen peroxide solution; placing an elemental lead decomposition catalyst which reacts with produced oxygen to form lead oxide in contact with the solution and recovering oxygen from the solution; the improvement in minimizing degradation of catalyst performance and in increasing instantaneous oxygen production rate throughout a production period of 0-8 hours comprising adding to the solution an acid which reacts with lead oxide to produce reaction products selected from the group consisting of water soluble lead salts, water, gases innocuous to animal life and mixtures thereof.
Claim 11
Independent Claim 97 words
A method of generating oxygen comprising providing a catalytically decomposable water-based hydrogen peroxide solution; placing an elemental lead decomposition catalyst which reacts with produced oxygen to form lead oxide in contact with the solution and recovering oxygen from the solution; the improvement in minimizing degradation of catalyst performance and in increasing instantaneous oxygen production rate throughout a production period of 0-8 hours comprising adding to the solution an acid which reacts with lead oxide to produce reaction products selected from the group consisting of water soluble lead salts, water, gases innocuous to animal life and mixtures thereof.

References Cited (Backward Citations)

US2836570A Cited
US2627454A Cited
US3542524A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-05 1978-11-04 1979-05-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-05 1982-11-04 1983-05-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-05 1986-11-04 1987-05-06 $7700.00 Window Closed / Lapsed

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