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US3882090A Expired / Lapsed US ⏱️ 0.0 years remaining

Water-soluble polyamides from alkyleneoxy bis(propyl-amine)

Assignee: Eastman Kodak Co
•
Filing: 1974-03-20
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Granted: 1975-05-06
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Expires: 1994-03-20
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Abstract

Abstract This invention relates to novel linear water-soluble polyamides having ether linkages in the polymer chain which are comprised of components A, B and C as follows: (A) an aliphatic dicarboxylic acid selected from adipic acid, pimelic acid, suberic acid and combinations thereof, (B) a modifying amount of up to 25 mole percent of a nine carbon aliphatic dicarboxylic acid or up to 15 mole percent of 1,12-dodecanedioic acid, and (C) an aliphatic diamine having the formula H2N-C3H6-(OR)-n-O-C3H6NH2 wherein R is ethylene, 1,2-propylene or 1,3-propylene and n is an integer of 2 to about 13. These polyamides are useful as textile sizing agents, coatings, and adhesives.

Inventors

  • 👤 David R Fagerburg
  • 👤 Burns Davis
  • 👤 Charles J Kibler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 05:43
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/40

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 182 words
A POLYAMIDE CONSISTING ESSENTIALLY OF THE POLYMERIC CONDENSATION PRODUCT OF COMPONENTS (A), (B) AND (C) AS FOLLOWS: A. A DICARBOXYLIC ACID SELECTED FROM THE GROUP CONSISTING OF ADIPIC ACID, PIMELLIC ACID, SUBERIC ACID AND COMBINATIONS THEREOF, B. A MODIFYING AMOUNT OF (1) UP TO 25 MOLE PERCENT OF A NINE CARBON ATOMS ALIPHATIC DICARBOXYLIC ACID, OR (2) UP TO 15 MOLE PERCENT OF 1,12-DODECANEDIOIC ACID, SAID MOLE PERCENTS BEING BASED UPON THE TOTAL AMOUNT OF DICARBOXYLIC ACID; AND C. AN ALIPHATIC DIAMINE AT LEAST 95 MOLE PERCENT OF WHICH IS AN (ALKYLENEOXY)BIS(PROPYLENE) HAVING THE FORMULA: H2N-C3H6-OR-N-O-C3H6-NH2 WHEREIN R IS ETHYLENE, 1,2-PROPYLENE OR 1,3-PROPYLENE AND N IS AN INTEGER OF 2 TO ABOUT 13. OR COMBINATIONS THEREOF, SAID POLYAMIDE HAVING AN INHERENT VISCOSITY OF FROM 0.15 TO ABOUT 1.0 AS MEASURED AT 25*C. AT A CONCENTRATION OF 0.5 GRAMS OF SAID POLYAMIDE PER 100 ML. OF A SOLVENT CONSISTING OF 60 PERCENT BY WEIGHT PHENOL AND 40 PERCENT BY WEIGHT TETRACHLOROETHANE, SAID POLYAMIDE HAVING A RATIO OF ALKYLENEOXY TO AMIDE LINKAGES IN THE RANGE OF FROM AT LEAST ABOUT 3:2 TO ABOUT 14:2.
Claim 2
Dependent Claim 182 words
A POLYAMIDE CONSISTING ESSENTIALLY OF THE POLYMERIC CONDENSATION PRODUCT OF COMPONENTS (A), (B) AND (C) AS FOLLOWS: A. A DICARBOXYLIC ACID SELECTED FROM THE GROUP CONSISTING OF ADIPIC ACID, PIMELLIC ACID, SUBERIC ACID AND COMBINATIONS THEREOF, B. A MODIFYING AMOUNT OF (1) UP TO 25 MOLE PERCENT OF A NINE CARBON ATOMS ALIPHATIC DICARBOXYLIC ACID, OR (2) UP TO 15 MOLE PERCENT OF 1,12-DODECANEDIOIC ACID, SAID MOLE PERCENTS BEING BASED UPON THE TOTAL AMOUNT OF DICARBOXYLIC ACID; AND C. AN ALIPHATIC DIAMINE AT LEAST 95 MOLE PERCENT OF WHICH IS AN (ALKYLENEOXY)BIS(PROPYLENE) HAVING THE FORMULA: H2N-C3H6-OR-N-O-C3H6-NH2 WHEREIN R IS ETHYLENE, 1,2-PROPYLENE OR 1,3-PROPYLENE AND N IS AN INTEGER OF 2 TO ABOUT 13. OR COMBINATIONS THEREOF, SAID POLYAMIDE HAVING AN INHERENT VISCOSITY OF FROM 0.15 TO ABOUT 1.0 AS MEASURED AT 25*C. AT A CONCENTRATION OF 0.5 GRAMS OF SAID POLYAMIDE PER 100 ML. OF A SOLVENT CONSISTING OF 60 PERCENT BY WEIGHT PHENOL AND 40 PERCENT BY WEIGHT TETRACHLOROETHANE, SAID POLYAMIDE HAVING A RATIO OF ALKYLENEOXY TO AMIDE LINKAGES IN THE RANGE OF FROM AT LEAST ABOUT 3:2 TO ABOUT 14:2.
Claim 3
Dependent Claim 43 words
Polyamide according to claim 1 wherein the ratio of alkyleneoxy to amide linkages is in the range of from at least about 3:2 to about 5:2, the inherent viscosity is from about 0.25 to about 0.65, and there being none of component (B).
Claim 4
Dependent Claim 19 words
Polyamide according to claim 1 wherein the dicarboxylic acid is adipic acid and the aliphatic diamine component is 3,3''-(diethylenetrioxy)bis(propylamine).
Claim 5
Dependent Claim 11 words
Polyamide according to claim 1 wherein the aliphatic diamine is 3,3''-(diethylenetrioxy)bis(propylamine).
Claim 6
Dependent Claim 13 words
Polyamide according to claim 1 wherein the aliphatic dicarboxylic acid is adipic acid.
Claim 7
Dependent Claim 19 words
Polyamide according to claim 2 wherein the dicarboxylic acid is adipic acid and the aliphatic diamine component is 3,3''-(diethylenetrioxy)bis(propylamine).
Claim 8
Dependent Claim 11 words
Polyamide according to claim 2 wherein the aliphatic diamine is 3,3''-(diethylenetrioxy)bis(propylamine).
Claim 9
Dependent Claim 13 words
Polyamide according to claim 2 wherein the aliphatic dicarboxylic acid is adipic acid.

References Cited (Backward Citations)

US3499853A Cited
US3454534A Cited
US3509106A Cited
US3556927A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-05 1978-11-04 1979-05-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-05 1982-11-04 1983-05-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-05 1986-11-04 1987-05-06 $7700.00 Window Closed / Lapsed

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