US3882090A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Water-soluble polyamides from alkyleneoxy bis(propyl-amine)
Assignee: Eastman Kodak Co
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Filing: 1974-03-20
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Granted: 1975-05-06
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Expires: 1994-03-20
Abstract
Abstract This invention relates to novel linear water-soluble polyamides having ether linkages in the polymer chain which are comprised of components A, B and C as follows: (A) an aliphatic dicarboxylic acid selected from adipic acid, pimelic acid, suberic acid and combinations thereof, (B) a modifying amount of up to 25 mole percent of a nine carbon aliphatic dicarboxylic acid or up to 15 mole percent of 1,12-dodecanedioic acid, and (C) an aliphatic diamine having the formula H2N-C3H6-(OR)-n-O-C3H6NH2 wherein R is ethylene, 1,2-propylene or 1,3-propylene and n is an integer of 2 to about 13. These polyamides are useful as textile sizing agents, coatings, and adhesives.
Inventors
- 👤 David R Fagerburg
- 👤 Burns Davis
- 👤 Charles J Kibler
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 05:43
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/40
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
182 words
A POLYAMIDE CONSISTING ESSENTIALLY OF THE POLYMERIC CONDENSATION PRODUCT OF COMPONENTS (A), (B) AND (C) AS FOLLOWS: A. A DICARBOXYLIC ACID SELECTED FROM THE GROUP CONSISTING OF ADIPIC ACID, PIMELLIC ACID, SUBERIC ACID AND COMBINATIONS THEREOF, B. A MODIFYING AMOUNT OF (1) UP TO 25 MOLE PERCENT OF A NINE CARBON ATOMS ALIPHATIC DICARBOXYLIC ACID, OR (2) UP TO 15 MOLE PERCENT OF 1,12-DODECANEDIOIC ACID, SAID MOLE PERCENTS BEING BASED UPON THE TOTAL AMOUNT OF DICARBOXYLIC ACID; AND C. AN ALIPHATIC DIAMINE AT LEAST 95 MOLE PERCENT OF WHICH IS AN (ALKYLENEOXY)BIS(PROPYLENE) HAVING THE FORMULA: H2N-C3H6-OR-N-O-C3H6-NH2 WHEREIN R IS ETHYLENE, 1,2-PROPYLENE OR 1,3-PROPYLENE AND N IS AN INTEGER OF 2 TO ABOUT 13. OR COMBINATIONS THEREOF, SAID POLYAMIDE HAVING AN INHERENT VISCOSITY OF FROM 0.15 TO ABOUT 1.0 AS MEASURED AT 25*C. AT A CONCENTRATION OF 0.5 GRAMS OF SAID POLYAMIDE PER 100 ML. OF A SOLVENT CONSISTING OF 60 PERCENT BY WEIGHT PHENOL AND 40 PERCENT BY WEIGHT TETRACHLOROETHANE, SAID POLYAMIDE HAVING A RATIO OF ALKYLENEOXY TO AMIDE LINKAGES IN THE RANGE OF FROM AT LEAST ABOUT 3:2 TO ABOUT 14:2.
Claim 2
Dependent Claim
182 words
A POLYAMIDE CONSISTING ESSENTIALLY OF THE POLYMERIC CONDENSATION PRODUCT OF COMPONENTS (A), (B) AND (C) AS FOLLOWS: A. A DICARBOXYLIC ACID SELECTED FROM THE GROUP CONSISTING OF ADIPIC ACID, PIMELLIC ACID, SUBERIC ACID AND COMBINATIONS THEREOF, B. A MODIFYING AMOUNT OF (1) UP TO 25 MOLE PERCENT OF A NINE CARBON ATOMS ALIPHATIC DICARBOXYLIC ACID, OR (2) UP TO 15 MOLE PERCENT OF 1,12-DODECANEDIOIC ACID, SAID MOLE PERCENTS BEING BASED UPON THE TOTAL AMOUNT OF DICARBOXYLIC ACID; AND C. AN ALIPHATIC DIAMINE AT LEAST 95 MOLE PERCENT OF WHICH IS AN (ALKYLENEOXY)BIS(PROPYLENE) HAVING THE FORMULA: H2N-C3H6-OR-N-O-C3H6-NH2 WHEREIN R IS ETHYLENE, 1,2-PROPYLENE OR 1,3-PROPYLENE AND N IS AN INTEGER OF 2 TO ABOUT 13. OR COMBINATIONS THEREOF, SAID POLYAMIDE HAVING AN INHERENT VISCOSITY OF FROM 0.15 TO ABOUT 1.0 AS MEASURED AT 25*C. AT A CONCENTRATION OF 0.5 GRAMS OF SAID POLYAMIDE PER 100 ML. OF A SOLVENT CONSISTING OF 60 PERCENT BY WEIGHT PHENOL AND 40 PERCENT BY WEIGHT TETRACHLOROETHANE, SAID POLYAMIDE HAVING A RATIO OF ALKYLENEOXY TO AMIDE LINKAGES IN THE RANGE OF FROM AT LEAST ABOUT 3:2 TO ABOUT 14:2.
Claim 3
Dependent Claim
43 words
Polyamide according to claim 1 wherein the ratio of alkyleneoxy to amide linkages is in the range of from at least about 3:2 to about 5:2, the inherent viscosity is from about 0.25 to about 0.65, and there being none of component (B).
Claim 4
Dependent Claim
19 words
Polyamide according to claim 1 wherein the dicarboxylic acid is adipic acid and the aliphatic diamine component is 3,3''-(diethylenetrioxy)bis(propylamine).
Claim 5
Dependent Claim
11 words
Polyamide according to claim 1 wherein the aliphatic diamine is 3,3''-(diethylenetrioxy)bis(propylamine).
Claim 6
Dependent Claim
13 words
Polyamide according to claim 1 wherein the aliphatic dicarboxylic acid is adipic acid.
Claim 7
Dependent Claim
19 words
Polyamide according to claim 2 wherein the dicarboxylic acid is adipic acid and the aliphatic diamine component is 3,3''-(diethylenetrioxy)bis(propylamine).
Claim 8
Dependent Claim
11 words
Polyamide according to claim 2 wherein the aliphatic diamine is 3,3''-(diethylenetrioxy)bis(propylamine).
Claim 9
Dependent Claim
13 words
Polyamide according to claim 2 wherein the aliphatic dicarboxylic acid is adipic acid.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-05-05 | 1978-11-04 | 1979-05-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-05-05 | 1982-11-04 | 1983-05-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-05-05 | 1986-11-04 | 1987-05-06 | $7700.00 | Window Closed / Lapsed |