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US3881696A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for cleaning engine exhaust gases

Assignee: Azote et Produits Chimiques SA
•
Filing: 1973-02-23
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Granted: 1975-05-06
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Expires: 1993-02-23
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Abstract

Abstract For decreasing the pollutants in automobile exhaust gases there is provided a catalyst containing a ceramic carrier such as alumina combined with manganese oxide and/or chromium oxide, and impregnated thereon a mixture of platinum and a metal oxide such as nickel, cobalt or iron oxides. An aluminum salt is preferably impregnated into the ceramic carrier, and then calcined to form an aluminum oxide layer, this step being conducted prior to the introduction of platinum.

Inventors

  • 👤 Jean-Michel Lepeytre
  • 👤 Claude Paul
  • 👤 Louis Grandet
  • 👤 Louis Minjolle

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 00:35
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9445; B01D53/945; B01D53/74; B01D53/86; B01J; B01J23/00; B01J23/70; B01J23/89; B01J23/8933; B01J23/8993; Y; Y02; Y02A; Y02A50/00; Y02A50/20; Y02T; Y02T10/00; Y02T10/10; Y02T10/12

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 192 words
A CATALYST SUITABLE FOR REDUCING THE CONTENT OF POLLUTANTS IN ENGINE EXHAUST GASES, SAID CATALYST CONSISTING ESSENTIALLLY OF IN PRECENT BY WEIGHT: A. 80 TO 95% OF A CERAMIC CARRIER CONSISTING ESSENTAILLY OF A FIRED INTIMATE MIXTURE OF: I. 55 TO 98% OF A REFRACTORY MEMBER SELECTED FROM THE GROUP CONSISTING OF ALUMINA, ALUMINOSILICATE, MAGNESIUM SILICATE AND MIXTURES THEREOF, II. 2 TO 45% OF A CATALYST MEMBER SELECTED FROM THE GROUP CONSISTING OF MANGANESE OXIDE, CHROMIUM OXIDE AND MIXTURES THEREOF, AND B. 5 TO 20% CATALYST COMPONENTS LYING ON THE SURFACE OF SAID CARRIER, SAID CATALYST COMPONENTS CONSISTING ESSENTIALLY OF: I. 0.025 TO 1% OF PLATINUM II. 50 TO 99.975% OF A METAL OXIDE SELECTED FROM THE GROUP CONSISTING OF NICKEL OXIDE, COBALT OXIDE, IRON OXIDE AND MIXTURES THEREOF, AND III. 0 TO 49% OF MANGANESE OXIDE, CHROMIUM OXIDE AND MIXTURES THEREOF, SAID REFRACTORY CATALYST MEMBER AND ON AN OVERALL BASIS CONSISTING ESSENTIALLY OF IN PERCENT BY WEIGHT: 40-90% OF SAID REFRACTORY MEMBER TO 40% OF MANGANESE OXIDE, CHROMIUM OXIDE, OR MIXTURES THEREOF, 0.005 TO 0.05% OF PLATINUM, AND 5 TO 20% OF NICKEL OXIDE, COBALT OXIDE, IRON OXIDE OR MIXTURES THEREOF.
Claim 2
Dependent Claim 192 words
A CATALYST SUITABLE FOR REDUCING THE CONTENT OF POLLUTANTS IN ENGINE EXHAUST GASES, SAID CATALYST CONSISTING ESSENTIALLLY OF IN PRECENT BY WEIGHT: A. 80 TO 95% OF A CERAMIC CARRIER CONSISTING ESSENTAILLY OF A FIRED INTIMATE MIXTURE OF: I. 55 TO 98% OF A REFRACTORY MEMBER SELECTED FROM THE GROUP CONSISTING OF ALUMINA, ALUMINOSILICATE, MAGNESIUM SILICATE AND MIXTURES THEREOF, II. 2 TO 45% OF A CATALYST MEMBER SELECTED FROM THE GROUP CONSISTING OF MANGANESE OXIDE, CHROMIUM OXIDE AND MIXTURES THEREOF, AND B. 5 TO 20% CATALYST COMPONENTS LYING ON THE SURFACE OF SAID CARRIER, SAID CATALYST COMPONENTS CONSISTING ESSENTIALLY OF: I. 0.025 TO 1% OF PLATINUM II. 50 TO 99.975% OF A METAL OXIDE SELECTED FROM THE GROUP CONSISTING OF NICKEL OXIDE, COBALT OXIDE, IRON OXIDE AND MIXTURES THEREOF, AND III. 0 TO 49% OF MANGANESE OXIDE, CHROMIUM OXIDE AND MIXTURES THEREOF, SAID REFRACTORY CATALYST MEMBER AND ON AN OVERALL BASIS CONSISTING ESSENTIALLY OF IN PERCENT BY WEIGHT: 40-90% OF SAID REFRACTORY MEMBER TO 40% OF MANGANESE OXIDE, CHROMIUM OXIDE, OR MIXTURES THEREOF, 0.005 TO 0.05% OF PLATINUM, AND 5 TO 20% OF NICKEL OXIDE, COBALT OXIDE, IRON OXIDE OR MIXTURES THEREOF.
Claim 3
Dependent Claim 9 words
A catalyst according to claim 1, containing nickel oxide.
Claim 4
Dependent Claim 9 words
A catalyst according to claim 1, containing manganese oxide.
Claim 5
Dependent Claim 9 words
A catalyst according to claim 2, containing manganese oxide.
Claim 6
Dependent Claim 18 words
A catalyst according to claim 1, wherein the ceramic carrier has a specific surface lower than 30 m2/g.
Claim 7
Dependent Claim 48 words
A catalyst according to claim 1, wherein the catalyst on an overall basis comprises on a percent by weight basis 8 to 12% of an oxide of Fe, Ni or Co or mixtures thereof and 8 to 15% of an oxide of Mn or Cr or mixtures thereof.
Claim 8
Dependent Claim 38 words
A catalyst according to claim 6, wherein said 8 to 12% is comprised of at least a major amount of NiO and Wherein said 8 to 15% is comprised of at least a major amount of manganese oxide.
Claim 9
Dependent Claim 17 words
A catalyst as defined by claim 1, said ceramic carrier having deposited thereon aluminum oxide aluminum oxide.
Claim 10
Dependent Claim 24 words
A catalyst as defined by claim 8, said deposited aluminum oxide comprising on an overall basis 3 to 12% by weight of the catalyst.
Claim 11
Dependent Claim 21 words
A catalyst as defined by claim 8, said carrier having deposited thereon said aluminum oxide prior to depositing thereon said platinum.
Claim 12
Dependent Claim 14 words
A catalyst according to claim 1, wherein said refractory member consists essentially of alumina.

References Cited (Backward Citations)

US2071119A Cited
US3112277A Cited
US3230182A Cited
US3259589A Cited
US3397154A Cited
US3699683A Cited
US3741725A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-05 1978-11-04 1979-05-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-05 1982-11-04 1983-05-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-05 1986-11-04 1987-05-06 $7700.00 Window Closed / Lapsed

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