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US3880970A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing microcellular shaped pieces of dimensional accuracy, particularly shoe soles

Assignee: BAR MUBAR ES CIPOPARI KUTATO I
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Filing: 1973-02-13
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Granted: 1975-04-29
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Expires: 1993-02-13
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Abstract

Abstract The invention relates to a process for the manufacture of microcellular shaped pieces, particularly shoe soles, in several vulcanization stages. In the first step, there is compounded a stock containing an elastomer, a plastomer and/or a thermoplastic elastomer, a blowing agent, an accelerator system and usual compounding ingredients used commonly in the rubber industry, e.g. plasticizers and fillers. This stock is prevulcanized and partially cross-linked in a closed mould under pressure at a temperature and for a time determined by the accelerator system, and the prevulcanized stock is expanded. In a further vulcanization phase, this prevulcanized, expanded semiproduct is completely vulcanized in a closed mould, and finally, the completly vulcanized product is cooled under pressure in a closed mould thereby hardening the component and stabilizing the final product in its predetermined form. By the aid of the invention, it has become possible to eliminate the phenomenon of postexpansion and postshrinkage, respectively, in the case of vulcanized, microcellular product, as a result of which in the second vulcanization stage there are produced shaped pieces of high dimensional accuracy and of a low apparent density (0.2 to 0.7 g/cc) having uniformly distributed cells, and the strength properties of which comply with every practical requirement.

Inventors

  • 👤 Boris Nisonovich Dinzburg
  • 👤 Jury Alexandrovich Smetkin
  • 👤 Vladimir Iosifovich Alexenko
  • 👤 Vsevolod Andreevich Mikhailov
  • 👤 Dr Ivan Lorant
  • 👤 Gyozo Seltenreich
  • 👤 Jeno Keszei
  • 👤 Gyorgy Marton
  • 👤 Albert Balazsfai
  • 👤 Jeno Donath
  • 👤 Erno Bolcskei

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 06:31
CPC Classifications
B; B29; B29D; B29D35/00; B29D35/12; B29D35/122; B29D35/128; B29K; B29K2021/00

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 236 words
IN A PROCESS FOR PRODUCING CLOSED CELL, CELLULAR, GASEXPANDED MATERIAL WHICH COMPRISES COMPOUNDING A VULCANIZABLE STOCK CONTAINING AN ELASTOMER, A MEMBER SELECTED FROM THE GROUP CONSISTING OF A PLASTOMER, THE MELTING TEMPERATURE OF WHICH IS EQUAL TO OR LESS THAN THE TEMPERATURE OF THE FIRST VULCANIZATION STEP, AND A THERMOPLASTIC ELASTOMER, A BLOWING AGENT THE DECOMPOSITION TEMPERATURE OF WHICH IS EQUAL TO OR LESS THAN THE TEMPERATURE OF THE FIRST VULCANIZATION STEP, AND AN ACCELERATOR SYSTEM, VULCANIZING SAID STOCK IN TWO SEQUENTIAL STAGES IN A CLOSED MOLD AT ELEVATED TEMPERATURE, WHILE EXPANDING THE PREVULCANIZED STOCK AFTER THE FIRST STAGE, COOLING THE VULCANIZED MATERIAL IN SAID CLOSED MOLD, AND THEREAFTER REMOVING THE COOLED VULCANIZED MATERIAL FROM THE MOLD; THE IMPROVEMENT COMPRISING USING AN ACCELERATOR SYSTEM WHICH INCLUDES A FAST CROSS-LINKING IN THE FIRST VULCANIZATION STEP AND TOGETHER WITH THE VULCANIZATION TEMPERATURE AND VULCANIZATION TIME EFFECTS VULCANIZATION IN THE 20-70% CROSS-LINKING RANGE; CARRYING OUT BOTH THE FIRST AND THE SECOND VULCANIZATION STAGES IN A COMPLETELY FILLED MOLD UNDER AN EXTERNAL PRESSURE OF ABOUT 40-60 KG/CMHU 2 IN SAID FIRST STAGE AND ABOUT 20 KG/CM2 IN SAID SECOND STAGE, AND COOLING THE COMPLETELY VULCANIZED PRODUCT UNDER THE LATTER SAID PRESSURE IN SAID CLOSED MOLD THEREBY HARDENING THE PLASTOMER COMPONENT AND STABILIZING THE FINAL PRODUCT IN A FORM WHICH CORRESPONDS TO THE FORM OF THE CLOSED MOLD USED IN THE FINAL VULCANIZATION STEP, THUS PRODUCING A DIMENSIONALLY STABLE MICROCELLULAR MATERIAL.
Claim 2
Dependent Claim 236 words
IN A PROCESS FOR PRODUCING CLOSED CELL, CELLULAR, GASEXPANDED MATERIAL WHICH COMPRISES COMPOUNDING A VULCANIZABLE STOCK CONTAINING AN ELASTOMER, A MEMBER SELECTED FROM THE GROUP CONSISTING OF A PLASTOMER, THE MELTING TEMPERATURE OF WHICH IS EQUAL TO OR LESS THAN THE TEMPERATURE OF THE FIRST VULCANIZATION STEP, AND A THERMOPLASTIC ELASTOMER, A BLOWING AGENT THE DECOMPOSITION TEMPERATURE OF WHICH IS EQUAL TO OR LESS THAN THE TEMPERATURE OF THE FIRST VULCANIZATION STEP, AND AN ACCELERATOR SYSTEM, VULCANIZING SAID STOCK IN TWO SEQUENTIAL STAGES IN A CLOSED MOLD AT ELEVATED TEMPERATURE, WHILE EXPANDING THE PREVULCANIZED STOCK AFTER THE FIRST STAGE, COOLING THE VULCANIZED MATERIAL IN SAID CLOSED MOLD, AND THEREAFTER REMOVING THE COOLED VULCANIZED MATERIAL FROM THE MOLD; THE IMPROVEMENT COMPRISING USING AN ACCELERATOR SYSTEM WHICH INCLUDES A FAST CROSS-LINKING IN THE FIRST VULCANIZATION STEP AND TOGETHER WITH THE VULCANIZATION TEMPERATURE AND VULCANIZATION TIME EFFECTS VULCANIZATION IN THE 20-70% CROSS-LINKING RANGE; CARRYING OUT BOTH THE FIRST AND THE SECOND VULCANIZATION STAGES IN A COMPLETELY FILLED MOLD UNDER AN EXTERNAL PRESSURE OF ABOUT 40-60 KG/CMHU 2 IN SAID FIRST STAGE AND ABOUT 20 KG/CM2 IN SAID SECOND STAGE, AND COOLING THE COMPLETELY VULCANIZED PRODUCT UNDER THE LATTER SAID PRESSURE IN SAID CLOSED MOLD THEREBY HARDENING THE PLASTOMER COMPONENT AND STABILIZING THE FINAL PRODUCT IN A FORM WHICH CORRESPONDS TO THE FORM OF THE CLOSED MOLD USED IN THE FINAL VULCANIZATION STEP, THUS PRODUCING A DIMENSIONALLY STABLE MICROCELLULAR MATERIAL.
Claim 3
Dependent Claim 84 words
A process as claimed in claim 1, in which said first vulcanization step is conducted in said closed mold and said material occupies less than all of the volume of said closed mold in said first stage, and applying said pressure in said first stage by introducing a liquid into said closed mold to surround said material, and thereafter discharging said liquid from said closed mold after said first stage whereupon said material expands and completely fills said closed mold for said second stage.
Claim 4
Dependent Claim 25 words
A process as claimed in claim 2, wherein said liquid is heated whereby both said pressure and said temperature required for vulcanization are simultaneously ensured.

References Cited (Backward Citations)

US2296305A Cited
US2297022A Cited
US2570182A Cited
US2650390A Cited
US3003192A Cited
US3751534A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-04-28 1978-10-28 1979-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-04-28 1982-10-28 1983-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-04-28 1986-10-28 1987-04-29 $7700.00 Window Closed / Lapsed

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