← Back to Patent Explorer
US3880771A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous suspension vehicle useful in suspension polymerization system for spheres

Assignee: Normac Inc
•
Filing: 1972-01-17
•
Granted: 1975-04-29
•
Expires: 1992-01-17
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract There is disclosed an aqueous suspension vehicle consisting essentially of water having dissolved therein a water-soluble suspending agent, such as one or more hydroxyethylcelluloses, in a concentration below about 0.4 weight percent, and about 0.01 to about 0.5 percent of a water-soluble organic solvent for said suspending agent, such as dimethylformamide.

Inventors

  • 👤 Max Klein

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 14:51
CPC Classifications
C; C08; C08F; C08F12/00; C08F12/02; C08F12/04; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/06; Y10S526/00; Y10S526/909

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 199 words
AN AQUEOUS SUSPENSION VEHICLE USEFUL IN SUSPENSION POLYMERIZATION OF A STYRENE-MONOMER IN THE PRESENCE OF A STYRENEMONOMER-POLYMERIZATION EFFECTIVE AMOUNT OF A STYRENEMONOMER-POLYMERIZATION FREE RADICAL-PROVIDING CATALYST, WHICH SUSPENSION CONSISTS ESSENTIALLY OF (A) WATER AND DISSOLVED THEREIN (B) A WATER-SOLUBLE SUSPENDING AGENT INERT TO REACTION WITH STYRENE, WHICH IS AT LEAST ONE OF (I) A HYDROXYETHYLCELLULOSE HAVING A VISCOSITY WITHIN THE RANGE OF ONE WHOSE 2 PERCENT BY WEIGHT, ON DRY BASIS, AQUEOUS SOLUTION AT 20*C. HAS A HOOPLER VISCOSITY OF FROM 6175 TO 7600 CENTIPOISES, (II) A HYDROXYETHYLCELLULOSE WHOSE SUCH 5 PERCENT AQUEOUS SOLUTION AT 20*C. HAS A HOOPLER VISCOSITY OF FROM 120 TO 160 CENTIPOISES, (III) CARBOXYMETHYLCELLULOSE, (IV) POLYACRYLIC ACID, (V) POLYMETHACRYLIC ACID, (VI) THE SODIUM OR AMMONIUM SALT OF ANY OF THE CARBOXYLIC ACID SUBSTANCES (III), (IV), AND (V), AND (VII) POLYVINYL ALCOHOL; SAID SUSPENDING AGENT BEING PRESENT IN A CONCENTRATION ABOVE THAT WHICH WILL ALLOW THE PRODUCED STYRENE-POLYMER TO AGGLOMERATE UNDER THE POLYMERIZATION CONDITIONS AND BELOW ABOUT 0.4 WEIGHT PERCENT, AND (C) FROM ABOUT 0.01 TO ABOUT 0.5 PERCENT OF A WATER-SOLUBLE ORGANIC SOLVENT FOR SAID SUSPENDING AGENT, WHICH SOLVENT IS SELECTED FROM THE GROUP CONSISTING OF FORMIC ACID, DIMETHYLFORMAMIDE, DIMETHYL-ACETAMIDE, TETRAHYDROUFURAN, ETHYLENEDIAMINE, DIETHYLENETRIAMINE, 2-BROMOPYRIDINE, AND 3-CYANOPYRIDINE.
Claim 2
Dependent Claim 199 words
AN AQUEOUS SUSPENSION VEHICLE USEFUL IN SUSPENSION POLYMERIZATION OF A STYRENE-MONOMER IN THE PRESENCE OF A STYRENEMONOMER-POLYMERIZATION EFFECTIVE AMOUNT OF A STYRENEMONOMER-POLYMERIZATION FREE RADICAL-PROVIDING CATALYST, WHICH SUSPENSION CONSISTS ESSENTIALLY OF (A) WATER AND DISSOLVED THEREIN (B) A WATER-SOLUBLE SUSPENDING AGENT INERT TO REACTION WITH STYRENE, WHICH IS AT LEAST ONE OF (I) A HYDROXYETHYLCELLULOSE HAVING A VISCOSITY WITHIN THE RANGE OF ONE WHOSE 2 PERCENT BY WEIGHT, ON DRY BASIS, AQUEOUS SOLUTION AT 20*C. HAS A HOOPLER VISCOSITY OF FROM 6175 TO 7600 CENTIPOISES, (II) A HYDROXYETHYLCELLULOSE WHOSE SUCH 5 PERCENT AQUEOUS SOLUTION AT 20*C. HAS A HOOPLER VISCOSITY OF FROM 120 TO 160 CENTIPOISES, (III) CARBOXYMETHYLCELLULOSE, (IV) POLYACRYLIC ACID, (V) POLYMETHACRYLIC ACID, (VI) THE SODIUM OR AMMONIUM SALT OF ANY OF THE CARBOXYLIC ACID SUBSTANCES (III), (IV), AND (V), AND (VII) POLYVINYL ALCOHOL; SAID SUSPENDING AGENT BEING PRESENT IN A CONCENTRATION ABOVE THAT WHICH WILL ALLOW THE PRODUCED STYRENE-POLYMER TO AGGLOMERATE UNDER THE POLYMERIZATION CONDITIONS AND BELOW ABOUT 0.4 WEIGHT PERCENT, AND (C) FROM ABOUT 0.01 TO ABOUT 0.5 PERCENT OF A WATER-SOLUBLE ORGANIC SOLVENT FOR SAID SUSPENDING AGENT, WHICH SOLVENT IS SELECTED FROM THE GROUP CONSISTING OF FORMIC ACID, DIMETHYLFORMAMIDE, DIMETHYL-ACETAMIDE, TETRAHYDROUFURAN, ETHYLENEDIAMINE, DIETHYLENETRIAMINE, 2-BROMOPYRIDINE, AND 3-CYANOPYRIDINE.
Claim 3
Dependent Claim 25 words
An aqueous suspension vehicle as claimed in claim 1, wherein the styrene-monomer is styrene, and said suspending agent is at least one of said hydroxyethylcelluloses.
Claim 4
Dependent Claim 43 words
An aqueous suspension vehicle as claimed in claim 1, wherein the suspending agent is a mixture of approximately equal parts of each of said hydroxyethylcelluloses having the respective viscosities of those at the beginning and end of the range expressed in claim 1.
Claim 5
Dependent Claim 15 words
An aqueous suspension vehicle as claimed in claim 2, wherein said organic solvent is dimethylformamide.
Claim 6
Dependent Claim 26 words
An aqueous suspension vehicle as claimed in claim 4, wherein the dimethylformamide is replaced in part or entirely by one or both of dimethylacetamide or tetrahydrofuran.

References Cited (Backward Citations)

US2508341A Cited
US3186975A Cited
US3280089A Cited
US3328374A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-04-28 1978-10-28 1979-04-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-04-28 1982-10-28 1983-04-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-04-28 1986-10-28 1987-04-29 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag