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US3879319A Expired / Lapsed US ⏱️ 0.0 years remaining

Silicone resin molding compositions

Assignee: Shin-Etsu Chemical Co Ltd
•
Filing: 1973-02-02
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Granted: 1975-04-22
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Expires: 1993-02-02
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Abstract

Abstract Silicone resin compositions comprising an ester-modified organopolysiloxane resin which is produced by modifying an organopolysiloxane resin containing substituted or unsubstituted silicon-bonded organic monovalent hydrocarbon groups, the ratio of the organic groups to silicon atoms being from 1:1 to 1.6:1, with at least one ester having molecular weight exceeding 300 and being a condensation product of an aliphatic polyol and an organocarboxylic acid, an inorganic filler, and a curing catalyst. They are suitable especially for molding transfer molding compositions to give articles having improved moisture resistance and adhesive ability to metallic surfaces and also a fine texture with few microvoids.

Inventors

  • 👤 Yasuhiko Sato
  • 👤 Yasuaki Hara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 05:22
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08L83/06; C08G; C08G77/00; C08G77/04; C08G77/38

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 187 words
A silicone resin molding composition comprising essentially (a) an ester-modified organopolysiloxane resin which is produced by modifying an organopolysiloxane resin containing substituted or unsubstituted silicon-bonded organic monovalent hydrocarbon groups, the ratio of the organic groups to silicon atoms being from 1:1 to 1.6:1, and hydroxy groups bonded to silicon atoms in an amount larger than 0.25% by weight, with at least one ester having molecular weight exceeding 300 and produced by the condensation reaction of an aliphatic alcohol and an organocarboxylic acid, said ester-modified organopolysiloxane resin being produced by heating the mixture of 100 parts by weight of said organopolysiloxane resin and from 3 to 30 parts by weight of said ester at an elevated temperature, (b) an inorganic filler selected from the group consisting of glass powder, asbestos, wollastonite, diatomaceous earth, euartz powder, clay, fumed silica, precipitated silica, zirconium silicate, magnesium silicate, lithium silicate, and aluminum silicate, and (c) a curing catalyst wherein said curing catalyst is selected from the group consisting of inorganic and organic salt of lead, cobalt and manganese and mixtures thereof with polyols, organic carboxylic acids, ammonium carboxylates or carboxylic acid anhydrides.
Claim 2
Dependent Claim 187 words
A silicone resin molding composition comprising essentially (a) an ester-modified organopolysiloxane resin which is produced by modifying an organopolysiloxane resin containing substituted or unsubstituted silicon-bonded organic monovalent hydrocarbon groups, the ratio of the organic groups to silicon atoms being from 1:1 to 1.6:1, and hydroxy groups bonded to silicon atoms in an amount larger than 0.25% by weight, with at least one ester having molecular weight exceeding 300 and produced by the condensation reaction of an aliphatic alcohol and an organocarboxylic acid, said ester-modified organopolysiloxane resin being produced by heating the mixture of 100 parts by weight of said organopolysiloxane resin and from 3 to 30 parts by weight of said ester at an elevated temperature, (b) an inorganic filler selected from the group consisting of glass powder, asbestos, wollastonite, diatomaceous earth, euartz powder, clay, fumed silica, precipitated silica, zirconium silicate, magnesium silicate, lithium silicate, and aluminum silicate, and (c) a curing catalyst wherein said curing catalyst is selected from the group consisting of inorganic and organic salt of lead, cobalt and manganese and mixtures thereof with polyols, organic carboxylic acids, ammonium carboxylates or carboxylic acid anhydrides.
Claim 3
Dependent Claim 189 words
A SILICONE RESIN MOLDING COMPOSITION COMPRISING ESSENTIALLY (A) AN ESTER-MODIFIED ORGANOPOLYSILOXANE RESIN WHICH IS PRODUCED BY MODIFYING AN ORGANOPOLYSILOXANE RESIN CONTAINING SUBSTITUTED OR UNSUBSTITUTED SILICONE-BONDED ORGANIC MONOVALENT HYDROCARBON GROUPS, THE RATIO OF THE ORGANIC GROUPS TO SILICON ATOMS BEING FROM 1:1 TO 1.6:1, AND HYDROXY GROUPS BONDED TO SILICON ATOMS IN AN AMOUNT LARGER THAN 0.25% BY WEIGHT, WITH AT LEAST ONE ESTER HAVING MOLECULAR EXCEEDING 300 AND PRODUCED BY THE CONDENSATION REACTION OF AN ALIPHATIC ALCOHOL AND AN ORGANOCARBOXYLIC ACID, SAID ESTERMODIFIED ORGANOPOLYSILOXANE RESIN BEING PRODUCED BY HEATING THE MIXTURE OF 100 PARTS BY WEIGHT OF SAID ORGANOPOLYSILOXANE RESIN AND FROM 3 TO 30 PARTS BY WEIGHT OF SAID ESTER AT AN ELEVATED TEMPERATURE, (B) AN INORGANIC FILLER SELECTED FROM THE GROUP CONSISTING OF GLASS POWDER, ASBERTOS, WOLLASTONITE, DIATOMACEOUS EARTH, EUARTZ POWDER, CLAY, DUMED, SILICA, PRECIPITATED SILICA, ZIRCONIUM SILICATE, AND (C) A CURING CATALYSTWHEREIN SAID AND ALUMINUM SILICATE, AND (C) A CURING CATALYST WHEREIN SAID CURING CATALYST IS SELECTED FROM THE GROUP CONSISTING OF INORGANIC AND ORGANIC SALT OF LEAD, COBALT AND MAG NGANESE AND MIXTURES THEREOF WITH POLYOLS, ORGANIC CARBOCYLIC ACIDS, AMMONIUM CARBOXYLATES OR CATARBOXYLIC ACID ANHYDRIES.
Claim 4
Dependent Claim 189 words
A SILICONE RESIN MOLDING COMPOSITION COMPRISING ESSENTIALLY (A) AN ESTER-MODIFIED ORGANOPOLYSILOXANE RESIN WHICH IS PRODUCED BY MODIFYING AN ORGANOPOLYSILOXANE RESIN CONTAINING SUBSTITUTED OR UNSUBSTITUTED SILICONE-BONDED ORGANIC MONOVALENT HYDROCARBON GROUPS, THE RATIO OF THE ORGANIC GROUPS TO SILICON ATOMS BEING FROM 1:1 TO 1.6:1, AND HYDROXY GROUPS BONDED TO SILICON ATOMS IN AN AMOUNT LARGER THAN 0.25% BY WEIGHT, WITH AT LEAST ONE ESTER HAVING MOLECULAR EXCEEDING 300 AND PRODUCED BY THE CONDENSATION REACTION OF AN ALIPHATIC ALCOHOL AND AN ORGANOCARBOXYLIC ACID, SAID ESTERMODIFIED ORGANOPOLYSILOXANE RESIN BEING PRODUCED BY HEATING THE MIXTURE OF 100 PARTS BY WEIGHT OF SAID ORGANOPOLYSILOXANE RESIN AND FROM 3 TO 30 PARTS BY WEIGHT OF SAID ESTER AT AN ELEVATED TEMPERATURE, (B) AN INORGANIC FILLER SELECTED FROM THE GROUP CONSISTING OF GLASS POWDER, ASBERTOS, WOLLASTONITE, DIATOMACEOUS EARTH, EUARTZ POWDER, CLAY, DUMED, SILICA, PRECIPITATED SILICA, ZIRCONIUM SILICATE, AND (C) A CURING CATALYSTWHEREIN SAID AND ALUMINUM SILICATE, AND (C) A CURING CATALYST WHEREIN SAID CURING CATALYST IS SELECTED FROM THE GROUP CONSISTING OF INORGANIC AND ORGANIC SALT OF LEAD, COBALT AND MAG NGANESE AND MIXTURES THEREOF WITH POLYOLS, ORGANIC CARBOCYLIC ACIDS, AMMONIUM CARBOXYLATES OR CATARBOXYLIC ACID ANHYDRIES.
Claim 5
Dependent Claim 33 words
The compositions as claimed in claim 1 wherein said ester-modified organopolysiloxane resin is produced by modifying 100 parts of said organopolysiloxane resin with from 5 to 20 parts by weight of said ester.
Claim 6
Dependent Claim 55 words
The composition as claimed in claim 1 wherein said ester-modified organopolysiloxane resin is produced by modifying said organopolysiloxane with at least one ester having a molecular weight exceeding 300, produced by the condensation reaction of an aliphatic alcohol and an organic carboxylic acid and containing an ester of glycerine and an unsaturated higher carboxylic acid.
Claim 7
Dependent Claim 37 words
The composition as claimed in claim 1 wherein said ester-modified organopolysiloxane is produced by modifying said organopolysiloxane resin with at least one ester having a molecular weight exceeding 300 and having an acid value not exceeding 50.
Claim 8
Dependent Claim 60 words
The composition as claimed in claim 1 wherein said ester-modified organopolysiloxane resin is produced by adding to said organopolysiloxane resin at least one ester having a molecular weight exceeding 300, produced by the condensation reactions of an aliphatic alcohol and an organic carboxylic acid and containing an ester of glycerine and an unsaturated higher carboxylic acid and heating the mixture.
Claim 9
Dependent Claim 25 words
The composition as claimed in claim 1 which comprises a blended mixture with aluminium, calcium, zinc and cobalt salts of stearic acid, waxes and/or stabilizers.

References Cited (Backward Citations)

US3208961A Cited
US3264260A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-04-21 1978-10-21 1979-04-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-04-21 1982-10-21 1983-04-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-04-21 1986-10-21 1987-04-22 $7700.00 Window Closed / Lapsed

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