US3876735A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of manufacturing an artificial paper
Assignee: UCB SA
•
Filing: 1971-06-29
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Granted: 1975-04-08
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Expires: 1991-06-29
Abstract
Abstract The present invention relates to the production of artificial paper of improved physical characteristics yet which retains the advantageous properties of cellulose paper. This novel artificial paper is comprised of (a) at least one of a specific class of rigid polyolefins, (b) at least one specific class of polymers incompatible with the rigid polyolefin and (c) at least one of a specific class of macromolecular materials which produce compatability of (a) and (b).
Inventors
- 👤 Walter Bontinck
- 👤 Coster Willy De
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 23:57
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08K; C08K3/00; C08K3/01; C08K3/013; C08K3/18; C08K3/20; C08K3/22; C08K3/24; C08K3/26; C08K5/00; C08L23/04; C08L23/06; C08L23/08; C08L23/0807; C08L23/0815; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/10; C08L9/00; C08L91/00; C08L2205/00; C08L2205/03; C08L2205/035; C08L2207/00; C08L2207/06; C08L2207/062
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
274 words
A PROCESS FOR THE MANUFACTURE OF ARTIFICIAL PAPER REQUIRING NEITHER CALENDERING NOR BIORIENTATION, WHICH COMPRISES HOMOGENIZING IN A CONVENTIONAL ROTARY MIXER A COMPOSITION CONTAINING: 40 TO 80 PERCENT BY WEIGHT OF AT LEAST ONE RIGID POLYOLEFIN (A) SELECTED FROM THE GROUP CONSISTING OF HOMOPOLYMERS AND COPOLYMERS OF ETHYLENE, PROPYLENE, AND BUTYLENE AND ALSO MIXTURES THEREOF, AND HAVING A MELT INDEX OF AT MOST 1 DG./MIN., 5 TO 30 PERCENT BY WEIGHT OF AT LEAST ONE POLYMER (B) WHICH IS INCOMPATIBLE WITH THE RIGID POLYOLEFIN (A) AND WHICH WHEN EXTRUDED BY ITSELF PRODUCES A BRITTLE FILM WHICH HAS A MELT INDEX LOWER THAN 10 DG./MIN., THE POLYMER (B) BEING SELECTED FROM THE GROUP CONSISTING OF HOMOPOLYMERS AND COPOLYMERS CONTAINING A PREPONDERANT AMOUNT OF STYRENE AN AMOUNT WITHIN THE RANGE OF 20 TO 25 PERCENT BY WEIGHT OF A MACROMOLECULAR MATERIAL (C), SAID AMOUNT BEING SUFFICIENT TO PRODUCE COMPATIBILITY BETWEEN (A) AND (B), SELECTED FROM THE GROUP CONSISTING OF: COPOLYMERS OF T LEAST ONE MONOMER SELECTED FROM THE GROUP CONSISTING OF ETHYLENE, PROPYLENE, AND GROUP CONAND AT LEAST ONE MONOMER SELECTED FROM THE GROUP CONSISTING OF ISOBUTYLENE, BUTADIENE, AND ISOPRENE, AND SAID MACROMOLECULAR MATERIAL HAVING A MELT INDEX OF AT MOST 2 DG/MIN., 5 TO 45 PERCENT BY WEIGHT OF AN INORGANIC FILLER (D) HAVING A GRANULOMETRY LOWER THAN 50 MICRONS, 0 TO 10 PERCENT BY WEIGHT OF ADJUVANTS (E) SELECTED FROM THE GROUP CONSISTING OF ANTIOXIDIZING AGENTS, THERMAL STABILIZERS, OPTICAL BLEACHING AGENT, PIGMENTS, COLORING MATERIALS, ANTISTATIC AGENTS, AND LUBRICANTS, THE MIXTURE THUS HOMOGENIZED BEING SUBJECTED TO EXTRUSION TO OBTAIN AN ARTIFICAL PAPER AND THE ARTIFICAL PAPER THUS, OBTAINED, IF DESIRED, BEING SUBJECTED TO SURFACE TREATMENT.
Claim 2
Dependent Claim
274 words
A PROCESS FOR THE MANUFACTURE OF ARTIFICIAL PAPER REQUIRING NEITHER CALENDERING NOR BIORIENTATION, WHICH COMPRISES HOMOGENIZING IN A CONVENTIONAL ROTARY MIXER A COMPOSITION CONTAINING: 40 TO 80 PERCENT BY WEIGHT OF AT LEAST ONE RIGID POLYOLEFIN (A) SELECTED FROM THE GROUP CONSISTING OF HOMOPOLYMERS AND COPOLYMERS OF ETHYLENE, PROPYLENE, AND BUTYLENE AND ALSO MIXTURES THEREOF, AND HAVING A MELT INDEX OF AT MOST 1 DG./MIN., 5 TO 30 PERCENT BY WEIGHT OF AT LEAST ONE POLYMER (B) WHICH IS INCOMPATIBLE WITH THE RIGID POLYOLEFIN (A) AND WHICH WHEN EXTRUDED BY ITSELF PRODUCES A BRITTLE FILM WHICH HAS A MELT INDEX LOWER THAN 10 DG./MIN., THE POLYMER (B) BEING SELECTED FROM THE GROUP CONSISTING OF HOMOPOLYMERS AND COPOLYMERS CONTAINING A PREPONDERANT AMOUNT OF STYRENE AN AMOUNT WITHIN THE RANGE OF 20 TO 25 PERCENT BY WEIGHT OF A MACROMOLECULAR MATERIAL (C), SAID AMOUNT BEING SUFFICIENT TO PRODUCE COMPATIBILITY BETWEEN (A) AND (B), SELECTED FROM THE GROUP CONSISTING OF: COPOLYMERS OF T LEAST ONE MONOMER SELECTED FROM THE GROUP CONSISTING OF ETHYLENE, PROPYLENE, AND GROUP CONAND AT LEAST ONE MONOMER SELECTED FROM THE GROUP CONSISTING OF ISOBUTYLENE, BUTADIENE, AND ISOPRENE, AND SAID MACROMOLECULAR MATERIAL HAVING A MELT INDEX OF AT MOST 2 DG/MIN., 5 TO 45 PERCENT BY WEIGHT OF AN INORGANIC FILLER (D) HAVING A GRANULOMETRY LOWER THAN 50 MICRONS, 0 TO 10 PERCENT BY WEIGHT OF ADJUVANTS (E) SELECTED FROM THE GROUP CONSISTING OF ANTIOXIDIZING AGENTS, THERMAL STABILIZERS, OPTICAL BLEACHING AGENT, PIGMENTS, COLORING MATERIALS, ANTISTATIC AGENTS, AND LUBRICANTS, THE MIXTURE THUS HOMOGENIZED BEING SUBJECTED TO EXTRUSION TO OBTAIN AN ARTIFICAL PAPER AND THE ARTIFICAL PAPER THUS, OBTAINED, IF DESIRED, BEING SUBJECTED TO SURFACE TREATMENT.
Claim 3
Dependent Claim
26 words
A process according to claim 1, in which the polyolefin (A) is selected from the group consisting of high density polyethylene, isotactic polypropylene, and isotactic polybutene.
Claim 4
Dependent Claim
34 words
A process according to claim 1, in which the polyolefin (A) is a physical mixture of at least two polyolefins selected from the group consisting of high density polyethylene, isotactic polypropylene, and isotactic polybutene.
Claim 5
Dependent Claim
30 words
A process according to claim 1, in which the polyolefin (A) is a copolymer obtained from at least two olefins selected from the group consisting of ethylene, propylene and butylene.
Claim 6
Dependent Claim
49 words
A process according to claim 1, in which the polymer (B) is constituted by a mixture containing a major amount of a homopolymer of styrene and a minor amount of a homopolymer obtained by polymerization of an olefinic compound selected from the group consisting of isobutylene, butadiene, and isoprene.
Claim 7
Dependent Claim
42 words
A process according to claim 1, in which the polymer (B) is a copolymer obtained by copolymerization of a major amount of styrene and a minor amount of a polymerizable olefinic monomer selected from the group consisting of isobutylene, butadiene, and isoprene.
Claim 8
Dependent Claim
23 words
A process according to claim 1, in which the polymer (B) is plasticized with 0.1 to 30 percent by weight of a plasticizer.
Claim 9
Dependent Claim
28 words
A process according to claim 1, in which the macromolecular material (C) is selected from the group consisting of a 50/50 ethylene-isobutylene copolymer and a 75/25 ethylene-butadiene copolymer.
Claim 10
Dependent Claim
36 words
A process according to claim 1, in which the inorganic filler (D) is selected from the group consisting of talc, titanium dioxide, kaolin, zeolites, silica, zinc oxide, natural or precipitated calcium carbonate, magnesium carbonate, and barytine.
Claim 11
Dependent Claim
39 words
A process according to claim 1, in which the thermal stabilizer used as adjuvant (E) is selected from the group consisting of diphenylthiourea, alpha-phenyl-indol, barium palmitate, cadmium palmitate, zinc palmitate, barium stearate, cadmium stearate, zinc stearate, and tris-nonylphenyl phosphite.
Claim 12
Dependent Claim
27 words
A process according to claim 1, in which the antioxidizing agent used as adjuvant (E) is selected from the group consisting of 4,4''-thio-bis(6-t-butyl-meta-cresol), 4,4''-methylene-bis(2,6-di-t-butylphenol), and butylated hydroxytoluenes.
Claim 13
Dependent Claim
26 words
A process according to claim 1, in which the optical bleaching agent used as adjuvant (E) is selected from the class of sulfonated derivatives of stilbene.
Claim 14
Dependent Claim
30 words
A process according to claim 1, in which the organic coloring agent used as adjuvant (E) is selected from the group consisting of phthalocyanines, disazoic coloring agents, and chlorinated indanthrenes.
Claim 15
Dependent Claim
28 words
A process according to claim 1, in which the pigment used as adjuvant (E) is selected from the group consisting of zinc chromate, cadmium sulfide, and iron oxide.
Claim 16
Dependent Claim
28 words
A process according to claim 1, in which the lubricant used as adjuvant (E) is selected from the group consisting of magnesium stearate, calcium stearate, and paraffin oil.
Claim 17
Dependent Claim
26 words
A process according to claim 1, in which the mixing of the components A,B,C,D, and E in the rotary mixer is carried out at ambient temperature.
Claim 18
Dependent Claim
20 words
A process according to claim 1, in which the extrusion is carried out at a temperature between 100.degree. and 290.degree.C.
Claim 19
Dependent Claim
22 words
A process according to claim 1, in which the surface treatment to which the artificial paper is subjected is a flame treatment.
Claim 20
Dependent Claim
24 words
A process according to claim 1, in which the surface treatment to which the artificial paper is subjected is a treatment by corona effect.
Claim 21
Dependent Claim
24 words
A process according to claim 1, in which the surface treatment to which the artificial paper is subjected is a treatment by oxidizing agents.
Claim 22
Dependent Claim
18 words
A process according to claim 1, in which the artificial paper is additionally subjected to an embossing operation.
References Cited (Backward Citations)
US3154461A
Cited
US3632674A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-04-07 | 1978-10-07 | 1979-04-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-04-07 | 1982-10-07 | 1983-04-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-04-07 | 1986-10-07 | 1987-04-08 | $7700.00 | Window Closed / Lapsed |