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US3876730A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing binary or ternary graft-copolymer

Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1973-01-29
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Granted: 1975-04-08
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Expires: 1993-01-29
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Abstract

Abstract A binary or ternary graft-copolymer excellent in both tensile strength and impact resistance is obtained by the process for producing a binary or ternary graft-copolymer consisting essentially of an ethylene-propylene rubber and an aromatic vinyl compound or of an ethylene-propylene rubber, an aromatic vinyl compound, and a vinyl cyanide compound, characterized by subjecting these materials to solution polymerization in a mixed solvent comprising an aliphatic hydrocarbon solvent capable of dissolving the ethylene-propylene rubber and a polar solvent capable of dissolving a poly-(aromatic vinyl compound) or a copolymer of the aromatic vinyl compound and the vinyl cyanide compound.

Inventors

  • 👤 Masayoshi Morimoto
  • 👤 Tetsutaro Sanjiki
  • 👤 Hideki Horiike
  • 👤 Takeo Oyamada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 15:46
CPC Classifications
C; C08; C08F; C08F255/00; C08F255/02

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 293 words
A PROCESS FOR PRODUCING A BINARY OR TERNARY GRAFTCOPOLYMER CONSISTING ESSENTIALLY OF AN ETHYLENE-PROPYLENE RUBBER AND AN AROMATIC VINYL COMPOUND OR OF AN ETHYLENEPROPYLENE RUBBER, AN AROMATIC VINYL COMPOUND AND A VINYL CYANIDE COMPOUND, THE ETHYLENE-PROPYLENE RUBBER COMPRISING ETHYLENE AND PROPYLENE IN A MOLAR RATIO OF 5:1 TO 1:2 AND BEING SELECTED FROM THE GROUP CONSISTING OF TWO-COMPONENT POLYMER COMPRISING ETHYLENE AND PROPYLENE AND ETHYLENEPROPYLENE-DIENE TERPOLYMER CONTAINING AS A THIRD COMPONENT A DIENE SELECTED FROM THE GROUP CONSISTING OF DICYCLOPENTADIENE, ETHYLIDENENORBORENE, 1,4-HEXADIENE, 1,3CYCLOOCTADIENE, 1,5-HEXADIENE, 1,7-OCTADIENE OR 1,4PENTADIENE AND A PROPORTION OF THE DIENE COMPONENT BEING 4 TO 50 IN TERMS OF IODINE VALUE, THE AROMATIC VINYL COMPOUND BEING SELECTED FROM THE GROUP CONSISTING OF STYRENE, AMETHYLSTYRENE, A-CHLOROSTYRENE, AND DIMETHYLSTYRENE, AND THE VINYL CYANIDE COMPOUND BEING SELECTED FROM THE GROUP CONSISTING OF ACRYLONITRILE AND METHACRYLONITRILE, WHICH COMPRISES SUBJECTING THESE MATERIALS TO SOLUTION POLYMERIZATION IN THE PRESENCE OF A RADICAL CATALYST AT A TEMPERATURE OF 50* TO 120*C FOR 5 TO 25 HOURS IN A MIXED SOLVENT COMPRISING 5 TO 95% BY WEIGHT OF AN ALIPHATIC HYDROCARBON SOLVENT CAPABLE OF DISSOLVING THE ETHYLENE-PROPYLENE RUBBER AND 95 TO 5% BY WEIGHT OF A POLAR SOLVENT CAPABLE OF DISSOLVING A POLY-(AROMATIC VINYL COMPOUND) IN THE CASE OF THE BINARY GRAFT-COPOLYMER OR OF DISSOLVING A COPOLYMER OF THE AROMATIC VINYL COMPOUND AND THE VINYL CYANIDE COMPOUND IN THE CASE OF THE TERNARY GRAFTCOPOLYMER, THE AIPHATIC HYDROCARBON SOLVENT BEING SELECTED FROM THE GROUP CONSISTING OF PARAFFINS AND CYCLOPARAFFINS HAVING 5 TO 10 CARBON ATOMS, CYCLOPENTANES HAVING SUBSTITUENT ALKYL GROUPS OF 1 TO 4 CARBON ATOMS, AND CYCLOHEXANES HAVING SUBSTITUENT ALKYL GROUPS OF 1 TO 4 CARBON ATOMS, AND THE POLAR SOLVENT BEING SELECTED FROM THE GROUP CONSISTING OF KETONES, ESTERS, ETHER, CHLORINE-SUBSTITUTED ALIPHATIC HYDROCARBONS, NITROGEN-CONTAINING HYDROCARBONS, AND SULFURCONTAINING HYDROCARBONS.
Claim 2
Dependent Claim 293 words
A PROCESS FOR PRODUCING A BINARY OR TERNARY GRAFTCOPOLYMER CONSISTING ESSENTIALLY OF AN ETHYLENE-PROPYLENE RUBBER AND AN AROMATIC VINYL COMPOUND OR OF AN ETHYLENEPROPYLENE RUBBER, AN AROMATIC VINYL COMPOUND AND A VINYL CYANIDE COMPOUND, THE ETHYLENE-PROPYLENE RUBBER COMPRISING ETHYLENE AND PROPYLENE IN A MOLAR RATIO OF 5:1 TO 1:2 AND BEING SELECTED FROM THE GROUP CONSISTING OF TWO-COMPONENT POLYMER COMPRISING ETHYLENE AND PROPYLENE AND ETHYLENEPROPYLENE-DIENE TERPOLYMER CONTAINING AS A THIRD COMPONENT A DIENE SELECTED FROM THE GROUP CONSISTING OF DICYCLOPENTADIENE, ETHYLIDENENORBORENE, 1,4-HEXADIENE, 1,3CYCLOOCTADIENE, 1,5-HEXADIENE, 1,7-OCTADIENE OR 1,4PENTADIENE AND A PROPORTION OF THE DIENE COMPONENT BEING 4 TO 50 IN TERMS OF IODINE VALUE, THE AROMATIC VINYL COMPOUND BEING SELECTED FROM THE GROUP CONSISTING OF STYRENE, AMETHYLSTYRENE, A-CHLOROSTYRENE, AND DIMETHYLSTYRENE, AND THE VINYL CYANIDE COMPOUND BEING SELECTED FROM THE GROUP CONSISTING OF ACRYLONITRILE AND METHACRYLONITRILE, WHICH COMPRISES SUBJECTING THESE MATERIALS TO SOLUTION POLYMERIZATION IN THE PRESENCE OF A RADICAL CATALYST AT A TEMPERATURE OF 50* TO 120*C FOR 5 TO 25 HOURS IN A MIXED SOLVENT COMPRISING 5 TO 95% BY WEIGHT OF AN ALIPHATIC HYDROCARBON SOLVENT CAPABLE OF DISSOLVING THE ETHYLENE-PROPYLENE RUBBER AND 95 TO 5% BY WEIGHT OF A POLAR SOLVENT CAPABLE OF DISSOLVING A POLY-(AROMATIC VINYL COMPOUND) IN THE CASE OF THE BINARY GRAFT-COPOLYMER OR OF DISSOLVING A COPOLYMER OF THE AROMATIC VINYL COMPOUND AND THE VINYL CYANIDE COMPOUND IN THE CASE OF THE TERNARY GRAFTCOPOLYMER, THE AIPHATIC HYDROCARBON SOLVENT BEING SELECTED FROM THE GROUP CONSISTING OF PARAFFINS AND CYCLOPARAFFINS HAVING 5 TO 10 CARBON ATOMS, CYCLOPENTANES HAVING SUBSTITUENT ALKYL GROUPS OF 1 TO 4 CARBON ATOMS, AND CYCLOHEXANES HAVING SUBSTITUENT ALKYL GROUPS OF 1 TO 4 CARBON ATOMS, AND THE POLAR SOLVENT BEING SELECTED FROM THE GROUP CONSISTING OF KETONES, ESTERS, ETHER, CHLORINE-SUBSTITUTED ALIPHATIC HYDROCARBONS, NITROGEN-CONTAINING HYDROCARBONS, AND SULFURCONTAINING HYDROCARBONS.
Claim 3
Dependent Claim 59 words
A process according to claim 1, wherein the polar solvent is at least one member selected from the group consisting of acetone, methyl ethyl ketone, methyl n-propyl ketone, diethyl ketone, 2-hexanone, 3-hexanone, acetophenone, propiophenone, methyl formate, ethyl formate, methyl acetate, ethyl acetate, n-propyl acetate, n-butyl acetate, n-amyl acetate, methyl propionate, methyl n-butyrate, tetrahydrofuran, dioxane, dichloroethane, chloroform, pyridine, aniline, acetonitrile,
Claim 4
Dependent Claim 50 words
A process according to claim 1, wherein the proportion of the polar solvent in the mixed solvent is 0 to 20 % by weight at the beginning of polymerization, the proportion being increased during the progress of polymerization by addition of fresh polar solvent, and reaches 30 to 80 %
Claim 5
Dependent Claim 20 words
A process according to claim 1, wherein a blend of the ethylene-propylene rubber with one or two of polybutadidne, polyisoprene
Claim 6
Dependent Claim 24 words
A process according to claim 4, wherein the blend containing the ethylene-propylene rubber in a proportion of 50 to 100 % by weight is
Claim 7
Dependent Claim 12 words
A process according to claim 1, wherein the aromatic vinyl compound is
Claim 8
Dependent Claim 30 words
A process according to claim 1, wherein the ratio of the aromatic vinyl compound to the vinyl cyanide compound is from 2 : 1 to 5 : 1 by weight.
Claim 9
Dependent Claim 12 words
A process according to claim 1, wherein the aromatic vinyl compound is
Claim 10
Dependent Claim 12 words
A process according to claim 8, wherein the ratio of styrene to
Claim 11
Dependent Claim 37 words
A process according to claim 1, wherein the radical catalyst is at least one member selected from the group consisting of benzoyl peroxide, lauroyl peroxide, di-tert-butyl peroxide, acetyl peroxide, tert-butyl peroxybenzoate, dicumyl peroxide, peroxybenzoic acid, peroxyacetic acid,
Claim 12
Dependent Claim 27 words
A process according to claim 1, wherein the polymerization is conducted in the presence of 0.1 to 10 % by weight of a catalyst on the vinyl
Claim 13
Dependent Claim 26 words
The process of claim 1 wherein said aliphatic hydrocabon solvent is at least one member selected from the group consisting of pentane, n-hexane, 2-methylpentane, 3-methylpentane, 2,2-dimethylpentane,
Claim 14
Dependent Claim 27 words
The process of claim 1 wherein 5 to 20% by weight of said ethylene-propylene rubber is used with 95 to 80% by weight of said vinyl compound.

References Cited (Backward Citations)

US3538191A Cited
US3538190A Cited
US3538193A Cited
US3538192A Cited
US3642950A Cited
US3683050A Cited
US3671608A Cited
US3657395A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-04-07 1978-10-07 1979-04-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-04-07 1982-10-07 1983-04-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-04-07 1986-10-07 1987-04-08 $7700.00 Window Closed / Lapsed

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