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US3876532A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for reducing the total acid number of a middle distillate oil

Assignee: Gulf Research and Development Co
•
Filing: 1973-02-27
•
Granted: 1975-04-08
•
Expires: 1993-02-27
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Abstract

Abstract Middle distillate virgin oils, such as straight run furnace oil, jet fuel or kerosene are required to meet many commercial specifications, among which are maximum allowable total sulfur content, maximum allowable mercaptan sulfur content and maximum allowable total acid number. Middle distillates which do not meet commercial specifications in regard to total sulfur content can be hydrodesulfurized for the removal of the portion of the total sulfur required for meeting the commercial requirement. Such hydrodesulfurization requires more severe conditions than do processes for reduction of total acid number or for reduction of mercaptan sulfur content so that under the severe conditions required for hydrodesulfurization, excessive total acid number and excessive mercaptan content are automatically concomitantly reduced to commerically acceptable levels. The present invention relates to the hydrotreatment of virgin middle distillates which meet commercial specifications in regard to total sulfur content in the absence of prior hydrotreating or any other treatment, but do not meet commercial specifications in regard to total acid number or in regard to mercaptan sulfur content. According to the present invention, the latter middle distillates are not blended with high total sulfur feeds flowing to hydrodesulfurization processes requiring severe conditions to accomplish reduction in total sulfur content, but are hydrotreated separately under relatively more mild catalytic hydrotreating conditions to reduce mercaptan sulfur content or total acid number at hydrotreating severities which are so mild that there is an extremely limited consumption of hydrogen and a very limited removal of total sulfur. The catalyst employed in the mild hydrotreating processes of this invention is a deactivated hydrotreating catalyst from a more severe hydrodesulfurization or other hydrotreating operation which is no longer of viable use in the more severe operation due to numerous cycles of use and regeneration, due to excessive metals deposit thereon, or any other reason.

Inventors

  • 👤 Robert A Plundo
  • 👤 Thomas C Readal
  • 👤 James R Strom

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 11:06
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/02; C10G2400/00; C10G2400/06

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 118 words
A RELATIVELY LOW PRESSURE PROCESS FOR HYDROTREATING A STRAIGHT RUN NO. 2 HOME HEATING FUEL OIL FEED HAVING A TOTAL SULFUR CONTENT OF LESS THAN 0.2 WEIGHT PERCENT. COMPRISING PASSING SAID OIL OVER A HYDROTREATING CATALYST, SAID STRAIGHT RUN FEED OIL HAVING A TOTAL ACID NUMBER GREATER THAN 0.1 AS DETERMINED BY ASTM TEST D664 OR D974, THE PRESSURE IN SAID PROCESS BEING NO GREATER THAN ABOUT 150 PSI, THE TEMPERATURE IN SAID PROCESS BEING FROM 400* TO BELOW 500*F., HYDROGEN CONSUMPTION INCLUDING SOLUTION LOSSES IN SAID PROCESS BEING NO GREATER THAN ABOUT 25 STANDARD CUBIC FEET OF HYDROGEN PER BARREL OF FEED OIL, AND RECOVERING AN EFFLUENT OIL HAVING A TOTAL ACID NUMBER NO GREATER THAN 0.1.
Claim 2
Dependent Claim 118 words
A RELATIVELY LOW PRESSURE PROCESS FOR HYDROTREATING A STRAIGHT RUN NO. 2 HOME HEATING FUEL OIL FEED HAVING A TOTAL SULFUR CONTENT OF LESS THAN 0.2 WEIGHT PERCENT. COMPRISING PASSING SAID OIL OVER A HYDROTREATING CATALYST, SAID STRAIGHT RUN FEED OIL HAVING A TOTAL ACID NUMBER GREATER THAN 0.1 AS DETERMINED BY ASTM TEST D664 OR D974, THE PRESSURE IN SAID PROCESS BEING NO GREATER THAN ABOUT 150 PSI, THE TEMPERATURE IN SAID PROCESS BEING FROM 400* TO BELOW 500*F., HYDROGEN CONSUMPTION INCLUDING SOLUTION LOSSES IN SAID PROCESS BEING NO GREATER THAN ABOUT 25 STANDARD CUBIC FEET OF HYDROGEN PER BARREL OF FEED OIL, AND RECOVERING AN EFFLUENT OIL HAVING A TOTAL ACID NUMBER NO GREATER THAN 0.1.
Claim 3
Dependent Claim 20 words
The process of claim 1 wherein said hydrotreating catalyst previously has been used in a relatively high pressure hydrotreating process.
Claim 4
Dependent Claim 34 words
The process of claim 1 wherein said hydrotreating catalyst previously has been used in a relatively high pressure hydrotreating process until it has been substantially permanently deactivated for purposes of said high pressure process.
Claim 5
Dependent Claim 38 words
The process of claim 1 wherein the total acid number of the feed oil is reduced at least about 80 percent while the total sulfur content of the feed oil is reduced not more than 40 weight percent.
Claim 6
Dependent Claim 25 words
The process of claim 1 wherein the catalyst comprises supported Group VI and Group VIII metals and the pressure is no greater than 100 psi.
Claim 7
Dependent Claim 11 words
The process of claim 1 wherein the temperature is below 450.degree.F.
Claim 8
Dependent Claim 13 words
The process of claim 1 wherein the LHSV is between 4 and 8.
Claim 9
Dependent Claim 40 words
The process of claim 1 wherein the total acid number of the feed oil is reduced at least about 80 percent while not more than about 20 weight percent of the total sulfur content of the feed oil is removed.
Claim 10
Dependent Claim 24 words
The process of claim 2 wherein the prior relatively high pressure hydrotreating process is a hydrodesulfurization process operated at a pressure above 600 psi.
Claim 11
Dependent Claim 24 words
The process of claim 1 wherein chemical hydrogen consumption excluding solution losses is less than 10 standard cubic feet per barrel of feed oil.
Claim 12
Dependent Claim 23 words
The process of claim 1 wherein hydrogen consumption including solution losses is less than 20 standard cubic feet per barrel of feed oil.
Claim 13
Dependent Claim 23 words
The process of claim 1 wherein the hydrogen circulation rate is between 200 and 1,200 standard cubic feet per barrel of feed oil.
Claim 14
Dependent Claim 19 words
The process of claim 1 wherein the total acid number of said feed oil is above 0.47 or more.
Claim 15
Dependent Claim 16 words
The process of claim 1 wherein there is substantially 100 percent yield of said feed oil.
Claim 16
Dependent Claim 145 words
A relatively low pressure process for hydrotreating a straight run No. 2 home heating fuel oil feed having a total sulfur content of less than 0.2 weight percent, comprising passing said oil over a hydrotreating catalyst which has been used in a prior relatively high pressure hydrotreating process until it has been substantially permanently deactivated for purposes of said high pressure process, said straight run feed oil having a total acid number greater than 0.2 as determined by ASTM test D664 or D974, the pressure in said process being no greater than about 150 psi, the temperature in said process being from 400.degree. to below 500.degree.F., unit hydrogen consumption including solution losses in said process being no greater than about 30 standard cubic feet of hydrogen per barrel of feed oil, and recovering an effluent oil having a total acid number no greater than 0.2.
Claim 17
Dependent Claim 145 words
A relatively low pressure process for hydrotreating a straight run No. 2 home heating fuel oil feed having a total sulfur content of less than 0.2 weight percent, comprising passing said oil over a hydrotreating catalyst which has been used in a prior relatively high pressure hydrotreating process until it has been substantially permanently deactivated for purposes of said high pressure process, said straight run feed oil having a total acid number greater than 0.2 as determined by ASTM test D664 or D974, the pressure in said process being no greater than about 150 psi, the temperature in said process being from 400.degree. to below 500.degree.F., unit hydrogen consumption including solution losses in said process being no greater than about 30 standard cubic feet of hydrogen per barrel of feed oil, and recovering an effluent oil having a total acid number no greater than 0.2.

References Cited (Backward Citations)

US2717857A Cited
US2793986A Cited
US2921023A Cited
US2963425A Cited
US2998381A Cited
US3483119A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-04-07 1978-10-07 1979-04-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-04-07 1982-10-07 1983-04-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-04-07 1986-10-07 1987-04-08 $7700.00 Window Closed / Lapsed

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