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US3876481A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass compositions, fibers and methods of making same

Assignee: Owens Corning
•
Filing: 1973-03-19
•
Granted: 1975-04-08
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Expires: 1993-03-19
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Abstract

Abstract Glass compositions are disclosed which are fiberizable and are free of boron and fluorine. The compositions have the following range of proportions (by weight): SiO.sub.2, 55 to 63%; Al.sub.2 O.sub.3, 11 to 18%; CaO, 9 to 25%; Li.sub.2 O, 0.3 to 2.5%; TiO.sub.2, 2 to 5%; MgO, 0 to 10%; MnO, 0 to 1.5%; Na.sub.2 O, K.sub.2 O, 0 to 2.5%; BaO, 0 to 2.5%; SrO, 0 to 1.5%; ZnO, 0 to 4%; ZrO.sub.2, 0 to 2%; and Fe.sub.2 O.sub.3, 0 to 1%, wherein the total weight percent of Li.sub.2 O and TiO.sub.2 is 3.5 to 6.5%. The preferred glass composition has a liquidus temperature of 2200.degree.F., or less, and a viscosity of log 2.5 poises at 2450.degree.F., or less.

Inventors

  • 👤 Thomas D Erickson
  • 👤 Warren W Wolf

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 07:58
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/04; C03C3/076; C03C3/083; C03C3/085; C03C3/087; C03C13/00

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 103 words
FIBERIZABLE, BORON AND FLUORINE FREE GLASS COMPOSITIONS CONSISTING ESSENTIALLY BY WEIGHT OF: PERCENT SIO2 55 TO 63 AI2O3 11 TO 18 CAO 9 TO 25 LI2O 0.3 TO 2.5 TIO2 2 TO 5 MGO 0 TO 10 MNO 0 TO 1.5 NA2O, K2O 0 TO 2.5 BAO 0 TO 2.5 SRO 0 TO 1.5 ZNO 0 TO 4 ZRO 0 TO 2 FE2O3 0 TO 1 WHEREIN THE TOTAL WEIGHT PERCENT OF LI2O AND TIO2 IS 3.5 TO 6.5% AND WHEREIN THE GLASS COMPOSITION HAS A LIQUIDUS TEMPERATURE OF 2200*F, OR LESS, AND A VISCOSITY OF LOG 2.5 POISES AT 2450*F., OR LESS.
Claim 2
Dependent Claim 103 words
FIBERIZABLE, BORON AND FLUORINE FREE GLASS COMPOSITIONS CONSISTING ESSENTIALLY BY WEIGHT OF: PERCENT SIO2 55 TO 63 AI2O3 11 TO 18 CAO 9 TO 25 LI2O 0.3 TO 2.5 TIO2 2 TO 5 MGO 0 TO 10 MNO 0 TO 1.5 NA2O, K2O 0 TO 2.5 BAO 0 TO 2.5 SRO 0 TO 1.5 ZNO 0 TO 4 ZRO 0 TO 2 FE2O3 0 TO 1 WHEREIN THE TOTAL WEIGHT PERCENT OF LI2O AND TIO2 IS 3.5 TO 6.5% AND WHEREIN THE GLASS COMPOSITION HAS A LIQUIDUS TEMPERATURE OF 2200*F, OR LESS, AND A VISCOSITY OF LOG 2.5 POISES AT 2450*F., OR LESS.
Claim 3
Dependent Claim 38 words
The glass composition defined in claim 1, wherein the total weight percent of Na.sub.2 O, K.sub.2 O and Li.sub.2 O is greater than one percent and the total weight percent of Na.sub.2 O and K.sub.2 O is less
Claim 4
Dependent Claim 12 words
The glass composition defined in claim 1, having a concentration of MgO
Claim 5
Dependent Claim 12 words
Fiberizable, boron and fluorine free glass compositions, consisting essentially by weight of:
Claim 6
Dependent Claim 12 words
Fiberizable, boron and fluorine free glass compositions, consisting essentially by weight of:
Claim 7
Dependent Claim 12 words
Boron and fluorine free textile glass fibers, consisting essentially by weight of:
Claim 8
Dependent Claim 12 words
Boron and fluorine free textile glass fibers, consisting essentially by weight of:
Claim 9
Dependent Claim 8 words
Textile glass fibers consisting essentially by weight of:
Claim 10
Dependent Claim 8 words
Textile glass fibers consisting essentially by weight of:
Claim 11
Independent Claim 38 words
The method of making a fiberizable glass composition, by adding 0.3 to 2.5% by weight Li.sub.2 O and 2 to 5% by weight TiO.sub.2 to the following boron and fluorine free glass composition, consisting essentially of, by weight:
Claim 12
Independent Claim 38 words
The method of making a fiberizable glass composition, by adding 0.3 to 2.5% by weight Li.sub.2 O and 2 to 5% by weight TiO.sub.2 to the following boron and fluorine free glass composition, consisting essentially of, by weight:

References Cited (Backward Citations)

US2394493A Cited
US2920971A Cited
US3095311A Cited
US3540893A Cited
US3673049A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-04-07 1978-10-07 1979-04-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-04-07 1982-10-07 1983-04-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-04-07 1986-10-07 1987-04-08 $7700.00 Window Closed / Lapsed

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