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US3876368A Expired / Lapsed US ⏱️ 0.0 years remaining

Indamines for dyeing keratinic fibers

Assignee: L'Oréal SA
•
Filing: 1973-08-13
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Granted: 1975-04-08
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Expires: 1993-08-13
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Abstract

Abstract Imdamine having the formula Wherein R and R'' each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms, lower alkoxy having 1-4 carbon atoms, amino, acylamino wherein the acyl moiety has 1 to 4 carbon atoms and hydroxy, with the proviso that one, but not both of R and R'' is said amino, acylamino or hydroxy; R.sub.1 and R.sub.2 each independently represent a member selected from the group consisting of lower alkyl having 1-4 carbon atoms and lower alkyl having 1-4 carbon atoms and substituted with a member selected from the group consisting of hydroxy, acylamino wherein the acyl moiety has 1 to 4 carbon atoms, carbamyl, piperidino, benzoylamino and alkylsulfonamido wherein the alkyl moiety has 1 to 4 carbon atoms; R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 each independently represent a member selected from the group consisting of hydrogen, lower alkyl having 1-4 carbon atoms and lower alkoxy having 1-4 carbon atoms, and the salts formed by these indamines with organic or inorganic acids, in particular, their acetates, hydrochlorides, hydrobromides, persulfates, perchlorates and the double zinc salts of these compounds, which can, of course, be in a tautomeric form of that represented by formula (I), are usefully employed for dyeing keratinous fibers, and, in particular, human hair.

Inventors

  • 👤 Gregoire Kalopissis
  • 👤 Andree Bugaut
  • 👤 Francoise Estradier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 23:41
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/41; A61K8/413; A61Q; A61Q5/00; A61Q5/10; Y; Y10; Y10S; Y10S424/00; Y10S424/01; Y10S424/02

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 32 words
A COMPOSITION FOR DYEING HUMAN HAIR COMPRISING AN AQUEOUS SOLUTION OF AT LEAST ONE COMPOUND SELECTED FROM THE GROUP CONSISTING OF (A) AN INDAMINE, INCLUDING THE TAUTOMERIC FORMS THEREOF, HAVING THE FORMULA
Claim 2
Dependent Claim 32 words
A COMPOSITION FOR DYEING HUMAN HAIR COMPRISING AN AQUEOUS SOLUTION OF AT LEAST ONE COMPOUND SELECTED FROM THE GROUP CONSISTING OF (A) AN INDAMINE, INCLUDING THE TAUTOMERIC FORMS THEREOF, HAVING THE FORMULA
Claim 3
Dependent Claim 133 words
The composition of claim 1 wherein said compound is selected from the group consisting of the hydrochloride of N- (4''-dimethylamino)phenyl! 3-amino 6-methoxy benzoquinonediimine, N- (4''-dimethylamino)phenyl! 3-amino 6-methoxy benzoquinonediimine, the double chloride of zinc and N- (4''- ethyl, acetylaminoethyl!amino)phenyl! 3-amino 6-methoxy benzoquinonediimine, the double chloride of zinc and N- (4''- ethyl, .beta.-piperidinoethyl!amino)phenyl! 3amino 6-methoxy benzoquinonediimine, the persulfate of N- (4''-dimethylamino) phenyl! 3-acetylamino 6-methyl benzoquinonediimine, N- (4''-dimethylamino)phenyl! 3-acetylamino 6-methyl benzoquinonediimine, the perchlorate of N- (2''-amino 4''-dimethylamino) phenyl! benzoquinonediimine, the acetate of N- (2''-acetylamino 4''-dimethylamino) phenyl! 3-methoxy 6-methyl benzoquinonediimine, the double chloride of zinc and N- (4''-diethylamino 2''-hydroxy) phenyl! 3-methoxy 6-methyl benzoquinonediimine, the double chloride of zinc and N- 4''-diethylamino 2''-hydroxy)phenyl! 2,6-dimethyl 3-methoxy benzoquinonediimine, the perchlorate of N- (4''-diethylamino 2''-amino) phenyl! 2,6-dimethyl 3-methoxy benzoquinonediimine, the persulfate of N,N- (4''- ethyl, .beta.-mesylaminoethyl! amino 2''-methyl)phenyl! 3-acetylamino 6-methyl benzoquinonediimine.
Claim 4
Dependent Claim 11 words
The composition of claim 1 having a pH between 3- 10.
Claim 5
Dependent Claim 11 words
The composition of claim 1 having a pH between 6- 9.
Claim 6
Dependent Claim 34 words
The composition of claim 1 wherein the aqueous solution further contains a lower alkanol and a film forming resin in amounts of about 1 to 3 percent based on the weight of said composition.
Claim 7
Dependent Claim 19 words
The composition of claim 5 wherein said lower alkanol is selected from the group consisting of ethanol and isopropanol.
Claim 8
Dependent Claim 24 words
The composition of claim 5 wherein said lower alkanol is present in amounts ranging from about 20- 50 percent by weight of said composition.
Claim 9
Dependent Claim 23 words
The composition of claim 5 wherein said compound is present in amounts of about 0.002 to 0.5 percent by weight of said composition.
Claim 10
Dependent Claim 43 words
The composition of claim 5 wherein said film forming resin is selected from the group consisting of polyvinylpyrrolidone, a copolymer of crotonic acid and vinyl acetate, a copolymer of vinylpyrrolidone and vinyl acetate and a copolymer of maleic anhydride and butyl vinyl ether.
Claim 11
Dependent Claim 50 words
A process for dyeing human hair which comprises applying to said hair in an amount effective to dye the same an aqueous solution containing 0.002 to 1 percent by weight of a compound selected from the group consisting of a. an indamine, including the tautomeric forms thereof, having the formula
Claim 12
Dependent Claim 50 words
A process for dyeing human hair which comprises applying to said hair in an amount effective to dye the same an aqueous solution containing 0.002 to 1 percent by weight of a compound selected from the group consisting of a. an indamine, including the tautomeric forms thereof, having the formula
Claim 13
Dependent Claim 19 words
The composition of claim 1 wherein said compound is the persulfate of N,N- (4''- ethyl, .beta.-mesylaminoethyl! amino 2''-methyl)phenyl!-3-acetylamino-6-methyl benzoquinonediimine.

References Cited (Backward Citations)

US1102028A Cited
US3210252A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-04-07 1978-10-07 1979-04-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-04-07 1982-10-07 1983-04-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-04-07 1986-10-07 1987-04-08 $7700.00 Window Closed / Lapsed

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