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US3875302A Expired / Lapsed US ⏱️ 0.0 years remaining

Gelled vinyl alcohol polymers and articles therefrom

Assignee: Kuraray Co Ltd
•
Filing: 1973-08-07
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Granted: 1975-04-01
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Expires: 1993-08-07
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Abstract

Abstract A process is provided for preparing gelled vinyl alcohol polymers comprising freezing an aqueous solution of a vinyl alcohol polymer below about -5*C., and thereafter melting the frozen solution. Articles such as artificial bait prepared from said gelled vinyl alcohol polymers are also provided.

Inventors

  • 👤 Taisei Inoue

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 03:56
CPC Classifications
C; C05; C05G; C05G5/00; C05G5/40; A; A01; A01C; A01C21/00; A01K; A01K97/00; A01K97/04; A01K97/045; B; B01; B01J; B01J13/00; B01J13/0052; B01J13/0065; B01J2/00; B01J2/02; B01J2/06; B01J2/08; C08; C08K; C08K5/00; C08K5/0008; C08L; C08L29/00; C08L29/02; C08L29/04

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 129 words
A GELLED POLYVINYL ALCOHOL POLYMER HAVING A DEGREE OF POLYMERIZATION OF BETWEEN ABOUT 500 AND 2000 AND CONTAINING A FISH ATTRACTANT, SAID GELLED POLYVINYL ALCOHOL POLYMER HAVING A RATIO OF WATER CONTENT TO SOLIDS CONTENT SIMILAR TO RAW FISH BAIT AND A FLEXIBLE AND SOFTNESS SIMILAR TO RAW FISH BAIT AND EXHIBITING RETARDED LEACHING OF SAID FISH ATTRACTANT, SAID GELLED POLYVINYL ALCOHOL POLYMER PREPARED BY A PROCESS COMPRISING ADMIXING SAID FISH ATTRACTANT WITH AN AQUEOUS SOLUTION CONSISTING ESSENTIALLY OF WATER AND FROM ABOUT 5 TO ABOUT 40 WT % OF A VINYL ALCOHOL POLYMER FREEZING SAID ADMIXTURE AT A TEMPERATURE BELOW ABOUT -5*C FOR A PERIOD OF FROM ABOUT 10 TO ABOUT 50 HOURS, AND MELTING THE RESULTING FROZEN SOLUTION TO OBTAIN SAID FISH ATTRACTANT-CONTAINING GELLED POLYVINYL ALCOHOL POLYMER.
Claim 2
Dependent Claim 129 words
A GELLED POLYVINYL ALCOHOL POLYMER HAVING A DEGREE OF POLYMERIZATION OF BETWEEN ABOUT 500 AND 2000 AND CONTAINING A FISH ATTRACTANT, SAID GELLED POLYVINYL ALCOHOL POLYMER HAVING A RATIO OF WATER CONTENT TO SOLIDS CONTENT SIMILAR TO RAW FISH BAIT AND A FLEXIBLE AND SOFTNESS SIMILAR TO RAW FISH BAIT AND EXHIBITING RETARDED LEACHING OF SAID FISH ATTRACTANT, SAID GELLED POLYVINYL ALCOHOL POLYMER PREPARED BY A PROCESS COMPRISING ADMIXING SAID FISH ATTRACTANT WITH AN AQUEOUS SOLUTION CONSISTING ESSENTIALLY OF WATER AND FROM ABOUT 5 TO ABOUT 40 WT % OF A VINYL ALCOHOL POLYMER FREEZING SAID ADMIXTURE AT A TEMPERATURE BELOW ABOUT -5*C FOR A PERIOD OF FROM ABOUT 10 TO ABOUT 50 HOURS, AND MELTING THE RESULTING FROZEN SOLUTION TO OBTAIN SAID FISH ATTRACTANT-CONTAINING GELLED POLYVINYL ALCOHOL POLYMER.
Claim 3
Dependent Claim 22 words
A gelled polyvinyl alcohol polymer as defined in claim 1 wherein the aqueous solution is frozen at a temperature below about -15*C.
Claim 4
Dependent Claim 24 words
A gelled polyvinyl alcohol polymer as defined in claim 2 wherein the aqueous solution is frozen at a temperature of from -15*C. to -50*C.
Claim 5
Dependent Claim 27 words
A gelled polyvinyl alcohol polymer as defined in claim 1 wherein, after the frozen solution is melted, it is at least once again frozen and then melted.
Claim 6
Dependent Claim 124 words
The gelled polyvinyl alcohol polymer of claim 1 wherein globules of said polymer are formed by a process comprising intermittently adding an admixture of fish attractant and an aqueous solution consisting essentially of water and from about 5 to 40 wt.% of a vinyl alcohol polymer to a liquid non-solvent for the vinyl alcohol polymer which is substantially incompatible with water, said liquid non-solvent exhibiting a specific gravity which is equal to or less than that of the aqueous solution of the vinyl alcohol polymer, whereby the aqueous solution of vinyl alcohol polymer assumes a globular form, freezing the admixture in said liquid non-solvent at a temperature below about -5*C., and melting the resultant frozen mixture to obtain globules of gelled vinyl alcohol polymer.
Claim 7
Dependent Claim 23 words
A gelled polyvinyl alcohol polymer as defined in claim 1 which additionally contains a colorant, said colorant being admixed with the aqueous solution.
Claim 8
Dependent Claim 27 words
A gelled polyvinyl alcohol polymer as defined in claim 1 which additionally contains reinforcing fibers or fabric, said fibers or fabric being admixed with the aqueous solution.
Claim 9
Dependent Claim 99 words
A process of manufacturing a hydrophilic fishing bait having a ratio of water content to solid content similar to raw bait and a flexibility and softness similar to raw bait, and a retarded leaching characteristic, comprising the steps of forming an aqueous mixture of from about 5 to 40 wt.% of a polyvinyl alcohol having a degree of polymerization between about 500 and 2000 and a fish attractant, freezing said mixture at a temperature below about -5*C. for a period of from about 10 to about 50 hours, and melting the frozen mixture to obtain said hydrophilic fishing bait.
Claim 10
Dependent Claim 99 words
A process of manufacturing a hydrophilic fishing bait having a ratio of water content to solid content similar to raw bait and a flexibility and softness similar to raw bait, and a retarded leaching characteristic, comprising the steps of forming an aqueous mixture of from about 5 to 40 wt.% of a polyvinyl alcohol having a degree of polymerization between about 500 and 2000 and a fish attractant, freezing said mixture at a temperature below about -5*C. for a period of from about 10 to about 50 hours, and melting the frozen mixture to obtain said hydrophilic fishing bait.

References Cited (Backward Citations)

US2815329A Cited
US2979778A Cited
US3421899A Cited
US3579895A Cited
US3664963A Cited
US3627693A Cited
US3684519A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-03-31 1978-09-30 1979-04-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-03-31 1982-09-30 1983-04-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-03-31 1986-09-30 1987-04-01 $7700.00 Window Closed / Lapsed

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