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US3873390A Expired / Lapsed US ⏱️ 0.0 years remaining

Phosphorescent, fluorescent and reflective coated sheets or films and compositions and method for making the same

Assignee: Individual
•
Filing: 1972-09-27
•
Granted: 1975-03-25
•
Expires: 1992-09-27
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Abstract

Abstract Phosphorescent and fluorescent coated sheets and films and coating compositions and methods for making the same in which the coating compositions include a solid phase embodying a phosphorescent pigment and/or fluorescent pigment phase and a socalled hot melt coating or vehicle for the pigment. The coating compositions are applied to a carrier or base sheet by a continuous coating operation, at an elevated temperature, following which the coating composition is transferred from the carrier or base sheet to a polyester or like film, or to a paper sheet or woven fabric, on which it is carried to complete the phosphorescent and/or fluorescent coated film. The phosphorescent products are useful as label stock, highway warning signs and road stripes, identification tapes, which glow at night, on tags, games, clock faces, instrument dial faces and for other purposes and the fluorescent products are useful in the graphic art fields and elsewhere. The continuous coating operation is much more rapid than prior art processes and avoids the use of highly volatile solvents employed in that process and the industrial pollution and other hazards thereto, as well as the extended drying time of the solvents which is required in the use of such prior art methods. Finely divided light-reflective particles, such for example, as glass beads, aluminum foil chips, metal powders and colored plastic resinous particles may also be incorporated in the new coated sheets or films by application to the hot melt coating while the latter is in a soft condition to enable the finely divided reflective particles to adhere thereto.

Inventors

  • 👤 Richard K Cornell
  • 👤 Gerald J Deddo
  • 👤 Henry L Gianatasio

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 02:07
CPC Classifications
B; B05; B05D; B05D7/00; B05D7/02; B05D7/04; B05D1/00; B05D1/28; B05D1/286; B05D5/00; B05D5/06; B05D5/061; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T156/00; Y10T156/10; Y10T156/1089; Y10T156/1092; Y10T156/1093; Y10T156/1095; Y10T428/00; Y10T428/25; Y10T428/256

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 48 words
THE METHOD OF MAKING A FLEXIBLE COATED FILM OR SHEET WHICH COMPRISES THE STEPS OF: A. FORMING A PIGMENT ADHESIVE COATING COMPOSITION BY INTIMATELY MIXING A FINELY DIVIDED PIGMENT PHASE SELECTED FROM THE GROUP CONSISTING OF PHOSPHORESCENT AND FLUORESCENT PIGMENTS, AND MIXTURES THEREOF, AND AN ADHESIVE VEHICLE PHASE;
Claim 2
Independent Claim 48 words
THE METHOD OF MAKING A FLEXIBLE COATED FILM OR SHEET WHICH COMPRISES THE STEPS OF: A. FORMING A PIGMENT ADHESIVE COATING COMPOSITION BY INTIMATELY MIXING A FINELY DIVIDED PIGMENT PHASE SELECTED FROM THE GROUP CONSISTING OF PHOSPHORESCENT AND FLUORESCENT PIGMENTS, AND MIXTURES THEREOF, AND AN ADHESIVE VEHICLE PHASE;
Claim 3
Dependent Claim 128 words
THE SAID ADHESIVE VEHILCE PHASE OF THE SAID COATING COMPOSITION HAVING MELTING POINT OF NOT SUBSTANTIALLY HIGHER THAN 405*F AND NOT SUBSTANTIALLY LOWER THAN 295*F AND HAVING A VISCOSITY WITHIN THE AFORESAID TEMPERATURE RANGE OF BETWEEN 217 AND 1,100 CPS; B. APPLYING THE AFORESAID PIGMENT ADHESIVE COATING COMPOSITION WITHIN THE AFORESAID TEMPERATURE AND VISCOSITY RANGES TO A FLEXIBLE FILM BASE OR CARRIER SHEET; C. TRANSFERRING THE AFORESAID PIGMENT ADHESIVE COATING COMPOSITION WHILE IT IS IN A MOLTEN STATE, FROM THE SAID FLEXIBLE FILM BASE OR CARRIER SHEET TO A FLEXIBLE SUPPORTING FILM OR SHEET TO COMPLETE THE SAID FLEXIBLE COATED FILM OR SHEET; AND THEN (D) COOLING THE FLEXIBLE SUPPORTING FILM OR SHEET WITH THE SAID PIGMENT ADHESIVE COATING THEREON IN ORDER TO SOLIDIFY SAID PIGMENT ADHESIVE COATING.
Claim 4
Dependent Claim 128 words
THE SAID ADHESIVE VEHILCE PHASE OF THE SAID COATING COMPOSITION HAVING MELTING POINT OF NOT SUBSTANTIALLY HIGHER THAN 405*F AND NOT SUBSTANTIALLY LOWER THAN 295*F AND HAVING A VISCOSITY WITHIN THE AFORESAID TEMPERATURE RANGE OF BETWEEN 217 AND 1,100 CPS; B. APPLYING THE AFORESAID PIGMENT ADHESIVE COATING COMPOSITION WITHIN THE AFORESAID TEMPERATURE AND VISCOSITY RANGES TO A FLEXIBLE FILM BASE OR CARRIER SHEET; C. TRANSFERRING THE AFORESAID PIGMENT ADHESIVE COATING COMPOSITION WHILE IT IS IN A MOLTEN STATE, FROM THE SAID FLEXIBLE FILM BASE OR CARRIER SHEET TO A FLEXIBLE SUPPORTING FILM OR SHEET TO COMPLETE THE SAID FLEXIBLE COATED FILM OR SHEET; AND THEN (D) COOLING THE FLEXIBLE SUPPORTING FILM OR SHEET WITH THE SAID PIGMENT ADHESIVE COATING THEREON IN ORDER TO SOLIDIFY SAID PIGMENT ADHESIVE COATING.
Claim 5
Dependent Claim 78 words
The method defined in claim 1 in which a. the said flexible film base or carrier sheet and the said flexible supporting film or sheet are laminated to laminate the said flexible film base or carrier sheet and the said flexible supporting film or sheet together and thus transfer the said pigment adhesive coating white it is in a matter state from the said flexible film base or carrier sheet to the said flexible supporting film or sheet.
Claim 6
Dependent Claim 22 words
then effecting delamination of the pigment adhesive coated flexible supporting film or sheet from the said flexible film base or carrier sheet.
Claim 7
Dependent Claim 22 words
then effecting delamination of the pigment adhesive coated flexible supporting film or sheet from the said flexible film base or carrier sheet.
Claim 8
Dependent Claim 29 words
The method defined in claim 2 which comprises passing the said flexible film base or carrier sheet over a coating roll while applying the said pigment adhesive coating thereto.
Claim 9
Dependent Claim 52 words
The method defined in claim 3 in which (a) the said flexible supporting film or sheet with the said pigment adhesive coating thereon is cooled in order to solidify said pigment adhesive coating, and then said flexible supporting film or sheet is delaminated from the said flexible film base or caRrier sheet.
Claim 10
Dependent Claim 32 words
The method defined in claim 4 in which a. the delamination of the said coated flexible supporting film or sheet from the said flexible film base or carrier sheet is effected by
Claim 11
Independent Claim 126 words
The method of making a flexible coated film or sheet which comprises the steps of: a. forming a pigment adhesive coating composition by intimately mixing a finely divided pigment phase in the form of a phosphorescent pigment selected from the group consisting of calcium sulfide and strontium sulfide and fluorescent pigment selected from the group consisting of zinc sulfide and cadmium sulfide, and mixtures thereof, and silica gel as a dispersant, with an adhesive vehicle phase comprised of one or more materials selected from the group consiting of (1) a mixture of petroleum wax, microcrystalline wax and polyethylene polymer; (2) ethylene vinyl acetate copolymer; (3) polyethylene copolymer; (4) polypropylene; (5) a mixture of paraffin wax and polyethylene polymer; and (6) a copolymer of styrene and isobutylene;
Claim 12
Independent Claim 126 words
The method of making a flexible coated film or sheet which comprises the steps of: a. forming a pigment adhesive coating composition by intimately mixing a finely divided pigment phase in the form of a phosphorescent pigment selected from the group consisting of calcium sulfide and strontium sulfide and fluorescent pigment selected from the group consisting of zinc sulfide and cadmium sulfide, and mixtures thereof, and silica gel as a dispersant, with an adhesive vehicle phase comprised of one or more materials selected from the group consiting of (1) a mixture of petroleum wax, microcrystalline wax and polyethylene polymer; (2) ethylene vinyl acetate copolymer; (3) polyethylene copolymer; (4) polypropylene; (5) a mixture of paraffin wax and polyethylene polymer; and (6) a copolymer of styrene and isobutylene;
Claim 13
Dependent Claim 55 words
The method defined in claim 6 in which a. the said adhesive vehicle phase of the said coating composition is heated to a temperature of not substantially higher than 405*F nor substantially lower than 295*F to melt the said adhesive vehicle phase of the said coating composition before the said pigment phase is added thereto.
Claim 14
Dependent Claim 114 words
The method defined in claim 6 in which a. the said flexible coated supporting film or sheet is heated to soften and render tacky the outer surface of the said pigment adhesive coating thereon; and in which b. a finely divided light-reflective material selected from the group consisting of small glass beads, finely divided aluminum foil chips, finely divided metal powders and finely divided plastic resinous particles, is applied and adhered to and exposed on the heated and softened outer surface of the said flexible coated supporting film or sheet while it is in a tacky condition without completely embedding the said finely divided materials in the body of the said pigment adhesive coating.
Claim 15
Independent Claim 46 words
The method of making a flexible coated film which comprises the steps of: a. forming a pigment adhesive coating composition by intimately mixing a finely divided pigment phase selected from the group consisting of phosphorescent and fluorescent pigments, and mixtures thereof, and an adhesive vehicle phase;
Claim 16
Independent Claim 46 words
The method of making a flexible coated film which comprises the steps of: a. forming a pigment adhesive coating composition by intimately mixing a finely divided pigment phase selected from the group consisting of phosphorescent and fluorescent pigments, and mixtures thereof, and an adhesive vehicle phase;
Claim 17
Dependent Claim 89 words
The method defined in claim 9 in which a. the said flexible coated film or sheet is heated to soften and render tacky the outer surface of the said pigment adhesive coating thereon; and in which b. a finely divided light-reflective material is applied and adhered to and exposed on the heated and softened outer surface of the said flexible coated film or sheet while it is in a tacky condition without completely embedding the said finely divided light-reflective material in the body of the said pigment adhesive coating.
Claim 18
Independent Claim 125 words
The method of making a flexible coated film or sheet which comprises the steps of: a. forming a pigment adhesive coating composition by intimately mixing a finely divided pigment phase in the form of a phosphorescent pigment selected from the group consisting of calcium sulfide and strontium sulfide and fluorescent pigment selected from the group consisting of zinc sulfide and cadmium sulfide, and mixtures thereof, and silica gel as a dispersant, with an adhesive vehicle phase comprised of one or more materials selected from the group consisting of (1) a mixture of petroleum wax, microcrystalline wax and polyethylene polymer; (2) ethylene vinyl acetate copolymer; (3) polyethylene copolymer; (4) polypropylene; (5) a mixture of paraffin wax and polyethylene polymer; and (6a copolymer of styrene and isobutylene;
Claim 19
Independent Claim 125 words
The method of making a flexible coated film or sheet which comprises the steps of: a. forming a pigment adhesive coating composition by intimately mixing a finely divided pigment phase in the form of a phosphorescent pigment selected from the group consisting of calcium sulfide and strontium sulfide and fluorescent pigment selected from the group consisting of zinc sulfide and cadmium sulfide, and mixtures thereof, and silica gel as a dispersant, with an adhesive vehicle phase comprised of one or more materials selected from the group consisting of (1) a mixture of petroleum wax, microcrystalline wax and polyethylene polymer; (2) ethylene vinyl acetate copolymer; (3) polyethylene copolymer; (4) polypropylene; (5) a mixture of paraffin wax and polyethylene polymer; and (6a copolymer of styrene and isobutylene;
Claim 20
Dependent Claim 10 words
A product prepared according to the process of claim 1.
Claim 21
Dependent Claim 10 words
A product prepared according to the process of claim 2.
Claim 22
Dependent Claim 10 words
A product prepared according to the process of claim 5.
Claim 23
Dependent Claim 10 words
A product prepared according to the process of claim 6.
Claim 24
Dependent Claim 10 words
A product prepared according to the process of claim 7.
Claim 25
Dependent Claim 10 words
A product prepared according to the process of claim 8.
Claim 26
Dependent Claim 10 words
A product prepared according to the process of claim 10.
Claim 27
Dependent Claim 10 words
A product prepared according to the process of claim 11.

References Cited (Backward Citations)

US2292914A Cited
US2798821A Cited
US2799609A Cited
US2949382A Cited
US3115417A Cited
US3253148A Cited
US3518205A Cited
US3679234A Cited
US3788879A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-03-24 1978-09-23 1979-03-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-03-24 1982-09-23 1983-03-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-03-24 1986-09-23 1987-03-25 $7700.00 Window Closed / Lapsed

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