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US3873349A Expired / Lapsed US ⏱️ 0.0 years remaining

Process of treating surfaces of metals

Assignee: JFE Engineering Corp
•
Filing: 1972-03-13
•
Granted: 1975-03-25
•
Expires: 1992-03-13
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Abstract

Abstract Both higher corrosion resistance and paint adherence are given to film formed on the surfaces of metals by treating the surfaces with aqueous solution of one or more materials selected from the group consisting of water soluble vinyl monomer, water soluble high polymer and then irradiating ionizing radioactive rays on the nearly dried surface film. When a water soluble inorganic compound is mixed with the above mentioned aqueous solution, the film properties are greatly improved.

Inventors

  • 👤 Tadao Kimura
  • 👤 Atuhiko Murao
  • 👤 Toshigoro Kuwahara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 09:29
CPC Classifications
B; B05; B05D; B05D7/00; B05D7/14; B05D3/00; B05D3/06; B05D3/068; B05D7/142; B05D2401/00; B05D2401/20

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 87 words
A METHOD OF COATING METAL SUBSTRATED BY APPLYING A COMPOSITION COMPRISING AN AQUEOUS SOLYTION OF WATER SOLUBLE VINYL MONOMER AND AN INORGANIC IONIC MATERIAL TO SAID METAL SUBSSTRATES, SAID INORGAINC IONIC MATERIAL CONTAINING A CATION SELECTED FROM THE GROUP CONSISTING OF CA, NG, ZN, CR, AL, FE AND NI; OR AN ANION SELECTED FROM THE GROUP CONSISTING OF CHROMATE, BICHROMATE, PHOSPHATE, BORATE, NITRATE, SULFATE, TITANATE, PERMANGANATE, FLUSILICATE AND FLUOBORATE; OR MIXTURES THEREOF; DRYING COATED SUBSTRATES, AND IRRADIATING THE DRIED COMPOSITION ON THE METAL SUBSTRATES WITH IONIZING RADIATION.
Claim 2
Independent Claim 87 words
A METHOD OF COATING METAL SUBSTRATED BY APPLYING A COMPOSITION COMPRISING AN AQUEOUS SOLYTION OF WATER SOLUBLE VINYL MONOMER AND AN INORGANIC IONIC MATERIAL TO SAID METAL SUBSSTRATES, SAID INORGAINC IONIC MATERIAL CONTAINING A CATION SELECTED FROM THE GROUP CONSISTING OF CA, NG, ZN, CR, AL, FE AND NI; OR AN ANION SELECTED FROM THE GROUP CONSISTING OF CHROMATE, BICHROMATE, PHOSPHATE, BORATE, NITRATE, SULFATE, TITANATE, PERMANGANATE, FLUSILICATE AND FLUOBORATE; OR MIXTURES THEREOF; DRYING COATED SUBSTRATES, AND IRRADIATING THE DRIED COMPOSITION ON THE METAL SUBSTRATES WITH IONIZING RADIATION.
Claim 3
Dependent Claim 38 words
Process of claim 1, wherein said water soluble vinyl monomer is selected from the group consisting of unsaturated acid, metallic salt of said unsaturated acids having divalent atom, unsaturated acid amide, unsaturated acid nitrile, and vinyl ester phosphate.
Claim 4
Dependent Claim 52 words
Process of claim 2, wherein said unsaturate acid is maleic acid, crotonic acid, itaconic acid, acrylic acid or metacrylic acid; wherein said unsaturated acid amide is acrylic amide or methacrylic amide and said unsaturated acid nitrile is acrylonitrile; and wherein said vinyl ester phosphate is 2-acid phosphoxyethyl methacrylate or 3-chloro-2-acid phosphoxypropyl methacrylate.
Claim 5
Dependent Claim 23 words
Process of claim 1, wherein said ionizing radioactive rays includes proton, alpha rays, beta rays, gamma rays, x rays, and accelerated electron beam.
Claim 6
Dependent Claim 25 words
Process of claim 1, wherein the mixing ratio of said organic monomer to inorganic material is within the range of 9:1 to 1:9 by weight.
Claim 7
Dependent Claim 12 words
Process of claim 5, wherein said mixing ratio is 4:6 by weight.
Claim 8
Dependent Claim 30 words
Process of claim 4, wherein said accelerating electron beam is employed with a beam voltage of between 150 KV and 500 KV, and beam current is more than 25 mA.
Claim 9
Dependent Claim 12 words
Process of claim 7, wherein said voltage is less than 300 KV.

References Cited (Backward Citations)

US3505128A Cited
US3532611A Cited
US3501390A Cited
US3671295A Cited
US3519495A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-03-24 1978-09-23 1979-03-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-03-24 1982-09-23 1983-03-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-03-24 1986-09-23 1987-03-25 $7700.00 Window Closed / Lapsed

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