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US3872209A Expired / Lapsed US ⏱️ 0.0 years remaining

Ion exchange process for the recovery of metals

Assignee: Hazen Research Inc
•
Filing: 1972-03-17
•
Granted: 1975-03-18
•
Expires: 1992-03-17
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Abstract

Abstract A process for recovering copper values from an acidic aqueous medium which comprises contacting the medium with a mixed extraction reagent. The reagent comprises an organic solvent having dissolved therein a 2-hydroxy benzophenoxime or mixtures thereof and an organo phosphoric acid in an amount up to about 4 percent by volume of the solvent. The invention includes the composition comprised of the substituted hydroxy benzophenoxime and the organophosphoric acid.

Inventors

  • 👤 Wayne C Hazen
  • 👤 Enzo L Coltrinari

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 05:44
CPC Classifications
C; C22; C22B; C22B3/00; C22B3/20; C22B3/26; C22B3/40; C22B3/409; C01; C01G; C01G3/00; C01G3/003; Y; Y02; Y02P; Y02P10/00; Y02P10/20

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 64 words
A PROCESS FOR THE RECOVERY OF COPPER VALUES FROM AN AQUEOUS MEDIUM COMPRISING CONTACTING SAID AQUEOUS MEDIUM FOR A TIME UP TO ABOUT ONE MINUTE WITH A MIXED EXTRACTION REAGENT, THE MIXED EXTRACTION REAGENT COMPRISING A WATERIMMISCIBLE ORGANIC SOLVENT HAVING DISSOLVED THEREIN A2HYDROXY BENZOPHENOXIME HAVING A SOLUBILITY OF AT LEAST 2% BY WEIGHT IN THE ORGANIC SOLVENT AND AN ORGANOPHOSPHORIC ACID HAVING THE FORMULA:
Claim 2
Dependent Claim 64 words
A PROCESS FOR THE RECOVERY OF COPPER VALUES FROM AN AQUEOUS MEDIUM COMPRISING CONTACTING SAID AQUEOUS MEDIUM FOR A TIME UP TO ABOUT ONE MINUTE WITH A MIXED EXTRACTION REAGENT, THE MIXED EXTRACTION REAGENT COMPRISING A WATERIMMISCIBLE ORGANIC SOLVENT HAVING DISSOLVED THEREIN A2HYDROXY BENZOPHENOXIME HAVING A SOLUBILITY OF AT LEAST 2% BY WEIGHT IN THE ORGANIC SOLVENT AND AN ORGANOPHOSPHORIC ACID HAVING THE FORMULA:
Claim 3
Dependent Claim 35 words
The process of claim 1 in which the 2-hydroxy benzophenoxime is a member selected from the group consisting of alkyl substituted, ethylenically unsaturated aliphatic substituted and alkyl or ethylenically unsaturated aliphatic ether substituted 2-hydroxy benzophenoximes.
Claim 4
Dependent Claim 13 words
The process of claim 2 in which the 2-hydroxy benzophenoxime has the formula:
Claim 5
Dependent Claim 17 words
The process of claim 3 in which R of the 2-hydroxy benzophenoxime is an ethylenically unsaturated group.
Claim 6
Dependent Claim 20 words
The process of claim 3 in which R'' of the 2-hydroxy benzophenoxime is an unsubstituted branched chain aliphatic hydrocarbon group.
Claim 7
Dependent Claim 19 words
The process of claim 3 in which R of the 2-hydroxy benzophenoxime is an unsubstituted branched chain hydrocarbon group.
Claim 8
Dependent Claim 21 words
The process of claim 3 in which at least one R group of the 2-hydroxy benzophenoxime is in the 5 POSITION.
Claim 9
Dependent Claim 25 words
The process of claim 1 in which the 2-hydroxy benzophenoxime is present in an amount up to about 20 percent by volume of the solvent.
Claim 10
Dependent Claim 24 words
The process of claim 1 in which the organophosphoric acid is present in an amount of about 1 percent by volume of the solvent.
Claim 11
Dependent Claim 14 words
The process of claim 1 in which the organophosphoric acid is di-2-ethylhexyl phosphoric acid.
Claim 12
Dependent Claim 14 words
The process of claim 1 in which the organophosphoric acid is di-decyl phosphoric acid.
Claim 13
Dependent Claim 14 words
The process of claim 1 in which the organophosphoric acid is isoamyl phosphoric acid.
Claim 14
Dependent Claim 14 words
The process of claim 1 in which the organophosphoric acid is amyl phosphoric acid.

References Cited (Backward Citations)

US2992894A Cited
US3592775A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-03-17 1978-09-16 1979-03-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-03-17 1982-09-16 1983-03-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-03-17 1986-09-16 1987-03-18 $7700.00 Window Closed / Lapsed

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