Patent EP0421031A1 successfully refreshed from Google Patents.
US3872064A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Liquid hydrocarbon derived resin
Assignee: Goodyear Tire and Rubber Co
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Filing: 1974-01-14
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Granted: 1975-03-18
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Expires: 1994-01-14
Abstract
Abstract There is disclosed a hydrocarbon-derived resin having a structure characterized by a softening point in the range of about 10*C. to about 30*C., a viscosity at about 25*C. in the range of about 400 to about 100,000 centipoises and comprising from about 40 to about 80 weight percent units derived from piperylene and correspondingly from about 60 to about 20 weight percent units derived from 2-methyl-2-butene. The invention is typically prepared by polymerizing the monomer mixture in the presence of a catalyst selected from boron trifluoride and boron trifluoride etherate. The resin has particular utility as a modifier, extender and tackifier for natural and synthetic rubber.
Inventors
- 👤 Henry A Pace
- 👤 Cyr David R St
- 👤 Herbert L Bullard
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 20:32
CPC Classifications
C; C08; C08F; C08F240/00; C08F10/00; C08F36/00; C08F36/02; C08F36/04
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
222 words
A HYDROCARBON-DERIVED RESIN HAVING A STRUCTURE CHARACTERIZED BY A SOFTENING POINT IN THE RANGE OF ABOUT 15*C TO ABOUT 25*C. A VISCOSITY AT ABOUT 25*C IN THE RANGE OF ABOUT 1,000 TO ABOUT 20,000 CENTIPOISES AND COMPRISING FROM ABOUT 50 TO ABOUT 75 WEIGHT PERCENT UNITS DERIVED FROM PIPERYLENE AND CORRESPONDINGLY FROM ABOUT 50 TO ABOUT 25 WEIGHT PERCENT UNITS DERIVED FROM 2-METHYL-2-BUTENE, PREPARED BY THE METHOD WHICH COMPRISES POLYMERIZING A MIXTURE COMPRISING FROM ABOUT 35 TO ABOUT 65 WEIGHT PERCENT PIPERYLENE AND CORRESPONDINGLY FROM ABOUT 65 WEIGHT PERCENT PIPERYLENE AND 2-METHYL-2-BUTENE, AND CONTAINING UP TO ABOUT 20 WEIGHT PERCENT OF AT LEAST ONE OTHER UNSATURATED HYDROCARBON SELECTED FROM AT LEAST ONE OF THE GROUP CONSISTING OF PIPERYLENE DIMERS PIPERYLENE TRIMERS AND OTHER UNSATURATED HYDROCARBONS CONTAINING FROM 4 TO 6 CARBON ATOMS BASED ON 100 WEIGHT PERCENT OF SAID PIPERYLENE 2-METHYL-2-BUTENE MIXTURE AT A TEMPERATURE IN THE RANGE OF ABOUT 10*C TO ABOUT 500*C IN THE PRESENCE OF A CATALYST SELECTED FROM THE GROUP CONSISTING OF BORON TRIFLUORIDE AND BORON TRIFLUORIDE ETHERATE, WHEREIN THE ETHERATE IS DERIVED FROM BORON TRIFLUORIDE AND AN ETHER SELECTED FROM DIMETHYL ETHER, DIETHYL ETHER, METHYL ETHYL ETHER, DI-N-PROPYL ETHER, DIISOPROPYL ETHER, DI-N-BUTYL ETHER, DIISOBUTYL ETHER, DI-T-BUTYL ETHER, DI-N-AMYL ETHER, DIISOAMYL ETHER, DI-T-AMYL ETHER, ETHYL AMYL ETHER, DIISOHEXYL ETHER, DIN-HEXYL ETHER, DI-T-HEXYL ETHER AND BUTYL (2-ETHYL HEXYL) ETHER.
Claim 2
Dependent Claim
222 words
A HYDROCARBON-DERIVED RESIN HAVING A STRUCTURE CHARACTERIZED BY A SOFTENING POINT IN THE RANGE OF ABOUT 15*C TO ABOUT 25*C. A VISCOSITY AT ABOUT 25*C IN THE RANGE OF ABOUT 1,000 TO ABOUT 20,000 CENTIPOISES AND COMPRISING FROM ABOUT 50 TO ABOUT 75 WEIGHT PERCENT UNITS DERIVED FROM PIPERYLENE AND CORRESPONDINGLY FROM ABOUT 50 TO ABOUT 25 WEIGHT PERCENT UNITS DERIVED FROM 2-METHYL-2-BUTENE, PREPARED BY THE METHOD WHICH COMPRISES POLYMERIZING A MIXTURE COMPRISING FROM ABOUT 35 TO ABOUT 65 WEIGHT PERCENT PIPERYLENE AND CORRESPONDINGLY FROM ABOUT 65 WEIGHT PERCENT PIPERYLENE AND 2-METHYL-2-BUTENE, AND CONTAINING UP TO ABOUT 20 WEIGHT PERCENT OF AT LEAST ONE OTHER UNSATURATED HYDROCARBON SELECTED FROM AT LEAST ONE OF THE GROUP CONSISTING OF PIPERYLENE DIMERS PIPERYLENE TRIMERS AND OTHER UNSATURATED HYDROCARBONS CONTAINING FROM 4 TO 6 CARBON ATOMS BASED ON 100 WEIGHT PERCENT OF SAID PIPERYLENE 2-METHYL-2-BUTENE MIXTURE AT A TEMPERATURE IN THE RANGE OF ABOUT 10*C TO ABOUT 500*C IN THE PRESENCE OF A CATALYST SELECTED FROM THE GROUP CONSISTING OF BORON TRIFLUORIDE AND BORON TRIFLUORIDE ETHERATE, WHEREIN THE ETHERATE IS DERIVED FROM BORON TRIFLUORIDE AND AN ETHER SELECTED FROM DIMETHYL ETHER, DIETHYL ETHER, METHYL ETHYL ETHER, DI-N-PROPYL ETHER, DIISOPROPYL ETHER, DI-N-BUTYL ETHER, DIISOBUTYL ETHER, DI-T-BUTYL ETHER, DI-N-AMYL ETHER, DIISOAMYL ETHER, DI-T-AMYL ETHER, ETHYL AMYL ETHER, DIISOHEXYL ETHER, DIN-HEXYL ETHER, DI-T-HEXYL ETHER AND BUTYL (2-ETHYL HEXYL) ETHER.
Claim 3
Dependent Claim
44 words
The hydrocarbon-derived resin of claim 1 where said other unsaturated hydrocarbons are selected from at least one of the group consisting essentially of piperylene dimers, piperylene trimers, 2-methyl-1-butene, 2,3-dimethyl-1-butene, 2,3-dimethyl-2-butene, 3,3-dimethyl-1-butene, 1-pentene, 2-pentene, 2-methyl-1-pentene, 2-methyl-2-pentene, 3-methyl-2-pentene, 4-methyl-1-pentene, 4-methyl-2-pentene, 2-hexene, isoprene, cyclopentene, cyclohexene and 1,3-cyclopentadiene.
Claim 4
Dependent Claim
27 words
The hydrocarbon-derived resin according to claim 1 where the catalyst is selected from boron trifluoride and a boron trifluoride etherate derived from boron trifluoride and diethyl ether.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-03-17 | 1978-09-16 | 1979-03-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-03-17 | 1982-09-16 | 1983-03-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-03-17 | 1986-09-16 | 1987-03-18 | $7700.00 | Window Closed / Lapsed |