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US3872064A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid hydrocarbon derived resin

Assignee: Goodyear Tire and Rubber Co
•
Filing: 1974-01-14
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Granted: 1975-03-18
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Expires: 1994-01-14
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Abstract

Abstract There is disclosed a hydrocarbon-derived resin having a structure characterized by a softening point in the range of about 10*C. to about 30*C., a viscosity at about 25*C. in the range of about 400 to about 100,000 centipoises and comprising from about 40 to about 80 weight percent units derived from piperylene and correspondingly from about 60 to about 20 weight percent units derived from 2-methyl-2-butene. The invention is typically prepared by polymerizing the monomer mixture in the presence of a catalyst selected from boron trifluoride and boron trifluoride etherate. The resin has particular utility as a modifier, extender and tackifier for natural and synthetic rubber.

Inventors

  • 👤 Henry A Pace
  • 👤 Cyr David R St
  • 👤 Herbert L Bullard

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 20:32
CPC Classifications
C; C08; C08F; C08F240/00; C08F10/00; C08F36/00; C08F36/02; C08F36/04

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 222 words
A HYDROCARBON-DERIVED RESIN HAVING A STRUCTURE CHARACTERIZED BY A SOFTENING POINT IN THE RANGE OF ABOUT 15*C TO ABOUT 25*C. A VISCOSITY AT ABOUT 25*C IN THE RANGE OF ABOUT 1,000 TO ABOUT 20,000 CENTIPOISES AND COMPRISING FROM ABOUT 50 TO ABOUT 75 WEIGHT PERCENT UNITS DERIVED FROM PIPERYLENE AND CORRESPONDINGLY FROM ABOUT 50 TO ABOUT 25 WEIGHT PERCENT UNITS DERIVED FROM 2-METHYL-2-BUTENE, PREPARED BY THE METHOD WHICH COMPRISES POLYMERIZING A MIXTURE COMPRISING FROM ABOUT 35 TO ABOUT 65 WEIGHT PERCENT PIPERYLENE AND CORRESPONDINGLY FROM ABOUT 65 WEIGHT PERCENT PIPERYLENE AND 2-METHYL-2-BUTENE, AND CONTAINING UP TO ABOUT 20 WEIGHT PERCENT OF AT LEAST ONE OTHER UNSATURATED HYDROCARBON SELECTED FROM AT LEAST ONE OF THE GROUP CONSISTING OF PIPERYLENE DIMERS PIPERYLENE TRIMERS AND OTHER UNSATURATED HYDROCARBONS CONTAINING FROM 4 TO 6 CARBON ATOMS BASED ON 100 WEIGHT PERCENT OF SAID PIPERYLENE 2-METHYL-2-BUTENE MIXTURE AT A TEMPERATURE IN THE RANGE OF ABOUT 10*C TO ABOUT 500*C IN THE PRESENCE OF A CATALYST SELECTED FROM THE GROUP CONSISTING OF BORON TRIFLUORIDE AND BORON TRIFLUORIDE ETHERATE, WHEREIN THE ETHERATE IS DERIVED FROM BORON TRIFLUORIDE AND AN ETHER SELECTED FROM DIMETHYL ETHER, DIETHYL ETHER, METHYL ETHYL ETHER, DI-N-PROPYL ETHER, DIISOPROPYL ETHER, DI-N-BUTYL ETHER, DIISOBUTYL ETHER, DI-T-BUTYL ETHER, DI-N-AMYL ETHER, DIISOAMYL ETHER, DI-T-AMYL ETHER, ETHYL AMYL ETHER, DIISOHEXYL ETHER, DIN-HEXYL ETHER, DI-T-HEXYL ETHER AND BUTYL (2-ETHYL HEXYL) ETHER.
Claim 2
Dependent Claim 222 words
A HYDROCARBON-DERIVED RESIN HAVING A STRUCTURE CHARACTERIZED BY A SOFTENING POINT IN THE RANGE OF ABOUT 15*C TO ABOUT 25*C. A VISCOSITY AT ABOUT 25*C IN THE RANGE OF ABOUT 1,000 TO ABOUT 20,000 CENTIPOISES AND COMPRISING FROM ABOUT 50 TO ABOUT 75 WEIGHT PERCENT UNITS DERIVED FROM PIPERYLENE AND CORRESPONDINGLY FROM ABOUT 50 TO ABOUT 25 WEIGHT PERCENT UNITS DERIVED FROM 2-METHYL-2-BUTENE, PREPARED BY THE METHOD WHICH COMPRISES POLYMERIZING A MIXTURE COMPRISING FROM ABOUT 35 TO ABOUT 65 WEIGHT PERCENT PIPERYLENE AND CORRESPONDINGLY FROM ABOUT 65 WEIGHT PERCENT PIPERYLENE AND 2-METHYL-2-BUTENE, AND CONTAINING UP TO ABOUT 20 WEIGHT PERCENT OF AT LEAST ONE OTHER UNSATURATED HYDROCARBON SELECTED FROM AT LEAST ONE OF THE GROUP CONSISTING OF PIPERYLENE DIMERS PIPERYLENE TRIMERS AND OTHER UNSATURATED HYDROCARBONS CONTAINING FROM 4 TO 6 CARBON ATOMS BASED ON 100 WEIGHT PERCENT OF SAID PIPERYLENE 2-METHYL-2-BUTENE MIXTURE AT A TEMPERATURE IN THE RANGE OF ABOUT 10*C TO ABOUT 500*C IN THE PRESENCE OF A CATALYST SELECTED FROM THE GROUP CONSISTING OF BORON TRIFLUORIDE AND BORON TRIFLUORIDE ETHERATE, WHEREIN THE ETHERATE IS DERIVED FROM BORON TRIFLUORIDE AND AN ETHER SELECTED FROM DIMETHYL ETHER, DIETHYL ETHER, METHYL ETHYL ETHER, DI-N-PROPYL ETHER, DIISOPROPYL ETHER, DI-N-BUTYL ETHER, DIISOBUTYL ETHER, DI-T-BUTYL ETHER, DI-N-AMYL ETHER, DIISOAMYL ETHER, DI-T-AMYL ETHER, ETHYL AMYL ETHER, DIISOHEXYL ETHER, DIN-HEXYL ETHER, DI-T-HEXYL ETHER AND BUTYL (2-ETHYL HEXYL) ETHER.
Claim 3
Dependent Claim 44 words
The hydrocarbon-derived resin of claim 1 where said other unsaturated hydrocarbons are selected from at least one of the group consisting essentially of piperylene dimers, piperylene trimers, 2-methyl-1-butene, 2,3-dimethyl-1-butene, 2,3-dimethyl-2-butene, 3,3-dimethyl-1-butene, 1-pentene, 2-pentene, 2-methyl-1-pentene, 2-methyl-2-pentene, 3-methyl-2-pentene, 4-methyl-1-pentene, 4-methyl-2-pentene, 2-hexene, isoprene, cyclopentene, cyclohexene and 1,3-cyclopentadiene.
Claim 4
Dependent Claim 27 words
The hydrocarbon-derived resin according to claim 1 where the catalyst is selected from boron trifluoride and a boron trifluoride etherate derived from boron trifluoride and diethyl ether.

References Cited (Backward Citations)

US2581154A Cited
US3577398A Cited
US3509239A Cited
US3541188A Cited
US3505300A Cited
US3692756A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-03-17 1978-09-16 1979-03-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-03-17 1982-09-16 1983-03-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-03-17 1986-09-16 1987-03-18 $7700.00 Window Closed / Lapsed

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