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US3872062A Expired / Lapsed US ⏱️ 0.0 years remaining

Imide additives for sulfur vulcanizable polymers

Assignee: Goodyear Tire and Rubber Co
•
Filing: 1974-03-07
•
Granted: 1975-03-18
•
Expires: 1994-03-07
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Abstract

Abstract Imides such as N-(morpholinothio)phthalimide are used to affect the vulcanization characteristics of sulfur vulcanizable polymers by increasing the state of vulcanization and/or improving scorch resistance and/or increasing the rate of vulcanization.

Inventors

  • 👤 John P Lawrence

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 12:19
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/36; C08K5/43

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 17 words
A SULFUR VULCANIZABLE DIENE POLYMER HAVING INCORPORATED THEREIN AT LEAST ONE IMIDE HAVING THE FOLLOWING STRUCTURAL FORMULA
Claim 2
Dependent Claim 17 words
A SULFUR VULCANIZABLE DIENE POLYMER HAVING INCORPORATED THEREIN AT LEAST ONE IMIDE HAVING THE FOLLOWING STRUCTURAL FORMULA
Claim 3
Dependent Claim 19 words
The sulfur vulcanizable diene polymer according to claim 1 wherein the polymer has incorporated therein an organic accelerating agent.
Claim 4
Dependent Claim 19 words
The sulfur vulcanizable diene polymer according to claim 1 wherein the polymer has incorporated therein a sulfur vulcanizing agent.
Claim 5
Dependent Claim 26 words
The sulfur vulcanizable diene polymer according to claim 2 wherein the organic accelerating agent is a primary accelerator and the polymer has incorporated therein elemental sulfur.
Claim 6
Dependent Claim 33 words
The sulfur vulcanizable diene polymer according to claim 1 wherein the imide is present in the amount of from 0.25 part to 5.0 parts by weight per 100 parts by weight of polymer.
Claim 7
Dependent Claim 51 words
The sulfur vulcanizable diene polymer according to claim 1 wherein R is Selected from the group consisting of 4,5-cyclohexenylene, orthophenylene, ethylene and 1,3-propylene, and A is selected from the group consisting of divalent radicals derived from piperazine, 2,5-dimethylpiperazine, imidazolidine, hexahydropyrimidine, homopiperazine, N,N''-dimethyl-ethylenediamine, N,N''-dimethyl-1,3-propylenediamine, N,N''-dimethyl-1,6-hexamethylenediamine, N,N''-dimethyl-1,4-cyclohexylenediamine, N,N''-dimethyl-p-phenylenediamine, 4,4''-ethylenedi(piperidine), 4,4''-trimethylenedi(piperidine), 4,4''-tetramethylenedi(piperidine) and 4,4''-hexamethylenedi(piperidine).
Claim 8
Dependent Claim 23 words
The sulfur vulcanizable diene polymer according to claim 1 wherein the imide is selected from the group consisting of 1,4-bis(phthalimidothio)-piperazine; 1,4-bis(phthalimidothio)-2,5-dimethylpiperazine and 4,4''-tetramethylenedi(piperidinothio)-bis(phthalimide).
Claim 9
Dependent Claim 31 words
The sulfur vulcanizable diene polymer according to claim 1 wherein the polymer is selected from the group consisting of natural rubber, cis-1,4 polybutadiene, cis-1,4 polyisoprene and copolymers of butadiene and styrene.

References Cited (Backward Citations)

US3573262A Cited
US3562225A Cited
US3671503A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-03-17 1978-09-16 1979-03-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-03-17 1982-09-16 1983-03-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-03-17 1986-09-16 1987-03-18 $7700.00 Window Closed / Lapsed

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