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US3865797A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of petroleum resins of varying softening points

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1973-09-24
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Granted: 1975-02-11
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Expires: 1993-09-24
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Abstract

Abstract A petroleum resin feedstock comprises a C5 stream distilled from a cracked petroleum fraction to which has been added butadiene raffinate which comprises isobutene, butenes-1 and -2 and butanes and which is what remains of a C4 fraction after removal of butadiene. The feedstock may be polymerised to a petroleum resin by means of a Friedel Crafts catalyst.

Inventors

  • 👤 David Richard Joy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 18:27
CPC Classifications
C; C08; C08F; C08F240/00; C08F10/00

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 93 words
A PROCESS FOR THE PRODUCTION OF PETROLEUM RESINS OF VARYING SOFTENING POINTS IN WHICH THE RESIDUE REMAINING AFTER THE REMOVAL OF BUTADIENE FROM A C4 FRACTION AND WHICH CONSISTS OF ISO-BUTENE, BUTENE-1, CIS- AND TRANS-BUTENE-2 AND BUTANES IS ADDED TO A C5 STREAM BOILING IN THE RANGE 10* TO 80* C WHICH IS DERIVED FROM A THERMALLY OR STEAM CRACKED NAPHTHA OR GAS OIL AND THE RESULTING MIXTURE POLYMERIZED BY MEANS OF A FRIEDEL CRAFTS CATALYST, THE AMOUNT OF SAID RESIDUE ADDED BEING CHOSEN TO ACHIEVE LOWERING THE SOFTENING POINT IN THE RESIN.
Claim 2
Dependent Claim 93 words
A PROCESS FOR THE PRODUCTION OF PETROLEUM RESINS OF VARYING SOFTENING POINTS IN WHICH THE RESIDUE REMAINING AFTER THE REMOVAL OF BUTADIENE FROM A C4 FRACTION AND WHICH CONSISTS OF ISO-BUTENE, BUTENE-1, CIS- AND TRANS-BUTENE-2 AND BUTANES IS ADDED TO A C5 STREAM BOILING IN THE RANGE 10* TO 80* C WHICH IS DERIVED FROM A THERMALLY OR STEAM CRACKED NAPHTHA OR GAS OIL AND THE RESULTING MIXTURE POLYMERIZED BY MEANS OF A FRIEDEL CRAFTS CATALYST, THE AMOUNT OF SAID RESIDUE ADDED BEING CHOSEN TO ACHIEVE LOWERING THE SOFTENING POINT IN THE RESIN.
Claim 3
Dependent Claim 22 words
The process of claim 1 in which the amount of residue which has been added is up to 30 percent by weight.
Claim 4
Dependent Claim 29 words
The process of claim 1 wherein the mixture has been heated to a temperature of at least 100* C so as to dimerise any mono-cyclopentadiene which may be present.
Claim 5
Dependent Claim 24 words
The process of claim 2 wherein the C5 stream contains cis-and trans- piperylene, n-pentane, isopentane, pentene-1, dicylopentadiene, trans-pentene-2, 2-methyl-butene-1, 3-methylbutene-1, 2-methylbutene-2, cyclopentene and cyclopentane.
Claim 6
Dependent Claim 31 words
The process of claim 1 in which the Friedel Crafts catalyst is a halide of an element selected from the group consisting of aluminium, iron, tin, boron, zinc, antimony and titanium.
Claim 7
Dependent Claim 20 words
The process of claim 5 in which the catalyst is aluminium chloride complexed with hydrogen chloride in an aromatic solvent.
Claim 8
Dependent Claim 43 words
The process of claim 6 in which the aromatic solvent is toluene, xylene or a benzene which is liquid at the temperature of the polymerisation and which is substituted by at least one secondary or tertiary alkyl group or by a cycloalkyl group.
Claim 9
Dependent Claim 48 words
A process for the production of a petroleum resin in which the feedstock of claim 4 is contacted with a catalyst comprising aluminium chloride and hydrogen chloride in toluene, xylene, cumene, tert-butylbenzene, p-cymene, p-isobutyl toluene or p-ethyl-tert.amylbenzene at a temperature in the range -100* C to +150* C.

References Cited (Backward Citations)

US3661870A Cited
US3709854A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-02-10 1978-08-12 1979-02-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-02-10 1982-08-12 1983-02-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-02-10 1986-08-12 1987-02-11 $7700.00 Window Closed / Lapsed

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