US3864283A
Expired / Lapsed
US
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Hydrocarbon conversion catalyst
Assignee: Shell USA Inc
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Filing: 1972-10-19
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Granted: 1975-02-04
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Expires: 1992-10-19
Abstract
Abstract A hydrocarbon conversion catalyst is prepared by mixing about 10-90%wt of channel pore structure zeolite with about 90-10%wt of three-dimensional pore structure zeolite, decationizing the zeolites either before or after mixing to reduce the alkali metal content to less than about 0.5%wt, then incorporating a catalytic amount of a hydrogenation metal component into the mixed zeolites.
Inventors
- 👤 Hans U Schutt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 14:09
CPC Classifications
C; C10; C10G; C10G47/00; C10G47/02; C10G47/10; C10G47/12; C10G47/16; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/80; C07; C07C; C07C5/00; C07C5/22; C07C5/27; C07C5/2702; C07C5/2724; C07C5/2767; C07C5/277; C07C5/2791; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/42; B01J29/08; B01J29/084; B01J29/18; B01J29/60; C10G2400/00; C10G2400/02
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
100 words
A METHOD OF PREPARING A MIXED CRYSTALLINE ALUMINOSILICATE ZEOLITE HYDROCONVERSION CATALYST WHICH COMPRISES FIRST PHYSICALLY MIXING ABOUT 10-90% WT OF CHANNEL PORE STRUCTURE ZEOLITE SELECTED FROM THE GROUP CONSISTING OF L-SIEVE AND MORDENITE AND WITH ABOUT 90-10% WT OF THREE-DIMENSIONAL PORE STRUCTURE Y-SIEVE ZEOLITE, DECATIONIZING THE ZEOLITES EITHER BEFORE OR AFTER MIXING TO REDUCE THE ALKALI METAL CONTENT TO LESS THAN BOUT 0.5% WT, THEN INCORPORATING A CATALYTIC AMOUNT OF A HYDROGENATION METAL COMPONENT SELECTED FROM THE GROUP CONSISTING OF GROUP VII AND GROUP VIB METALS OF THE PERIODIC CHART INTO THE MIXED ZEOLITES AND DRYING AND CALCINING THE CATALYST.
Claim 2
Independent Claim
100 words
A METHOD OF PREPARING A MIXED CRYSTALLINE ALUMINOSILICATE ZEOLITE HYDROCONVERSION CATALYST WHICH COMPRISES FIRST PHYSICALLY MIXING ABOUT 10-90% WT OF CHANNEL PORE STRUCTURE ZEOLITE SELECTED FROM THE GROUP CONSISTING OF L-SIEVE AND MORDENITE AND WITH ABOUT 90-10% WT OF THREE-DIMENSIONAL PORE STRUCTURE Y-SIEVE ZEOLITE, DECATIONIZING THE ZEOLITES EITHER BEFORE OR AFTER MIXING TO REDUCE THE ALKALI METAL CONTENT TO LESS THAN BOUT 0.5% WT, THEN INCORPORATING A CATALYTIC AMOUNT OF A HYDROGENATION METAL COMPONENT SELECTED FROM THE GROUP CONSISTING OF GROUP VII AND GROUP VIB METALS OF THE PERIODIC CHART INTO THE MIXED ZEOLITES AND DRYING AND CALCINING THE CATALYST.
Claim 3
Dependent Claim
40 words
The method of claim 1 wherein about 25-75%wt of L-sieve or mordenite are physically mixed with about 75-25%wt of Y-sieve zeolite and the hydrogenation metal component is selected from the group consisting of platinum, palladium, nickel, cobalt, molybdenum and tungsten.
Claim 4
Dependent Claim
21 words
The method of claim 1 wherein the zeolites are decationized to reduce the alkali metal content to less than about 0.1%wt.
Claim 5
Dependent Claim
85 words
A hydroconversion catalyst composition consisting essentially of a catalytic amount of a hydrogenation metal component selected from the group consisting of the Group VIII and Group VIB metals of the periodic chart incorporated into a physically mixed zeolite support after said support is mixed, said zeolite mixture consisting of about 10-90%wt of channel pore structure zeolite selected from the group consisting of L-sieve and mordenite and about 90-10%wt of three-dimensional pore structure Y-sieve zeolite, and having an alkali metal content of less than about 0.5%wt.
Claim 6
Dependent Claim
85 words
A hydroconversion catalyst composition consisting essentially of a catalytic amount of a hydrogenation metal component selected from the group consisting of the Group VIII and Group VIB metals of the periodic chart incorporated into a physically mixed zeolite support after said support is mixed, said zeolite mixture consisting of about 10-90%wt of channel pore structure zeolite selected from the group consisting of L-sieve and mordenite and about 90-10%wt of three-dimensional pore structure Y-sieve zeolite, and having an alkali metal content of less than about 0.5%wt.
Claim 7
Dependent Claim
40 words
The composition of claim 4 wherein about 25-75%wt of L-sieve or mordenite are physically mixed with about 75-25%wt of Y-sieve zeolite and the hydrogenation metal component is selected from the group consisting of platinum, palladium, nickel, cobalt, molybdenum and tungsten.
Claim 8
Dependent Claim
18 words
The composition of claim 4 wherein the alkali metal content of the zeolites is less than about 0.1%wt.
Claim 9
Dependent Claim
27 words
The composition of claim 6 wherein the hydrogenation metal component is from about 0.1-1.0%wt platinum or palladium and the mixed zeolites are decationized mordenite and stabilized Y-sieve.
Claim 10
Dependent Claim
16 words
The composition of claim 6 wherein the hydrogenation metal component is 5-30%wt nickel and 0.05-10%wt tungsten.
Claim 11
Dependent Claim
31 words
The composition of claim 6 wherein the mixed zeolite support consists of about 25-75% wt of said channel pore structure zeolite and about 75-25% wt of said three-dimensional pore structure zeolite.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-02-03 | 1978-08-05 | 1979-02-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-02-03 | 1982-08-05 | 1983-02-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-02-03 | 1986-08-05 | 1987-02-04 | $7700.00 | Window Closed / Lapsed |