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US3862071A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous Thermosetting Acrylic Enamel Containing Metallic Flake Pigment

Assignee: EIDP Inc
•
Filing: 1973-05-15
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Granted: 1975-01-21
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Expires: 1993-05-15
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Abstract

Abstract The aqueous thermosetting acrylic coating composition contains 0.25-1% by weight of uniformly dispersed metallic flake pigments and has the following film-forming constituents: 1. AN ACRYLIC POLYMER OF STYRENE AND/OR METHYL METHACRYLATE, AN ALKYL ACRYLATE OR AN ALKYL METHACRYLATE OTHER THAN METHYL METHACRYLATE, A HYDROXY ALKYL ACRYLATE OR A HYDROXY ALKYL METHACRYLATE AND AN Alpha , Beta -UNSATURATED CARBOXYLIC ACID WHEREIN THE POLYMER HAS AN ACID NUMBER OF 35-150 AND A CARBOXYL/HYDROXYL RATIO OF 1:0.2 TO 1:1.8; AND 2. A WATER-SOLUBLE OR WATER-DISPERSIBLE ALKYLATED MELAMINE FORMALDEHYDE RESIN; THE IMPROVEMENT USED WITH THIS COATING COMPOSITION COMPRISES 0.5-5% BY WEIGHT, BASED ON THE WEIGHT OF THE FILM-FORMING CONSTITUENTS, OF AN ACRYLIC COPOLYMER OF 75-95% BY WEIGHT OF AN ALKYL ACRYLATE HAVING 1-8 CARBON ATOMS IN THE ALKYL GROUP AND 5-25% BY WEIGHT OF ACRYLIC ACID OR METHACRYLIC ACID AND HAS A WEIGHT AVERAGE MOLECULAR WEIGHT OF 2,500 TO 45,000; THE NOVEL COATING COMPOSITION IS USEFUL AS AN EXTERIOR FINISH FOR AUTOMOBILE AND TRUCK BODIES.

Inventors

  • 👤 Carlo James Di

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 12:50
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/062; C09D133/066; C08; C08K; C08K3/00; C08K3/02; C08K3/08; C08L; C08L33/00; C08L33/04; C08L33/06; C08L33/08; C08L61/00; C08L61/20; C08L61/26; C08L61/28; C08L33/062; C08L33/064

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 120 words
10-40% by weight, based on the weight of the film-forming constituent, of a water dispersible alkylated melamine formaldehyde resin having 1-4 carbon atoms in the alkyl groups; and the composition is at least partially neutralized with a water-soluble amine and has a pH of about 6-9; the improvement comprising 0.5-5% by weight, based on the weight of the film-forming constituents, of an acrylic copolymer having a weight average molecular weight of about 2,500 to 45,000 and consisting essentially of 75-95% by weight, based on the weight of the acrylic copolymer of an alkyl acrylate having 1-8 carbon atoms in the alkyl group and 5-25% by weight, based on the weight of the acrylic copolymer, of acrylic acid or methacrylic acid.
Claim 2
Dependent Claim 27 words
The coating composition of claim 1 in which the acrylic copolymer cOnsists essentially of 75-95% by weight of butyl acrylate and 5-25% by weight of acrylic acid.
Claim 3
Dependent Claim 84 words
10-40% by weight, based on the weight of the film-forming constituent, of a hexa(methoxymethyl) melamine; and the composition is at least partially neutralized with a water-soluble amine and has a pH of about 7.1 - 7.5; the improvement in use therewith comprises 0.5-5% by weight, based on the weight of the film-forming constituents of an acrylic copolymer consisting essentially of 85% by weight of butyl acrylate and 15% by weight of acrylic acid having a weight average molecular weight of about 2,500 to 12,000.
Claim 4
Dependent Claim 11 words
The coating composition of claim 2 containing 0.1-40% by weight pigment.
Claim 5
Dependent Claim 60 words
The coating composition of claim 3 in which the acrylic polymer consists essentially of 50-60% by weight of methyl methacrylate, 30-40% by weight of butyl acrylate, 5-10% by weight of hydroxy ethyl acrylate and 4-12% by weight of acrylic acid and the polymer has an acid number of about 35-100 and a carboxyl to hydroxyl ratio of 1:0.3 to 1:1.5.
Claim 6
Dependent Claim 60 words
The coating composition of claim 3 in which the acrylic polymer consists essentially of 28-32% by weight of styrene, 22-26% by weight of methyl methacrylate, 30-35% by weight of butyl acrylate, 7-9% by weight of hydroxy ethyl acrylate, 4-6% by weight of acrylic acid, and has an acid number of 30-50, a carboxyl to hydroxyl ratio of 1:0.4 to 1:1.5.
Claim 7
Dependent Claim 44 words
The coating composition of claim 3 in which the acrylic polymer consists essentially of 54% methyl methacrylate, 34% butyl acrylate, 6% 2-hydroxyethyl acrylate and 6% acrylic acid and has an acid number of about 45-50 and a carboxyl to hydroxyl ratio of about 1:0.6.
Claim 8
Dependent Claim 17 words
The aqueous thermosetting acrylic enamel coating composition of claim 1; wherein the film-forming constituents consist essentially of

References Cited (Backward Citations)

US3218280A Cited
US3403088A Cited
US3503918A Cited
US3674734A Cited
US3766156A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-01-20 1978-07-22 1979-01-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-01-20 1982-07-22 1983-01-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-01-20 1986-07-22 1987-01-21 $7700.00 Window Closed / Lapsed

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