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US3857782A Expired / Lapsed US ⏱️ 0.0 years remaining

Semipermeable membrane process and device employing an aminoethylated polymeric material as the semipermeable membrane

Assignee: Kovalus Separation Solutions LLC
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Filing: 1971-11-04
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Granted: 1974-12-31
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Expires: 1991-11-04
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Abstract

Abstract An improved permeation process particularly useful for separating low molecular weight solids, such as urea and salts as in osmotic and dialytic separation processes, employs a semipermeable membrane material characterized by having polyaminoethylene grafts. Aminoethylated polymeric materials, such as cellulose and polyamides or polyethylene imine are employed in capillary fiber form in permeation processes and devices which materials exhibit improved permeation rates, particularly for low molecular weight solids in aqueous solutions.

Inventors

  • 👤 R Crowley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:30
CPC Classifications
B; B01; B01D; B01D67/00; B01D67/0081; B01D67/0093; B01D67/00931; B01D71/00; B01D71/06; B01D71/56; B01D71/76; B01D71/82; B01D2323/00; B01D2323/38

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 119 words
IN A SEPARATORY PROCESS WHICH COMPRISES: EXPOSING UNDER FLUID PRESSURE ONE SIDE OF A SELECTED POLYMERIC PPERMEABLE MEMBRANE TO A FLUID HAVING AT LEAST ONE COMPONENT PERMEABLE TO SAID MEMBRANE, AND SEPARATING THAT PORTION OF THE FLUID WHICH PERMEATER THE MEMBRANE FROM THAT PORTION OF THE FLUID WHICH DOES NOT PERMEATE THE MEMBRANE, THE IMPROVEMENT WHICH COMPRISES: EMPLOYING AS THE SELECTED PERMEABLE POLYMERIC MEMBRANE MATERIAL A POLYMER SELCTED FROM THE GROUP CONSISTING OF POLYETHYLENE IMINE AND A POLYAMIDE CONTAINING REACTIVE NH GROUPS AND MODIFIED BY THE REACTION OF THE NH GROUPS OF THE POLYAMIDE WITH AN ETHYLENE IMINE TO CONTAIN FROM ABOUT 5 TO 60 PERCENT BY WEIGHT ETHYLENE IMINE, GENERALLY IN THE FORM OF POLYETHYLENE IMINE GRAFTS THEREON.
Claim 2
Dependent Claim 119 words
IN A SEPARATORY PROCESS WHICH COMPRISES: EXPOSING UNDER FLUID PRESSURE ONE SIDE OF A SELECTED POLYMERIC PPERMEABLE MEMBRANE TO A FLUID HAVING AT LEAST ONE COMPONENT PERMEABLE TO SAID MEMBRANE, AND SEPARATING THAT PORTION OF THE FLUID WHICH PERMEATER THE MEMBRANE FROM THAT PORTION OF THE FLUID WHICH DOES NOT PERMEATE THE MEMBRANE, THE IMPROVEMENT WHICH COMPRISES: EMPLOYING AS THE SELECTED PERMEABLE POLYMERIC MEMBRANE MATERIAL A POLYMER SELCTED FROM THE GROUP CONSISTING OF POLYETHYLENE IMINE AND A POLYAMIDE CONTAINING REACTIVE NH GROUPS AND MODIFIED BY THE REACTION OF THE NH GROUPS OF THE POLYAMIDE WITH AN ETHYLENE IMINE TO CONTAIN FROM ABOUT 5 TO 60 PERCENT BY WEIGHT ETHYLENE IMINE, GENERALLY IN THE FORM OF POLYETHYLENE IMINE GRAFTS THEREON.
Claim 3
Dependent Claim 13 words
The process of claim 1 wherein said membrane is a hollow capillary fiber.
Claim 4
Dependent Claim 31 words
The process of claim 1 wherein the membrane has a high permeability to low molecular weight components and contains from about 40 to 65 percent by weight of combined ethylene imine.
Claim 5
Dependent Claim 27 words
A reverse osmosis process according to the process of claim 1 wherein the membrane contains from about 10 to 40 percent by weight of combined ethylene imine.
Claim 6
Dependent Claim 25 words
The process of claim 1 wherein said membrane is in a tubular form, the membrane material cast onto the internal portion of a tubular support.
Claim 7
Dependent Claim 40 words
The process of claim 1 wherein the membrane is exposed to a fluid which comprises a water solution containing urea, salts and proteinaceous matter and which membrane has a selectivity which permits the passage of the water, salt and urea.
Claim 8
Dependent Claim 30 words
The process of claim 1 wherein the membrane is a hollow capillary fiber and in which the exterior portion of the fiber material has been reacted with the ethylene imine.
Claim 9
Dependent Claim 14 words
The process of claim 1 wherein the ethylene imine is an alkyl ethylene imine.
Claim 10
Dependent Claim 10 words
The capillary fibers prepared by the process of claim 2.

References Cited (Backward Citations)

US3276598A Cited
US3342724A Cited
US3472766A Cited
US3620970A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-30 1978-07-01 1978-12-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-30 1982-07-01 1982-12-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-30 1986-07-01 1986-12-31 $7700.00 Window Closed / Lapsed

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