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US3857719A Expired / Lapsed US ⏱️ 0.0 years remaining

Treatment of clays

Assignee: Cyprus Mines Corp
•
Filing: 1973-09-13
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Granted: 1974-12-31
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Expires: 1993-09-13
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Abstract

Abstract Process and system for improving the brightness of clays to a point where the reflectance of light from the clay in dry form reaches a predetermined selected value. The process involves the formation of an agitated reaction mixture comprising an aqueous slurry of the clay and a decolorizing agent reactive with the impurities in the clay. The reaction mixture is maintained at a temperature sufficient to initiate and sustain the reaction and, as the reaction proceeds, at least a portion of the mixture is passed into a light reflectance measuring zone. Visible light is directed onto the mixture in the measuring zone and the magnitude of its reflectance from the mixture is measured. The measured value of reflectance is increased by reacting the decolorizing agent with the clay impurities until the measured value reaches a value representative of the predetermined selected value of the reflectance desired in the clay in dry form. Dry clay is then recovered from the reaction mixture having the desired brightness value. The system of the invention also provides means responsive to the magnitude of the reflectance of light from the clay slurry to regulate the rate of addition of the decolorizing agent into the reaction mixture. The invention provides a rapid, efficient means for monitoring and controlling the progress of the clay beneficiation reaction by measuring the light reflectance of the slurry, and avoids the time consuming steps of sampling, dewatering and drying of clay to obtain a sample for a brightness determination while the beneficiation process is being conducted, as was heretofore necessary in the prior art.

Inventors

  • 👤 T Baak
  • 👤 D Harris

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 23:42
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/40; C09C1/42; C01; C01P; C01P2004/00; C01P2004/80; C01P2004/82; C01P2004/84; C01P2006/00; C01P2006/60

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 145 words
A PROCESS FOR BRIGHTENING CLAY TO A POINT WHERE THE REFLECTANCE OF LIGHT FORM SAID CLAY IN DRY FROM HAS A PREDETERMINED SELECTED VALUE, WHICH COMPRISES: FORMING AN AGITATED REACTION MIXTURE COMPRISING AN AQUEOUS SLURRY OF SAID CLAY AND A DECOLORIZING AGENT REACTIVE WITH THE IMPURITIES IN SAID CLAY, MAINTAINING SAID REACTION MIXTURE AT A TEMPERATURE SUFFICIENT TO INITIATE AND SUSTAIN THE REACTION BETWEEN SAID DECOLORIZING AGENT AND SAID IMPURITIES, DIRECTING VISIBLE LIGHT ONTO AT LEAST A PORTION OF SAID SLURRY, MEASURING THE MAGNITUDE OF THE REFLECTANCE OF SAID LIGHT BY SAID SLURRY, INCREASING THE MEASURED VALUE OF THE REFLECTANCE OF SAID LIGHT BY SAID SLURRY BY REACTING SAID DECOLORIZING AGENT WITH SAID CLAY IMPURITIES UNTIL THE MEASURED VALUE REACHES A VALUE REPRESENTATIVE OF SAID PREDETERMINED VALUE, AND RECOVERING FROM AQUEOUS REACTION MIXTURE DRY CLAY CHARACTERIZED BY A LIGHT REFLECTANCE OF SAID PREDETERMINED SELECTED VALUE.
Claim 2
Dependent Claim 145 words
A PROCESS FOR BRIGHTENING CLAY TO A POINT WHERE THE REFLECTANCE OF LIGHT FORM SAID CLAY IN DRY FROM HAS A PREDETERMINED SELECTED VALUE, WHICH COMPRISES: FORMING AN AGITATED REACTION MIXTURE COMPRISING AN AQUEOUS SLURRY OF SAID CLAY AND A DECOLORIZING AGENT REACTIVE WITH THE IMPURITIES IN SAID CLAY, MAINTAINING SAID REACTION MIXTURE AT A TEMPERATURE SUFFICIENT TO INITIATE AND SUSTAIN THE REACTION BETWEEN SAID DECOLORIZING AGENT AND SAID IMPURITIES, DIRECTING VISIBLE LIGHT ONTO AT LEAST A PORTION OF SAID SLURRY, MEASURING THE MAGNITUDE OF THE REFLECTANCE OF SAID LIGHT BY SAID SLURRY, INCREASING THE MEASURED VALUE OF THE REFLECTANCE OF SAID LIGHT BY SAID SLURRY BY REACTING SAID DECOLORIZING AGENT WITH SAID CLAY IMPURITIES UNTIL THE MEASURED VALUE REACHES A VALUE REPRESENTATIVE OF SAID PREDETERMINED VALUE, AND RECOVERING FROM AQUEOUS REACTION MIXTURE DRY CLAY CHARACTERIZED BY A LIGHT REFLECTANCE OF SAID PREDETERMINED SELECTED VALUE.
Claim 3
Dependent Claim 207 words
A process for brightening clay to a point where the reflectance of light from said clay in dry form has a predetermined selected value, which comprises: agitating an aqueous slurry of said clay including a solids content of from about 5% to about 75% by weight, adding to said agitated slurry a predetermined amount of a decolorizing agent reactive with the impurities in said clay to form an aqueous reaction mixture, maintaining said reaction mixture at a temperature of from about 35*F. to about 210*F. sufficient to initiate and sustain the reaction between said decolorizing agent and said impurities, passing at least a portion of said aqueous reaction mixture into a light reflectance measuring zone, directing light characterized by a wave length of from 360 nm to 660 nm onto said aqueous reaction mixture in said zone, measuring the magnitude of the reflectance of said light by said aqueous reaction mixture, increasing the measured value of the reflectance of said light by said aqueous reaction mixture by reacting said decolorizing agent with said clay impurities until said measured value reaches a value representative of said predetermined selected value, and recovering from said aqueous reaction mixture dry clay characterized by a light reflectance of said predetermined selected value.
Claim 4
Dependent Claim 207 words
A process for brightening clay to a point where the reflectance of light from said clay in dry form has a predetermined selected value, which comprises: agitating an aqueous slurry of said clay including a solids content of from about 5% to about 75% by weight, adding to said agitated slurry a predetermined amount of a decolorizing agent reactive with the impurities in said clay to form an aqueous reaction mixture, maintaining said reaction mixture at a temperature of from about 35*F. to about 210*F. sufficient to initiate and sustain the reaction between said decolorizing agent and said impurities, passing at least a portion of said aqueous reaction mixture into a light reflectance measuring zone, directing light characterized by a wave length of from 360 nm to 660 nm onto said aqueous reaction mixture in said zone, measuring the magnitude of the reflectance of said light by said aqueous reaction mixture, increasing the measured value of the reflectance of said light by said aqueous reaction mixture by reacting said decolorizing agent with said clay impurities until said measured value reaches a value representative of said predetermined selected value, and recovering from said aqueous reaction mixture dry clay characterized by a light reflectance of said predetermined selected value.
Claim 5
Dependent Claim 24 words
The process of claim 1 including the additional step of adjusting the pH of said reaction mixture to optimize the efficiency of said reaction.
Claim 6
Dependent Claim 30 words
The process of claim 1 including the step of adding additional decolorizing agent to said slurry to increase the measured value of the reflectance of the light by said slurry.
Claim 7
Dependent Claim 13 words
The process of claim 1 wherein the decolorizing agent is an oxidizing bleach.
Claim 8
Dependent Claim 13 words
The process of claim 1 wherein the decolorizing agent is a reducing bleach.

References Cited (Backward Citations)

US2758010A Cited
US3423223A Cited
US3399960A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-30 1978-07-01 1978-12-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-30 1982-07-01 1982-12-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-30 1986-07-01 1986-12-31 $7700.00 Window Closed / Lapsed

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