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US3856757A Expired / Lapsed US ⏱️ 0.0 years remaining

Light-sensitive high polymer compound and process for the preparation thereof

Assignee: Fujifilm Holdings Corp
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Filing: 1973-08-30
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Granted: 1974-12-24
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Expires: 1993-08-30
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Abstract

Abstract A process for preparing a light-sensitive high molecular weight polymer compound, which comprises reacting an Beta -unsaturated carboxylic acid with an aliphatic or aromatic diepoxide to form the corresponding diol compound and reacting a diisocyanate compound with said diol compound and a process for preparing the light-sensitive high molecular weight polymer compounds, and to the novel polymer compounds produced.

Inventors

  • 👤 M Satomura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 21:52
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/6705; C08G18/675; C08G59/00; C08G59/14; C08G59/1433; C08G59/1438; C08G59/1455; C08G59/1461

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 39 words
A PROCESS FOR PREPARING A LIGHT-SENSITIVE HIGH MOLECULAR WEIGHT POLYMER COMPOUND, WHICH COMPRISES REACTING AN A,BUNSATURTED CARBOXYLIC ACID WITH AN ALIPHATIC OR AROMATIC DIEPOXIDE TO FORM THE CORRESPONDING DIOL COMPOUND AND REACTING A DIISOCYANATE COMPOUND WITH SAID DIOL COMPOUND.
Claim 2
Dependent Claim 39 words
A PROCESS FOR PREPARING A LIGHT-SENSITIVE HIGH MOLECULAR WEIGHT POLYMER COMPOUND, WHICH COMPRISES REACTING AN A,BUNSATURTED CARBOXYLIC ACID WITH AN ALIPHATIC OR AROMATIC DIEPOXIDE TO FORM THE CORRESPONDING DIOL COMPOUND AND REACTING A DIISOCYANATE COMPOUND WITH SAID DIOL COMPOUND.
Claim 3
Dependent Claim 104 words
The process of claim 1, wherein said process comprises reacting an Alpha , Beta -unsaturated crboxylic acid selected from the group consisting of cinnamic acid, Alpha -cyanocinnamic acid, furylacrylic acid, thienylacrylic acid, cinnamylidenacrylic acid, furylpentadienoic acid, acrylic acid, crotonic acid, sorbic acid, methacrylic acid, methoxycinnamic acid, nitrocinnamic acid and vinylcinnamic acid with a diepoxide to produce a diol compound and subsequently reacting said diol compound with a diisocyanate selected from the group consisting of hexamethylenediisocyanate, tolylenediisocyanate, naphthylene diisocyanate, diphenylmethanediisocyanate, dimethyl diphenyl methanediisocyanate, 2,4-tolylenediisocyanate dimer, propylenediisocyanate, butylenediisocyanate, 1,4-butyleneglycoldipropylether- omega , omega ''-diisocyanate, dipropylether- omega , omega ''-diisocyanate, 1,2-dimethylcyclohexane- omega , omega ''-diisocyanate and benzophenone diisocyanate.
Claim 4
Dependent Claim 68 words
The process of claim 2, wherein said diepoxide is selected from the group consisting of ethyleneglycol diglycidyl ether, diethyleneglycol diglycidyl ether, propyleneglycol diglycidyl ether, polyethyleneglycol diglycidyl ether, butanediol diglycidyl ether, hexanediol diglycidyl ether, cyclohexane diol diglycidyl ether, bisphenol A diglycidyl ether, p,p''-dihydroxydiphenylether diglycidyl ether, p,p''-dihydroxydiphenylether diglycidyl ether, dihydroxybenzene diglycidyl ether, diglycidylaniline, ethyl diglycidyl phosphate, 1-vinyl-3-cyclohexene diepoxide, dicyclopentadiene diepoxide, 1,5-hexadiene diepoxide, bis(3,4-epoxycyclohexylmethyl oxalate), bis(3,4-epoxycyclohexylmethylpimelate) and 3,4-epoxy-5-methyl cyclohexylmethyl-3'',4''-epoxy-5''-methyl cyclohexane carboxylate.
Claim 5
Dependent Claim 39 words
The process of claim 2, wherein said diol is further reacted with a monoepoxide selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide, epichlorohydrin prior to said reaction with diisocyanate to produce a second diol compound.
Claim 6
Dependent Claim 11 words
The process of claim 4, wherein said monoepoxide is ethylene oxide.
Claim 7
Dependent Claim 18 words
A polymer produced by the process of claim 1, wherein said polymer contains units having the following formula
Claim 8
Dependent Claim 25 words
A polymer produced by the process of claim 4, in which said monoexpoxide is ethylene oxide, wherein said polymer contains units of the following formula
Claim 9
Dependent Claim 8 words
A polymer containing units having the following formula
Claim 10
Dependent Claim 8 words
A polymer containing units having the following formula
Claim 11
Dependent Claim 8 words
A polymer containing units having the following formula
Claim 12
Dependent Claim 8 words
A polymer containing units having the following formula
Claim 13
Dependent Claim 28 words
A process for preparing a light-sensitive high molecular weight polymer compound which comprises reacting an Alpha , Beta -unsaturated carboxylic acid Z-COOH with an aliphatic or aromatic diepoxide
Claim 14
Dependent Claim 28 words
A process for preparing a light-sensitive high molecular weight polymer compound which comprises reacting an Alpha , Beta -unsaturated carboxylic acid Z-COOH with an aliphatic or aromatic diepoxide

References Cited (Backward Citations)

US3697312A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-23 1978-06-24 1978-12-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-23 1982-06-24 1982-12-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-23 1986-06-24 1986-12-24 $7700.00 Window Closed / Lapsed

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