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US3854970A Expired / Lapsed US ⏱️ 0.0 years remaining

Cationic starch and condensates for making the same

Assignee: ChampionX LLC
•
Filing: 1973-08-13
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Granted: 1974-12-17
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Expires: 1993-08-13
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Abstract

Abstract A cationic additive for starch which comprises a preferred condensate of epichlorohydrin with an equimolar quantity with dimethylamine, and in which a minor amount of up to 30% molar ammonia may be substituted for a like molar amount of dimethylamine. This condensate is preferably intimately admixed and utilized in an amount of 1-7% (preferred 5-7%) with alkaline gelatinized or alkali hydrolyzed starch to give a liquid cationic treating agent for paper. The percentage of condensate additive is calculated using as a base granular or dry starch and the condensate is preferably added to the liquid gelatinous starch after the gelatinization or in situ during the gelatinization. The starch, during the addition of the condensate, is maintained alkaline by a preferred alkali metal hydroxide of about 5% strength. This cationic starch may be used as a wet end pulp additive in the range 3-50 lbs/ton and has shown to favorably affect burst strength and pigment retention values.

Inventors

  • 👤 T Aitken

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 16:38
CPC Classifications
D; D21; D21H; D21H17/00; D21H17/20; D21H17/21; D21H17/24; D21H17/28; D21H17/29; C; C08; C08B; C08B31/00; C08B31/08; C08B31/12; C08B31/125; C08G; C08G65/00; C08G65/02; C08G65/26; C08G65/2618; C08G65/2621; C08G65/2624

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 54 words
A METHOD OF MAKING A CATIONIC STARCH SUITABLE FOR WET END PAPERMAKING WHICH COMPRISES PRODUCING GELATINOUS STARCH FROM GRANULAR STARCH, TREATING SAID STARCH WITH ALKALINE AGENT, AND ADDING TO SAID STARCH 1-7% OF A CONDENSATE OF GENERALLY EQUIMOLAR QUANTITIES OF EPUCHLOROHYDRIN AND DIMETHYYLAMINE WHEREIN THE PERCENTAGE OF SAID CONDENSATE IS CALCULATED FROM GRANULAR STARCH.
Claim 2
Independent Claim 54 words
A METHOD OF MAKING A CATIONIC STARCH SUITABLE FOR WET END PAPERMAKING WHICH COMPRISES PRODUCING GELATINOUS STARCH FROM GRANULAR STARCH, TREATING SAID STARCH WITH ALKALINE AGENT, AND ADDING TO SAID STARCH 1-7% OF A CONDENSATE OF GENERALLY EQUIMOLAR QUANTITIES OF EPUCHLOROHYDRIN AND DIMETHYYLAMINE WHEREIN THE PERCENTAGE OF SAID CONDENSATE IS CALCULATED FROM GRANULAR STARCH.
Claim 3
Dependent Claim 18 words
The method according to claim 1, wherein 5-7% of the condensate is added based on the granular starch.
Claim 4
Dependent Claim 17 words
The method according to claim 1, wherein the condensate is added during the gelatinization of the starch.
Claim 5
Dependent Claim 17 words
The method according to claim 1, wherein the condensate is added after the gelatinization of the starch.
Claim 6
Dependent Claim 16 words
The method according to claim 1, wherein up to 30% molar ammonia is substituted for dimethylamine.
Claim 7
Dependent Claim 49 words
A wet-end liquid sizing additive useful in papermaking in amounts of about 3-50 lbs./ton and consisting of gelatinized starch intimately admixed with about 1-7% of a condensation product of generally equimolar amounts of epichlorohydrin and dimethylamine, and wherein said percentage is calculated on the basis of dry granular starch.
Claim 8
Dependent Claim 49 words
A wet-end liquid sizing additive useful in papermaking in amounts of about 3-50 lbs./ton and consisting of gelatinized starch intimately admixed with about 1-7% of a condensation product of generally equimolar amounts of epichlorohydrin and dimethylamine, and wherein said percentage is calculated on the basis of dry granular starch.
Claim 9
Dependent Claim 21 words
The additive according to claim 6, wherein up to 30% molar ammonia is substituted for a like molar amount of dimethylamine.
Claim 10
Dependent Claim 15 words
The additive according to claim 6, wherein about 5-7% of the condensation product is utilized.

References Cited (Backward Citations)

US2876217A Cited
US3066032A Cited
US3320080A Cited
US3422087A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-16 1978-06-17 1978-12-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-16 1982-06-17 1982-12-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-16 1986-06-17 1986-12-17 $7700.00 Window Closed / Lapsed

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