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US3854873A Expired / Lapsed US ⏱️ 0.0 years remaining

Use of sodium bisulfite in an improved process for the treatment of cellulose textile materials with carbamate finishing agents and sulfurous acid

Assignee: United States Department of Agriculture
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Filing: 1972-12-13
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Granted: 1974-12-17
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Expires: 1992-12-13
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Abstract

Abstract An improved relationship of the strength to wrinkle recovery properties of cellulose-containing fabrics finished with methylol carbamate agents and sulfurous acid is obtained by inclusion of about 0.3-1 percent of sodium bisulfite in the treatment bath.

Inventors

  • 👤 R Kullman
  • 👤 N Cashen
  • 👤 J Reid
  • 👤 R Reinhardt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 04:18
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/39; D06M15/423; Y; Y10; Y10S; Y10S8/00; Y10S8/11; Y10T; Y10T442/00; Y10T442/20; Y10T442/2369; Y10T442/2393

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 54 words
AN IMPROVED PROCESS IN THE TREATMENT OF CELLULOSECONTAINING FABRICS WITH A METHYLOLATED CARBAMATE-SULFUROUS ACID FORMULATION WHICH PROCESS COMPRISES ADDING A MINOR AMOUNT OF SODIUM BISULFITE TO SAID FORMULATION, IMPREGNATING THE CELLULOSE-CONTAINING TEXTILE WITH SAID FORMULATION AND CURING THE IMPREGNATED FABRIC TO IMPART DURABLE PRESS PROPERTIES WITH IMPROVED STRENGTH-TO-WRINKLE RECOVERY RELATIONSHIP TO THE TREATED FABRIC.
Claim 2
Dependent Claim 54 words
AN IMPROVED PROCESS IN THE TREATMENT OF CELLULOSECONTAINING FABRICS WITH A METHYLOLATED CARBAMATE-SULFUROUS ACID FORMULATION WHICH PROCESS COMPRISES ADDING A MINOR AMOUNT OF SODIUM BISULFITE TO SAID FORMULATION, IMPREGNATING THE CELLULOSE-CONTAINING TEXTILE WITH SAID FORMULATION AND CURING THE IMPREGNATED FABRIC TO IMPART DURABLE PRESS PROPERTIES WITH IMPROVED STRENGTH-TO-WRINKLE RECOVERY RELATIONSHIP TO THE TREATED FABRIC.
Claim 3
Dependent Claim 29 words
The process of claim 1 wherein every 100 parts by weight of the methylolated carbamate-sulfurous acid formulation contains about from 0.3 to 1.0 part by weight of sodium bisulfite.
Claim 4
Dependent Claim 19 words
The process of claim 1 wherein the methylolated carbamate of the methylolated carbamate-sulfurous acid formulation is dimethylol methyl carbamate.
Claim 5
Dependent Claim 117 words
A process for treating cellulose-containing textiles to impart durable press properties with an improved strength-to-wrinkle recovery relationship, the process comprising: a. adding a sufficient quantity of sodium bisulfite to a methylolated carbamate-sulfurous acid formulation so that in every 100 parts by weight of the formulation there is about from 10 to 15 parts by weight of a methylolated carbamate, about from 0.1 to 0.2 part by weight of sulfurous acid, and about from 0.3 to 1 part by weight of sodium bisulfite; b. impregnating a cellulose-containing textile with a formulation from (a); and c. curing the wet impregnated textile for about from 2 to 4 minutes at about 100* C. and washing and drying the cured textile.
Claim 6
Dependent Claim 117 words
A process for treating cellulose-containing textiles to impart durable press properties with an improved strength-to-wrinkle recovery relationship, the process comprising: a. adding a sufficient quantity of sodium bisulfite to a methylolated carbamate-sulfurous acid formulation so that in every 100 parts by weight of the formulation there is about from 10 to 15 parts by weight of a methylolated carbamate, about from 0.1 to 0.2 part by weight of sulfurous acid, and about from 0.3 to 1 part by weight of sodium bisulfite; b. impregnating a cellulose-containing textile with a formulation from (a); and c. curing the wet impregnated textile for about from 2 to 4 minutes at about 100* C. and washing and drying the cured textile.
Claim 7
Dependent Claim 133 words
A process for treating cellulose-containing textiles to impart durable press properties with an improved strength-to-wrinkle recovery relationship, the process comprising: a. adding a sufficient quantity of sodium bisulfite to a methylolated carbamate-sulfurous acid formulation so that in every 100 parts by weight of the formulation there is about from 10 to 15 parts by weight of a methylolated carbamate, about from 0.1 to 0.2 parts by weight of sulfurous acid, and about from 0.3 to 1 part by weight of sodium bisulfite; b. impregnating a cellulose-containing textile with a formulation from step (a); c. drying the wet impregnated textile for about seven minutes at about from 60* C. and d. curing the dry impregnated textile for about 3 minutes at about from 80* to 160* C. and washing and drying the cured textile.
Claim 8
Dependent Claim 133 words
A process for treating cellulose-containing textiles to impart durable press properties with an improved strength-to-wrinkle recovery relationship, the process comprising: a. adding a sufficient quantity of sodium bisulfite to a methylolated carbamate-sulfurous acid formulation so that in every 100 parts by weight of the formulation there is about from 10 to 15 parts by weight of a methylolated carbamate, about from 0.1 to 0.2 parts by weight of sulfurous acid, and about from 0.3 to 1 part by weight of sodium bisulfite; b. impregnating a cellulose-containing textile with a formulation from step (a); c. drying the wet impregnated textile for about seven minutes at about from 60* C. and d. curing the dry impregnated textile for about 3 minutes at about from 80* to 160* C. and washing and drying the cured textile.
Claim 9
Dependent Claim 41 words
A cellulosic fabric prepared by the process of claim 5, characterized by an improved strength-to-wrinkle recovery relationship with respect tO a control fabric treated with an identical formulation to that used in claim 5 except for the omission of sodium bisulfite.

References Cited (Backward Citations)

US3776692A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-16 1978-06-17 1978-12-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-16 1982-06-17 1982-12-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-16 1986-06-17 1986-12-17 $7700.00 Window Closed / Lapsed

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