← Back to Patent Explorer
US3854485A Expired / Lapsed US ⏱️ 0.0 years remaining

Tobacco compositions comprising mono-esters of mono- and dialkylmalonates

Assignee: Liggett Group LLC
•
Filing: 1973-09-24
•
Granted: 1974-12-17
•
Expires: 1993-09-24
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract An article of manufacture comprising tobacco and a small but effective amount of one or a mixture of monoesters of monoand/or di-alkylmalonates as a flavorant composition. The indicated malonates decompose during smoking of the tobacco by decarboxylation to give the corresponding alkanoate esters which improve the taste and aroma of tobacco smoke. For example, monoethyl sec-butylmalonate in a cigarette at a level of about one ppm on the tobacco will produce a smoke flavor characterized by a fermented apple-peel with an English walnut-like taste. The flavor and taste apparently arise from the conversion of the monoethyl sec-butylmalonate to ethyl Beta -methylvalerate.

Inventors

  • 👤 J Mold
  • 👤 M Simpson
  • 👤 A Kallianos
  • 👤 R Means

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 00:16
CPC Classifications
A; A24; A24B; A24B15/00; A24B15/18; A24B15/28; A24B15/30; A24B15/32

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 23 words
TOBACCO SMOKING COMPOSITIONS COMPRISING TOBACCO AND A SMALL BUT EFFECTIVE AMOUNT OF AT LEAST ONE MONOESTER OF MONO- AND DI-ALKYLMALONATES HAVING THE FORMULA:
Claim 2
Dependent Claim 23 words
TOBACCO SMOKING COMPOSITIONS COMPRISING TOBACCO AND A SMALL BUT EFFECTIVE AMOUNT OF AT LEAST ONE MONOESTER OF MONO- AND DI-ALKYLMALONATES HAVING THE FORMULA:
Claim 3
Dependent Claim 11 words
The composition of claim 1 wherein said malonate is monoethyl sec-butylmalonate.
Claim 4
Dependent Claim 11 words
The composition of claim 1 wherein said malonate is monomethyl sec-butylmalonate.
Claim 5
Dependent Claim 11 words
The composition of claim 1 wherein said malonate is monoethyl methyl-n-propylmalonate.
Claim 6
Dependent Claim 11 words
The composition of claim 1 wherein said malonate is monooctyl sec-butylmalonate.
Claim 7
Dependent Claim 12 words
The composition of claim 1 wherein said malonate is calcium monoethyl sec-butylmalonate.
Claim 8
Dependent Claim 25 words
The composition of claim 1 wherein said malonate comprises from about 0.00001 to about 0.1 percent by weight based on the weight of said tobacco.
Claim 9
Dependent Claim 38 words
A process for the preparation of a tobacco smoking composition which comprises applying to tobacco a small but effective amount of a relatively non-volatile, non-odorous and stable flavoring agent of mono-esters of mono- and di-alkylmalonates having the formula:
Claim 10
Dependent Claim 38 words
A process for the preparation of a tobacco smoking composition which comprises applying to tobacco a small but effective amount of a relatively non-volatile, non-odorous and stable flavoring agent of mono-esters of mono- and di-alkylmalonates having the formula:
Claim 11
Dependent Claim 32 words
A process according to claim 8 wherein said malonate is applied to said tobacco in a range from about 0.00001 to about 0.1 percent weight based on the weight of said tobacco.

References Cited (Backward Citations)

US2766145A Cited
US3095882A Cited
US3782391A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-16 1978-06-17 1978-12-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-16 1982-06-17 1982-12-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-16 1986-06-17 1986-12-17 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag