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US3852490A Expired / Lapsed US ⏱️ 0.0 years remaining

Organic pesticide residue removal from aqueous solutions

Assignee: Chevron USA Inc
•
Filing: 1973-03-06
•
Granted: 1974-12-03
•
Expires: 1993-03-06
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Abstract

Abstract Organic pesticide residues are removed from aqueous solutions by treating the aqueous solution, e.g., wine, with a lower alkenevinyl lower alkanoate polymer, e.g., ethylenevinyl acetate.

Inventors

  • 👤 G Kohn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 19:14
CPC Classifications
A; A23; A23L; A23L2/00; A23L2/70; B; B01; B01D; B01D15/00; B01J; B01J20/00; B01J20/22; B01J20/26; B01J20/264; C; C02; C02F; C02F1/00; C02F1/28; C02F1/285; C12; C12H; C12H1/00; C12H1/02; C12H1/04; C12H1/0416; C12H1/0424

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 110 words
A PROCESS FOR REMOVING ORGANIC PESTICIDES SELECTED FROM CHLORINAED HYDROCARBONS, HALOALKYL SULFENYLATED CARBOXIMIDE, HALOALKYL SULFENYLATED PHTHALIMIDES, BENZIMIDAZOLE CARBAMATES, THIOUREIDOBENZENES, OXAZOLIDINEDIONES, HYDROCARBYL ARYL METHYLCARBAMATES OR PHOSPHATE ESTERS FROM AQUEOUS SOLUTIONS CONTAINING ABOUT 0.01 PPM TO 1,000 PPM OF SAID PESTICIDES WHICH COMPRISES CONTACTING SAID AQUEOUS SOLUTION WITH FROM 1 TO 200 PERCENT BY WEIGHT, BASED ON WEIGHT OF AQUEOUS SOLUTION, OF A C2-C4 ALKENE-VINYL C2-C4 ALKANOTE POLYMER HAVING A MELT INDEX OF ABOUT 2 TO 500 G/10 MIN., AN INHERENT VISOCITY OF ABOUT 0.5 TO 1.1, A DENSITY OF ABOUT 0.93 TO 0.96 G/CC, AND FROM ABOUT 15 TO 45 PERCENT BY WEIGHT BASED ON WEIGHT OF POLYMER, OF VINYL ALKANOATE.
Claim 2
Dependent Claim 110 words
A PROCESS FOR REMOVING ORGANIC PESTICIDES SELECTED FROM CHLORINAED HYDROCARBONS, HALOALKYL SULFENYLATED CARBOXIMIDE, HALOALKYL SULFENYLATED PHTHALIMIDES, BENZIMIDAZOLE CARBAMATES, THIOUREIDOBENZENES, OXAZOLIDINEDIONES, HYDROCARBYL ARYL METHYLCARBAMATES OR PHOSPHATE ESTERS FROM AQUEOUS SOLUTIONS CONTAINING ABOUT 0.01 PPM TO 1,000 PPM OF SAID PESTICIDES WHICH COMPRISES CONTACTING SAID AQUEOUS SOLUTION WITH FROM 1 TO 200 PERCENT BY WEIGHT, BASED ON WEIGHT OF AQUEOUS SOLUTION, OF A C2-C4 ALKENE-VINYL C2-C4 ALKANOTE POLYMER HAVING A MELT INDEX OF ABOUT 2 TO 500 G/10 MIN., AN INHERENT VISOCITY OF ABOUT 0.5 TO 1.1, A DENSITY OF ABOUT 0.93 TO 0.96 G/CC, AND FROM ABOUT 15 TO 45 PERCENT BY WEIGHT BASED ON WEIGHT OF POLYMER, OF VINYL ALKANOATE.
Claim 3
Dependent Claim 11 words
The process of claim 1 wherein the polymer is ethylene-vinyl acetate.
Claim 4
Dependent Claim 23 words
The process of claim 1 wherein organic pesticides are dissolved in the aqueous solution in amounts of about 0.01 ppm to 50 ppm.
Claim 5
Dependent Claim 62 words
The process of claim 2 wherein organic pesticides are dissolved in the aqueous solution in amounts of about 0.01 ppm to 50 ppm and are selected from the group consisting of octachloro-4,7-methanotetrahydroindane, 1, 1,1-trichloro-2,2-bis-(p-chlorophenyl)ethane, cis-N-(trichloromethylthio)-4-cyclohexene-1, 2-dicarboximide, N-(1,1,2,2-tetrachloroethylthio)-4-cyclohexene-1,2-dicarboximide, N-(trichloromethylthio)phthalimide, methyl-1-(butylcarbamoyl)-2-benzimidazole carbamate, methyl-2-benzimidazole carbamate, 1,2-bis-(3-ethoxycarbonyl-2-thioureido)-benzene, 1,2-bis-(3-methoxycarbonyl-2-thioureido)-benzene, 3-(3, 5-dichlorophenyl)-5,5-dimethyloxazolidinedione-2,4, 1-naphthyl methylcarbamate, m-(1-methylbutylphenyl methylcarbamate, m-(1-ethylpropyl)-phenyl methyl carbamate, 0,0-dimethyl phosphorodithioate of diethyl mercaptosuccinaTe and 0,0-dimethyl 0-p-nitrophenyl phosphorothioate.
Claim 6
Dependent Claim 15 words
The process of claim 4 wherein the aqueous alcoholic solution is a fermented fruit juice.
Claim 7
Dependent Claim 12 words
The process of claim 4 wherein the aqueous alcoholic solution is wine.
Claim 8
Dependent Claim 13 words
The process of claim 1 wherein the aqueous solution is a fruit juice.
Claim 9
Dependent Claim 12 words
The process of claim 7 wherein the fruit juice is grape juice.
Claim 10
Dependent Claim 12 words
The process of claim 2 wherein the organic pesticide residue is 1,1,1-trichloro-2,2-bis-(p-chlorophenyl)ethane.
Claim 11
Dependent Claim 12 words
The process of claim 2 wherein the organic pesticide residue is cis-N-(trichloromethylthio)-4-cyclohexene-1,2-dicarboximide.
Claim 12
Dependent Claim 12 words
The process of claim 2 wherein the organic pesticide residue is 3-(3,5-dichlorophenyl)-5,5-dimethyloxazolidinedione-2,4.
Claim 13
Dependent Claim 12 words
The process of claim 2 wherein the organic pesticide residue is N-(1,1,2,2-tetrachloroethylthio)-4-cyclohexene-1,2-dicarboximide.
Claim 14
Dependent Claim 27 words
The process of claim 2 wherein the polymer contains a minor amount of vinyl acetic and has an acid number in the range of 4 to 8.

References Cited (Backward Citations)

US3347811A Cited
US3400093A Cited
US3554759A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-02 1978-06-03 1978-12-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-02 1982-06-03 1982-12-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-02 1986-06-03 1986-12-03 $7700.00 Window Closed / Lapsed

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