Photo-degradable polyolefin resin composition

Abstract

Abstract 1. A PHOTO-DEGRADABLE POLYOLEFIN COMPRUSING (A) A POLYOLEFIN AND (B) 0.2 TO 10 PARTS BY WEIGHT PER 100 PARTS BY WEIGHT OF SAID POLYOLEFIN OF A PHOTO-DEGRADING AGENT CONSISTING OF (A) 5 TO 70% BY WEIGHT, BASE ON THE THE PHOTO-DEGRADING AGENT OF, AT LEAST ONE CARBONYL COMPOUND EXPRESSED BY THE FOLLOWING FORMULA R1,R2,R3-PHENYL-CO-R WHEREIN R IS A MEMBER SELECTED FROM THE GROUP CONSISTING OF LOWER ALKYL GROUPS WHICH MAY BE SUBSTITUTED BY HALOGEN, LOWER ALKOXY OR NITRO AND WHICH MAY BE BONDED TO THE CARBON ATOM AT THE ORTHO-POSITION OF THE BENZENE NUCLEUS OF FORMULA (I) DIRECTLY OR VIA-CO- TO FORM A FUSED RING, AND GROUPS EXPRESSED BY THE FOLLOWING FORMULA R4,R5,R6-PHENYL- WITH THE PROVISO THAT THE CARBON ATOMS ADJACENT TO THE CARBON ATOM BONDED TO -CO- IN FORMU (I) MAY BE BONDED TO THE CARBON ATOM AT THE ORTHO-POSITION OF THE BENZENE NUCELUS OF FORMULA (I) DIRECTLY OR VIA -CO-, AND R1, R2, R3, R4, R5 AND R6, WHICH MAY BE THE SAME OR DIFFERENT, REPRESENT A MEMBER SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, HALOGEN HYDROXYL, LOWER ALKYL, LOWER ALKOXY AND NITRO, WITH THE PROVISO THAT WHEN AT LEAST ONE OF R1, R2, R3, R4, R5 AND R6 IS A HYDROXYL GROUP, SAID HYDROXYL GROUP IS NOT BONDED TO THE CARBON ATOM OF THE BENZENE NUCLEUS ADJACENT TO THE CARBON ATOMS OF THE BENZENE NUCLEUS BONDED TO THE -CO- GROUP IN FORMULA (I); AND (B) 30 TO 95 PERCENT BY WEIGHT, BASED ON THE PHOTODEGRADING AGENT, OF AT LEAST ONE COMPOUND SELECTED FROM THE GROUP CONSISTING OF ALIPHATIC CARBOXYLIC ACIDS HAVING 6 TO 20 CARBON ATOMS, AND ZINC, MAGNESIUM ALUMINUM, CALCIUM AND BARIUM SALTS OF SAID ALIPHATIC CARBOXYLIC ACIDS.

Inventors

• 👤 H Matsuda
• 👤 H Mori
• 👤 H Matoba

Bibliographic Details