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US3852222A Expired / Lapsed US ⏱️ 0.0 years remaining

Fluorinated epoxy resins

Assignee: United States Department of the Navy
•
Filing: 1973-06-25
•
Granted: 1974-12-03
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Expires: 1993-06-25
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Abstract

Abstract Highly fluorinated polymers are synthesized and crosslinked to form fluorinated network polymers.

Inventors

  • 👤 D Field
  • 👤 J Griffith

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 04:48
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/48; C08G18/50; C08G18/5003; C08G18/5015; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/30

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 10 words
A RANDOM EPOXY-TERMINATED COPOLYMER COMPRISING RECURRING UNITS OF THE FORMULA:
Claim 2
Dependent Claim 10 words
A RANDOM EPOXY-TERMINATED COPOLYMER COMPRISING RECURRING UNITS OF THE FORMULA:
Claim 3
Dependent Claim 11 words
A crosslinked random epoxy-terminated copolymer comprising recurring units of the formula:
Claim 4
Dependent Claim 11 words
A crosslinked random epoxy-terminated copolymer comprising recurring units of the formula:
Claim 5
Dependent Claim 28 words
A copolymer according to claim 2, wherein R1 is a urethane derived from an isocyanate selected from the group consisting of hexamethylene diisocyanate, toluene diisocyanate, and derivatives thereof.
Claim 6
Dependent Claim 6 words
A random copolymer comprising the formula:
Claim 7
Dependent Claim 6 words
A random copolymer comprising the formula:
Claim 8
Dependent Claim 9 words
A crosslinked copolymer comprising recurring units of the formula:
Claim 9
Dependent Claim 9 words
A crosslinked copolymer comprising recurring units of the formula:
Claim 10
Dependent Claim 10 words
The polymer of claim 5 wherein R is diethylene triamine.
Claim 11
Dependent Claim 42 words
A reaction process for the production of a highly fluorinated copolymer comprising: reacting fluorinated diols selected from the group consisting of 1,3-Bis(2-Hydroxyhexafluoro-2-propyl)benzene, 2,2,3,3,4,4-Hexafluoro-1,5-Pentanediol, 1,4-Bis(2-Hydroxyhexafluoro-2-propyl)benzene, and mixtures thereof with epichlorohydrin and NaOH in the presence of acetone, and heating the reactants to reflux.
Claim 12
Dependent Claim 42 words
A reaction process for the production of a highly fluorinated copolymer comprising: reacting fluorinated diols selected from the group consisting of 1,3-Bis(2-Hydroxyhexafluoro-2-propyl)benzene, 2,2,3,3,4,4-Hexafluoro-1,5-Pentanediol, 1,4-Bis(2-Hydroxyhexafluoro-2-propyl)benzene, and mixtures thereof with epichlorohydrin and NaOH in the presence of acetone, and heating the reactants to reflux.
Claim 13
Dependent Claim 33 words
A reaction process according to claim 7 wherein the molar amount of epichlorohydrin is equivalent to the molar amount of fluorinated diol and the NaOH is present in excess of said molar amount.
Claim 14
Dependent Claim 23 words
A reaction process according to claim 7 wherein the molar amount of epichlorohydrin is in excess of the molar amount of fluorinated diol.
Claim 15
Dependent Claim 12 words
The copolymer according to claim 4, wherein i is greater than 10.

References Cited (Backward Citations)

US3475384A Cited
US3489813A Cited
US3591547A Cited
US3707483A Cited
US3706772A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-02 1978-06-03 1978-12-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-02 1982-06-03 1982-12-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-02 1986-06-03 1986-12-03 $7700.00 Window Closed / Lapsed

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