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US3852134A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for forming selectively perforate bodies

Assignee: General Electric Co
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Filing: 1972-11-20
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Granted: 1974-12-03
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Expires: 1992-11-20
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Abstract

Abstract This invention relates to a method of forming a selectively perforate membrane suitable for high resolution screen printing by homogeneously irradiating a sheet of synthetic resin, e.g., a polycarbonate resin, with heavy fission fragments whereupon the sheet is selectively irradiated in an oxygen atmosphere with electromagnetic radiation less than 4,000A (or a high intensity electron beam) to enhance the etch rate of those damage tracks lying within the electromagnetically irradiated area of the sheet. Apertures less than 200A in diameter then are etched through the sheet in areas of dual irradiation whereupon etching is abruptly terminated and the sheet is annealed at a temperature above 80*C to obliterate fission track damage. The selectively apertured sheet then is etched again to enlarge the apertures to a diameter between 1,000A and 100,000A.

Inventors

  • 👤 C Bean

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 08:35
CPC Classifications
G; G03; G03F; G03F1/00; G03F1/20; B; B26; B26F; B26F1/00; B26F1/26; B26F1/31; B29; B29C; B29C71/00; B29C71/04

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 141 words
A METHOD OF PREFORATING A SOLID BODY IN A PREDETERMINED PATTERN COMPRISNG SUBJECTING SAID BODY TO A HOMOGENEOUS BOMBARDMENT OF CHARGE PARTICLES HAVING AN ENERGY LEVEL FORMING DAMAGE TRACKS EXTENDING THROUGH SAID BODY, EXPOSING A SELECTIVE PORTION OF SAID HOMOGENEOUSLY BOMBARDED BODY IN AN OXYGEN CONTAINING AMBIENT TO RADIANT ENERGY FOR A PERIOD REQUIRED TO ALTER THE SOLUBILITY RATE OF SAID EXPOSED DAMAGE TRACKDS, ETCHING SAID BODY FOR A PERIOD SUFFICIENT TO ETCH THROUGH THOSE DAMAGE TRACKS LYING WITHIN THE SELECTIVELY EXPOSED PORTION OF SAID BODY, SAID ETCH PERIOD BEING INSUFFICIENT TO ETCH THROUGH DAMAGE TRACKS LYING OUTSIDE SAID EXPOSED PORTION OF SAID BODY, ANNEALING THE SELECTIVELY PERFORATE BODY FOR A PERIOD REQUIRED TO OBLITERATE THE ALTERED SOLUBILITY OF SAID DAMAGE TRACKS AND ETCHING SAID BODY TO ELARGE THE PERFORATIONS FORMED THROUGH SAID BODY DURING SAID INITIAL ETCH OF SAID BODY.
Claim 2
Independent Claim 141 words
A METHOD OF PREFORATING A SOLID BODY IN A PREDETERMINED PATTERN COMPRISNG SUBJECTING SAID BODY TO A HOMOGENEOUS BOMBARDMENT OF CHARGE PARTICLES HAVING AN ENERGY LEVEL FORMING DAMAGE TRACKS EXTENDING THROUGH SAID BODY, EXPOSING A SELECTIVE PORTION OF SAID HOMOGENEOUSLY BOMBARDED BODY IN AN OXYGEN CONTAINING AMBIENT TO RADIANT ENERGY FOR A PERIOD REQUIRED TO ALTER THE SOLUBILITY RATE OF SAID EXPOSED DAMAGE TRACKDS, ETCHING SAID BODY FOR A PERIOD SUFFICIENT TO ETCH THROUGH THOSE DAMAGE TRACKS LYING WITHIN THE SELECTIVELY EXPOSED PORTION OF SAID BODY, SAID ETCH PERIOD BEING INSUFFICIENT TO ETCH THROUGH DAMAGE TRACKS LYING OUTSIDE SAID EXPOSED PORTION OF SAID BODY, ANNEALING THE SELECTIVELY PERFORATE BODY FOR A PERIOD REQUIRED TO OBLITERATE THE ALTERED SOLUBILITY OF SAID DAMAGE TRACKS AND ETCHING SAID BODY TO ELARGE THE PERFORATIONS FORMED THROUGH SAID BODY DURING SAID INITIAL ETCH OF SAID BODY.
Claim 3
Independent Claim 230 words
A method of perforating the body of a material selected from the group consisting of polymeric resins and celluostic materials in a predetermined pattern comprising subjecting said body to a homogeneous bombardment of alpha particles to form damage tracks which are more susceptible to etching by an etchant for said material than adjacent undamaged material, covering a portion of the surface of the body with a metallic shield to mask an area of the predetermined pattern against ultraviolet radiation, exposing the masked homogeneously bombarded body in air to ultraviolet radiation for a period equivalent to at least 15 minutes exposure with a 100-watt black light lamp disposed at a distance of 1 cm. from said material, etching said body in an etchant for said material for a period of time sufficient to etch through those damage tracks lying within that portion of the body uncovered by said shield, said etch period being insufficient to etch through damage tracks lying within that portion of the body covered by said shield, annealing the shielded portion of said perforate body for a sufficient period of time and at a temperature to effectively remove said damage tracks and to obliterate the altered solubility of the regions of said damage tracks, and further etching said body in an etchant therefor to enlarge the perforations formed through said body during said initial etch of said body.
Claim 4
Independent Claim 230 words
A method of perforating the body of a material selected from the group consisting of polymeric resins and celluostic materials in a predetermined pattern comprising subjecting said body to a homogeneous bombardment of alpha particles to form damage tracks which are more susceptible to etching by an etchant for said material than adjacent undamaged material, covering a portion of the surface of the body with a metallic shield to mask an area of the predetermined pattern against ultraviolet radiation, exposing the masked homogeneously bombarded body in air to ultraviolet radiation for a period equivalent to at least 15 minutes exposure with a 100-watt black light lamp disposed at a distance of 1 cm. from said material, etching said body in an etchant for said material for a period of time sufficient to etch through those damage tracks lying within that portion of the body uncovered by said shield, said etch period being insufficient to etch through damage tracks lying within that portion of the body covered by said shield, annealing the shielded portion of said perforate body for a sufficient period of time and at a temperature to effectively remove said damage tracks and to obliterate the altered solubility of the regions of said damage tracks, and further etching said body in an etchant therefor to enlarge the perforations formed through said body during said initial etch of said body.
Claim 5
Independent Claim 221 words
A method of perforating a solid body of a material selected from the group consisting of synthetic resins annd cellulostic materials in a predetermined pattern comprising subjecting said body to a homogeneous bombardment of charged nuclear fragment particles having an energy level forming damage tracks which are more susceptible to etching by an etchant for said material than said undamaged material extending through said body, exposing a selective portion of said homogeneously bombarded body in an oxygen containing ambient to radiant energy selected from the group consisting of electromagnetic radiation having a wavelength shorter than 4,000 A.U. and high energy electrons for a period required to increase the solubility rate of said selectively exposed damage tracks, etching said body in an etchant for said material for a period sufficient to etch through those damage tracks lying within the selectively exposed portion of said body, said etch period being insufficient to etch through damage tracks lying outside said selectively exposed portion of said body, annealing the selectively perforate body for a sufficient period of time and at a temperature to effectively remove said damage tracks and to obliterate the alterEd solubility of the regions of said damage tracks and further etching said body in an etchant therefor to enlarge the perforations formed through said body during said initial etch of said body.
Claim 6
Independent Claim 221 words
A method of perforating a solid body of a material selected from the group consisting of synthetic resins annd cellulostic materials in a predetermined pattern comprising subjecting said body to a homogeneous bombardment of charged nuclear fragment particles having an energy level forming damage tracks which are more susceptible to etching by an etchant for said material than said undamaged material extending through said body, exposing a selective portion of said homogeneously bombarded body in an oxygen containing ambient to radiant energy selected from the group consisting of electromagnetic radiation having a wavelength shorter than 4,000 A.U. and high energy electrons for a period required to increase the solubility rate of said selectively exposed damage tracks, etching said body in an etchant for said material for a period sufficient to etch through those damage tracks lying within the selectively exposed portion of said body, said etch period being insufficient to etch through damage tracks lying outside said selectively exposed portion of said body, annealing the selectively perforate body for a sufficient period of time and at a temperature to effectively remove said damage tracks and to obliterate the alterEd solubility of the regions of said damage tracks and further etching said body in an etchant therefor to enlarge the perforations formed through said body during said initial etch of said body.

References Cited (Backward Citations)

US3335278A Cited
US3612871A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-12-02 1978-06-03 1978-12-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-12-02 1982-06-03 1982-12-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-12-02 1986-06-03 1986-12-03 $7700.00 Window Closed / Lapsed

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