Allylic oxidation of bicyclic hydrocarbons to alcohols and ketones
Abstract
Abstract WHEREIN R1, R2, R3, AND R4 ARE LOWER ALKYL OF ONE TO THREE CRBON ATOMS, X IS :CHR5-OR CHR5 CHR6-, Y IS -CHR7- OR -CHR7-CHR8-, AND R5, R6, R7 AND R8 ARE HYDROGEN OR LOWER ALKYL OF ONE TO THREE CARBON ATOMS, WITH OXYGEN IN THE PRESENCE OF A METAL ORGANIC CATALYST WHICH IS AN ACETATE, PROPIONTE, NAPHTHENATE OR ACETONYL ACETONATE OF NICKEL, COBALT, COPPER OR MANGANESE AT A TEMPERATURE FROM 50* TO 150*C TO PROVIDE A PRODUCT, SAID PRODUCT COMPOSED OF A MIXTURE OF COMPOUNDS HAVING A CARBOYL OR CARBINOL GROUP ADJACENT TO THE DOUBLE BOND ON THE Y-CONTAINING RING, AND RECOVERING THE COMPOUNDS. 1. A PROCESS FOR ALLYLIC OXIDATION WHICH COMPRISES REACTING A BICYCLIC COMPOUND HAVING THE FORMULA: X<(-C(-R1)(-R2)-C(-)-CH2-Y-CH2-C(-)-C(-R3)(-R4)-) WHEREIN THE C(-)''S ARE ATTACHED BY A DOUBLE BOND
Inventors
- 👤 J Hall
- 👤 L Lala
Bibliographic Details
Claims Analysis
Total Claims: 2References Cited (Backward Citations)
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