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US3847799A Expired / Lapsed US ⏱️ 0.0 years remaining

Conversion of black oil to low-sulfur fuel oil

Assignee: Universal Oil Products Co
•
Filing: 1972-10-10
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Granted: 1974-11-12
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Expires: 1992-10-10
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Abstract

Abstract An asphaltic, hydrocarbonaceous black oil, containing more than about 2.0 percent by weight of sulfur, is converted to a lowsulfur fuel oil in a plurality of catalytic conversion zones. The process is designed to afford series-flow of hydrogen through the system, and permits the relatively easier desulfurization of lower-boiling sulfurous compounds to be effected in a relatively less pure hydrogen atmosphere, while the more difficult desulfurization of higher-boiling sulfurous compounds is effected in a relatively concentrated hydrogen atmosphere. The fuel oil product has a sulfur concentration less than about 1.0 percent by weight, and concentrations of 0.5 percent by weight and less are made possible. There exists a significant decrease in the daily utility cost accompanied by a reduction in on-stream time which is lost due to unit shut-down necessitated by mechanical equipment failure.

Inventors

  • 👤 W Munro

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 19:25
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/02; C10G45/04; C10G2300/00; C10G2300/10; C10G2300/107

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 198 words
A PROCESS FOR PRODUCING A FUEL OIL, CONTAINING LESS THAN ABOUT 1.0 PERCENT BY WEIGHT OF SULFUR, FROM A SULFUROUS BLACK OIL CHARGE STOCK, WHICH PROCESS COMPRISES THE STEPS OF: A. REACTING SAID CHARGE STOCK WITH AN IMPURE HYDROGEN GAS CONTAINING HYDROGEN SULFIDE, IN A FRIST CATALYSTIC REACTION ZONE, AT DESULFURIZATION CONDITIONS SELECTED TO CONVERT LOWER BOILING SULFUROUS COMPOUNDS INTO HYDROGEN SULFIDE AND HYDROCARBONS; Bo SEPARATING AT LEAST A PORTION OF THE RESULTING FIRST REACTION ZONE EFFLUENT, IN A FRIST SEPARATION ZONE, AT SUBSTANTIALLY THE SAME TEMPERATURE AND PRESSURE, TO PROVIDE A FIRST PRINCIPALLY VAPOROUS PHASE AND A FIRST PRINCIPALLY LIQUID PHASE; C. SEPARATING AT LEAST A PORTION OF SAID FIRST VAPOROUS PHASE, IN A SECOND SEPARATION ZONE, AT SUBSTANTIALLY THE SAME PRESSURE AND A TEMPERATURE IN THE RANGE OF ABOUT 60*F. TO ABOUT 140*F., TO PROVIDE A SECOND PRINCIPALLY VAPOROUS PHASE AND A SECOND PRINCIPALLY LIQUID PHASE; D. REMOVING HYDROGEN SULFIDE FROM SAID SECOND VAPOROUS PHASE, AND REACTING AT LEAST A PORTION OF THE REMAINING RELATIVELY PURE HYDROGEN WITH AT LEAST A PORTION OF SAID PHASE, AND REACTING AT LEAST A PORTION OF SAID DESULFURIZATION CONDITIONS SELECTED TO CONVERT ADDITIONAL SULFUROUS COMPOUNDS INTO HYDROGEN SULFIDE AND HYDROCARBONDS;
Claim 2
Dependent Claim 198 words
A PROCESS FOR PRODUCING A FUEL OIL, CONTAINING LESS THAN ABOUT 1.0 PERCENT BY WEIGHT OF SULFUR, FROM A SULFUROUS BLACK OIL CHARGE STOCK, WHICH PROCESS COMPRISES THE STEPS OF: A. REACTING SAID CHARGE STOCK WITH AN IMPURE HYDROGEN GAS CONTAINING HYDROGEN SULFIDE, IN A FRIST CATALYSTIC REACTION ZONE, AT DESULFURIZATION CONDITIONS SELECTED TO CONVERT LOWER BOILING SULFUROUS COMPOUNDS INTO HYDROGEN SULFIDE AND HYDROCARBONS; Bo SEPARATING AT LEAST A PORTION OF THE RESULTING FIRST REACTION ZONE EFFLUENT, IN A FRIST SEPARATION ZONE, AT SUBSTANTIALLY THE SAME TEMPERATURE AND PRESSURE, TO PROVIDE A FIRST PRINCIPALLY VAPOROUS PHASE AND A FIRST PRINCIPALLY LIQUID PHASE; C. SEPARATING AT LEAST A PORTION OF SAID FIRST VAPOROUS PHASE, IN A SECOND SEPARATION ZONE, AT SUBSTANTIALLY THE SAME PRESSURE AND A TEMPERATURE IN THE RANGE OF ABOUT 60*F. TO ABOUT 140*F., TO PROVIDE A SECOND PRINCIPALLY VAPOROUS PHASE AND A SECOND PRINCIPALLY LIQUID PHASE; D. REMOVING HYDROGEN SULFIDE FROM SAID SECOND VAPOROUS PHASE, AND REACTING AT LEAST A PORTION OF THE REMAINING RELATIVELY PURE HYDROGEN WITH AT LEAST A PORTION OF SAID PHASE, AND REACTING AT LEAST A PORTION OF SAID DESULFURIZATION CONDITIONS SELECTED TO CONVERT ADDITIONAL SULFUROUS COMPOUNDS INTO HYDROGEN SULFIDE AND HYDROCARBONDS;
Claim 3
Dependent Claim 29 words
The process of claim 1 further characterized in that the desulfurization conditions in said first reaction zone include a pressure greater than that imposed upon said second reaction zone.
Claim 4
Dependent Claim 64 words
The process of claim 1 further characterized in that the desulfurization conditions, in said first and second reaction zones include a pressure from about 1,000 to about 3,000 psig., a hydrogen concentration in the range of about 1,000 to about 50, 000 scf./Bbl., a maximum catalyst bed temperature of from 600*F. to about 900*F. and a liquid hourly space velocity of 0.25 to 2.50.
Claim 5
Dependent Claim 25 words
The process of claim 1 further characterized in that at least a portion of said first liquid phase is recycled to said first reaction zone.
Claim 6
Dependent Claim 25 words
The process of claim 1 further characterized in that at least a portion of said third liquid phase is recycled to said second reaction zone.
Claim 7
Dependent Claim 39 words
The process of claim 1 further characterized in that said first and second reaction zones have therein a catalytic composite of a porous carrier material and at least one metallic component from the metals of Groups VI-B and VIII.

References Cited (Backward Citations)

US3193495A Cited
US3475327A Cited
US3717571A Cited
US3691152A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-11-11 1978-05-13 1978-11-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-11-11 1982-05-13 1982-11-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-11-11 1986-05-13 1986-11-12 $7700.00 Window Closed / Lapsed

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