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US3846374A Expired / Lapsed US ⏱️ 0.0 years remaining

1,2-azaphospholanes and their 2-oxides, 2-sulfides and salts and preparation thereof

Assignee: Wyeth Holdings LLC
•
Filing: 1971-05-27
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Granted: 1974-11-05
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Expires: 1991-05-27
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Abstract

Abstract WHEREIN R is alkyl of 1-8 carbon atoms or mononuclear aryl, R1, R2 and R, are hydrogen or lower alkyl, R4 is hydrogen, lower alkyl, phenyl or alkylphenyl, Q is oxygen or sulfur, m is 1 or zero and n is 1 or 2 and salts thereof are provided. They are effective depilatories and unhairing accelerators and can also be used as lubricating oil antioxidants and as flame retardants in plastics and textiles. They are prepared by reacting an appropriately substituted 3-aminopropylphosphine with a dialkyl or diaryl disulfide. Sulfides and oxides are produced by heating 1,2-azaphospholanes contained triavalent phosphorus with sulfur or oxygen or by using 3-aminopropylphosphine sulfides or oxides as starting materials. 1,2-Azaphospholanes and their 2-oxides and 2-sulfides having the formula

Inventors

  • 👤 C Farley
  • 👤 M Grayson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 12:35
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/547; C07F9/6564; C07F9/6581; C07F9/6584; C07F9/28; C07F9/50; C07F9/5031

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 13 words
A 1,2-AZAPHOSPHOLANE COMPOUND OR SALTS, CONSISTING OF A. A COMPOUND HAVING THE FORMULA
Claim 2
Dependent Claim 13 words
A 1,2-AZAPHOSPHOLANE COMPOUND OR SALTS, CONSISTING OF A. A COMPOUND HAVING THE FORMULA
Claim 3
Dependent Claim 16 words
An azaphospholane compound or salt defined by claim 1 wherein R1, R2 and R3 are hydrogen.
Claim 4
Dependent Claim 13 words
An azaphospholane compound or salt defined by claim 2 wherein R4 is hydrogen.
Claim 5
Dependent Claim 11 words
An azaphospholane salt defined by claim 3 wherein n is 2.
Claim 6
Dependent Claim 11 words
An azaphospholane salt defined by claim 3 wherein n is 1.
Claim 7
Dependent Claim 15 words
An azaphospholane compound defined by claim 3 wherein m is zero and R is alkyl.
Claim 8
Dependent Claim 32 words
A method of producing a 1,2-azaphospholane compound or salt defined by claim 1 which comprises the step of ring-closing an aminopropylphosphine selected from the group consisting of (a) 3-aminopropylphosphines of the forMula

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-11-04 1978-05-06 1978-11-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-11-04 1982-05-06 1982-11-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-11-04 1986-05-06 1986-11-05 $7700.00 Window Closed / Lapsed

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