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US3844927A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrodialytic recovery of acid and insoluble products from spent liquors

Assignee: Sybron Transition Corp
•
Filing: 1973-11-01
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Granted: 1974-10-29
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Expires: 1993-11-01
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Abstract

Abstract A multi-chambered electrodialytic apparatus and process are used to recover excess free acid and to regenerate and concentrate acid from spent liquors, e.g., spent pickle liquors. Sulfuric acid and hydrochloric acid are recovered and regenerated from their respective iron and steel pickle liquors along with oxides and hydroxides of iron. Efficiency for the recovery of the sulfuric or hydrochloric acids from the spent pickle liquor is greatly improved by using an electrodialytic apparatus having in sequence an anode chamber, at least one concentrating chamber, a spent liquor chamber and a cathode chamber. A sequestrant is used in the catholyte to prevent membrane fouling. Other values are recovered depending upon the make-up of the spent liquors.

Inventors

  • 👤 R Smith

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 05:33
CPC Classifications
B; B01; B01D; B01D61/00; B01D61/42; B01D61/44; B01D61/46; B01D61/461; C; C23; C23G; C23G1/00; C23G1/36

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 260 words
AN ELECTRODIALYTIC APPARATUS FOR THE REGENERATION AND CONCENTRATION OF ACID FROM A MIXTURE OF SAID ACID AND METAL IN SOLUTION COMPRISING, A FRAME HAVING IN SEQUENCE THEREIN AN ANODE CHAMBER ADAPTED TO CONTAIN CIRCULATING ANOLYTE AND HAVING AN ANODE WITH A SURFACE IN THE ANODE CHAMBER ADAPTED TO BE IN CONTACT WITH THE ANOLYTE; AT LEAST ONE CONCENTRATING CHAMBER ADAPTED TO CONTAIN CIRCULATING ELECTROLYTE; A SPENT LIQUOR CHAMBER ADAPTED TO CONTAIN A CIRCULATING MIXTURE OF SAID ACID AND METAL IN SOLUTION; A CATHODE CHAMBER ADAPTED TO CONTAIN CIRCULATING CATHOLYTE HAVING A CATHODE WITH A SURFACE IN THE CATHODE CHAMBER ADAPTED TO BE IN CONTACT WITH THE CATHOLYTE; ION PERMEABLE MEMBRANES SEPARATING SAID CHAMBERS, THE MEMBRANE SEPARATING THE CATHODE CHAMBER FROM THE SPENT LIQUOR CHAMBER BEING AN ANION PERMSELECTIVE MAMBRANE HAVING ONE SIDE DISPOSED IN THE CATHODE CHAMBER AND THE OTHER SIDE DISPOSED IN THE SPENT LIQUOR CHAMBER, THE ION PERMEABLE MEMBRANE SEPARATING THE ANODE CHAMBER AND THE CONCENTRATING CHAMBER HAVING ONE SIDE DISPOSED IN THE ANODE CHAMBER AND THE OTHER SIDE DISPOSED IN THE CONCENTRATING CHAMBER, AND THE ION PERMEABLE MEMBRANE SEPARATING THE CONCENTRATING CHAMBER AND THE SPENT LIQUOR CHAMBER BEING OF THE TYPE PERMITTING THE MIGRATION OF ANIONS AND HAVING ONE SIDE DISPOSED IN THE CONCENTRATING CHAMBER AND THE OTHER SIDE DISPOSED IN THE SPENT LIQUOR CHAMBER; AN INLET AND OUTLET MEANS FOR EACH CHAMBER AND MEANS FOR CIRCULATING SAID ANOLYTE, CATHOLYTE, ELECTROLYTE AND MIXTURE OF SAID ACID AND METAL IN SOLUTION THROUGH THE RESPECTIVE CHAMBERS; AND MEANS FOR IMPOSING A DIFFERENCE IN POTENTIAL ACROSS THE ANODE AND CATHODE.
Claim 2
Dependent Claim 260 words
AN ELECTRODIALYTIC APPARATUS FOR THE REGENERATION AND CONCENTRATION OF ACID FROM A MIXTURE OF SAID ACID AND METAL IN SOLUTION COMPRISING, A FRAME HAVING IN SEQUENCE THEREIN AN ANODE CHAMBER ADAPTED TO CONTAIN CIRCULATING ANOLYTE AND HAVING AN ANODE WITH A SURFACE IN THE ANODE CHAMBER ADAPTED TO BE IN CONTACT WITH THE ANOLYTE; AT LEAST ONE CONCENTRATING CHAMBER ADAPTED TO CONTAIN CIRCULATING ELECTROLYTE; A SPENT LIQUOR CHAMBER ADAPTED TO CONTAIN A CIRCULATING MIXTURE OF SAID ACID AND METAL IN SOLUTION; A CATHODE CHAMBER ADAPTED TO CONTAIN CIRCULATING CATHOLYTE HAVING A CATHODE WITH A SURFACE IN THE CATHODE CHAMBER ADAPTED TO BE IN CONTACT WITH THE CATHOLYTE; ION PERMEABLE MEMBRANES SEPARATING SAID CHAMBERS, THE MEMBRANE SEPARATING THE CATHODE CHAMBER FROM THE SPENT LIQUOR CHAMBER BEING AN ANION PERMSELECTIVE MAMBRANE HAVING ONE SIDE DISPOSED IN THE CATHODE CHAMBER AND THE OTHER SIDE DISPOSED IN THE SPENT LIQUOR CHAMBER, THE ION PERMEABLE MEMBRANE SEPARATING THE ANODE CHAMBER AND THE CONCENTRATING CHAMBER HAVING ONE SIDE DISPOSED IN THE ANODE CHAMBER AND THE OTHER SIDE DISPOSED IN THE CONCENTRATING CHAMBER, AND THE ION PERMEABLE MEMBRANE SEPARATING THE CONCENTRATING CHAMBER AND THE SPENT LIQUOR CHAMBER BEING OF THE TYPE PERMITTING THE MIGRATION OF ANIONS AND HAVING ONE SIDE DISPOSED IN THE CONCENTRATING CHAMBER AND THE OTHER SIDE DISPOSED IN THE SPENT LIQUOR CHAMBER; AN INLET AND OUTLET MEANS FOR EACH CHAMBER AND MEANS FOR CIRCULATING SAID ANOLYTE, CATHOLYTE, ELECTROLYTE AND MIXTURE OF SAID ACID AND METAL IN SOLUTION THROUGH THE RESPECTIVE CHAMBERS; AND MEANS FOR IMPOSING A DIFFERENCE IN POTENTIAL ACROSS THE ANODE AND CATHODE.
Claim 3
Dependent Claim 31 words
The apparatus according to claim 1 wherein the ion permeable membranes separating the anode chamber from the concentrating chamber and the concentrating chamber from the spent liquor chamber are non-selective membranes.
Claim 4
Dependent Claim 15 words
The apparatus according to claim 1 wherein the ion permeable membranes are anion permeable membranes.
Claim 5
Dependent Claim 35 words
The apparatus according to claim 1 wherein the ion permeable membranes separating the anode chamber from the concentrating chamber and the concentrating chamber from the spent liquor chamber are anion permeable membranes and non-selective membranes.
Claim 6
Dependent Claim 24 words
The apparatus according to claim 1 wherein the ion permeable membrane between the anode chamber and the concentrating chamber is a cation permeable membrane.
Claim 7
Dependent Claim 33 words
The apparatus according to claim 1 wherein the means for circulating the electrolyte through the concentrating chamber comprises suitable conduits for circulating the effluent of the spent liquor chamber in the concentrating chamber.
Claim 8
Dependent Claim 34 words
The apparatus according to claim 1 wherein the means for circulating the anolyte through the anode chamber comprises suitable conduits for circulating the effluent of at least one concentrating chamber to the anode chamber.
Claim 9
Dependent Claim 68 words
The apparatus according to claim 1 wherein the anode chamber comprises a first anode chamber having the anode surface therein and a second anode chamber adjacent said concentrating chamber, said first and second anode chambers separated by a non-selective membrane and communicating with each other by suitable conduit means to provide a sequential flow of anolyte contained therein from said second anolyte stream to said first anolyte stream.
Claim 10
Dependent Claim 63 words
The apparatus according to claim 1 wherein a plurality of concentrating chambers are interposed between said spent liquor chamber and said anode chamber and separated from each other and from said anode chamber by ion permeable membranes, said membrane separating the spent liquor chamber from the next adjacent concentrating chamber being an ion permeable membrane of the type permitting the migration of anions.

References Cited (Backward Citations)

US3227662A Cited
US3369906A Cited
US3394068A Cited
US3507764A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-10-28 1978-04-29 1978-10-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-10-28 1982-04-29 1982-10-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-10-28 1986-04-29 1986-10-29 $7700.00 Window Closed / Lapsed

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