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US3843740A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of aromatics

Assignee: ExxonMobil Oil Corp
•
Filing: 1973-11-14
•
Granted: 1974-10-22
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Expires: 1993-11-14
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Abstract

Abstract A modified process for aromatizing aliphatic feedstock to a principally aromatic containing liquid product and a principally light paraffin containing gas product which includes utilizing a two stage catalyst system in which the first stage is a ZSM-5 type synthetic aluminosilicate molecular sieve zeolite catalyst and the second stage is a mixture of such a ZSM-5 catalyst and a second molecular sieve (pore size about 4.5 to 6.7A) catalyst. The instant specification discloses a unique result flowing from this particular combination which is not achieved by either ZSM-5 or such second sieve alone, or by ZSM-5 mixed with such second sieve or with ZSM-5 followed by such second sieve; that is there is caused to be produced a liquid product having extremely small or no concentrations of C5+ aliphatics admixed with the aromatics content thereof. In a preferred embodiment hydrogen is added to the second stage catalyst zone whereby causing the gas product produced to be predominantly LPG.

Inventors

  • 👤 T Mitchell
  • 👤 D Whitehurst

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:09
CPC Classifications
C; C10; C10G; C10G35/00; C10G35/04; C10G35/06; C10G35/095; B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; B01J29/80; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/42; B01J29/405; B01J29/50

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 131 words
IN A PROCESS OF AROMATIZING A FEED HYDROCARBON COMPRISING AT LEAST ONE C2 TO 400*F. COMPONENT TO A PRODUCT COMPRISING A LIQID WHICH IS PREDOMINANTLY AROMATIC, AND GAS BY CONTACTING SUCH FEED IN A REACTION ZONE WITH A ZSM-5 TYPE SYNTHETIC ALUMINOSILICATE MOLECULAR SIEVE CATALYST AT ABOUT 800* TO 1500*F., A PRESSURE OF ABOUT 1 TO 35 ATMOSPHERES ABSOLUTE AND A SPACE VELOCITY EQUIVALENT OF ABOUT 1 TO 15 WHSV IN THE ABSENCE OF ADDED HYDROGEN UNDER SUCH COMBINATION OF CONDITIONS AS TO CONVERT AT LEAST 90 PERCENT OF THE AROMATIZABLE FEED TO A PRODUCT IN A YIELD OF AT LEAST 30 GRAMS OF AROMATICS PER 100 GRAMS OF NON-AROMATICS IN THE FEED; THE IMPROVEMENT, WHEREBY INCREASING THE PROPORTION OF AROMATICS IN SAID LIQUID PRODUCT, WHICH COMPRISES UTILIZING AS THE CATALYST
Claim 2
Dependent Claim 131 words
IN A PROCESS OF AROMATIZING A FEED HYDROCARBON COMPRISING AT LEAST ONE C2 TO 400*F. COMPONENT TO A PRODUCT COMPRISING A LIQID WHICH IS PREDOMINANTLY AROMATIC, AND GAS BY CONTACTING SUCH FEED IN A REACTION ZONE WITH A ZSM-5 TYPE SYNTHETIC ALUMINOSILICATE MOLECULAR SIEVE CATALYST AT ABOUT 800* TO 1500*F., A PRESSURE OF ABOUT 1 TO 35 ATMOSPHERES ABSOLUTE AND A SPACE VELOCITY EQUIVALENT OF ABOUT 1 TO 15 WHSV IN THE ABSENCE OF ADDED HYDROGEN UNDER SUCH COMBINATION OF CONDITIONS AS TO CONVERT AT LEAST 90 PERCENT OF THE AROMATIZABLE FEED TO A PRODUCT IN A YIELD OF AT LEAST 30 GRAMS OF AROMATICS PER 100 GRAMS OF NON-AROMATICS IN THE FEED; THE IMPROVEMENT, WHEREBY INCREASING THE PROPORTION OF AROMATICS IN SAID LIQUID PRODUCT, WHICH COMPRISES UTILIZING AS THE CATALYST
Claim 3
Dependent Claim 30 words
A process as claimed in claim 1 wherein said second stage catalyst comprises about 0.5 to 2 parts by weight of ZSM-5 per part by weight of said second sieve.
Claim 4
Dependent Claim 20 words
A process as claimed in claim 1 wherein the conversion in said first stage is at least about 80 percent.
Claim 5
Dependent Claim 48 words
A process as claimed in claim 1 wherein said second molecular sieve zeolite is at least one member selected from the group consisting of stilbite, laumontite, cancrinite, erionite, offretite, clinoptilolite, ferrierite, zeolite Alpha , zeolite N-A, zeolite ZK-21, zeolite ZK-22, zeolite T, zeolite L, dachiaradite, epistilbite and chabazite.
Claim 6
Dependent Claim 14 words
A process as claimed in claim 4 wherein said second molecular sieve is erionite.
Claim 7
Dependent Claim 36 words
A process as claimed in claim 1 wherein said second stage catalyst contains about 0.1 to 10 parts by weight of said ZSM-5 type of molecular sieve per part by weight of said second molecular sieve.
Claim 8
Dependent Claim 31 words
A process as claimed in claim 1 wherein said feed is selected from the group consisting of straight run naphtha, light naphtha, pyrolysis gasoline, reformate, raffinate, coker gasoline and mixtures thereof.
Claim 9
Dependent Claim 16 words
A process as claimed in claim 1 wherein said ZSM-5 type of molecular sieve is ZSM-5.
Claim 10
Dependent Claim 16 words
A process as claimed in claim 1 wherein hydrogen is fed to said second downstream catalyst.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-10-21 1978-04-22 1978-10-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-10-21 1982-04-22 1982-10-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-10-21 1986-04-22 1986-10-22 $7700.00 Window Closed / Lapsed

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