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US3843589A Expired / Lapsed US ⏱️ 0.0 years remaining

Stable pumpable slurries of ethylene oxide polymers

Assignee: Union Carbide Corp
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Filing: 1973-02-05
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Granted: 1974-10-22
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Expires: 1993-02-05
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Abstract

Abstract This invention relates to stable pumpable slurries of ethylene oxide polymers in liquid media, which comprise (a) particulate ethylene oxide polymer, having a density of about 1.15 to about 1.26, (b) an inert liquid vehicle which is a non-solvent for said ethylene oxide polymer and having a density of about 96.5 percent-103.5 percent of the density of said particulate ethylene oxide polymer. The vehicle is a mixture of two mutually soluble liquids or a solution of a solid in a liquid provided that it is a non-solvent for the ethylene oxide polymer and is miscible in water. The volume of liquid vehicle used per unit volume of polymer powder exceeds the void volume of the ethylene oxide polymer by at least 3 percent but by not more than 500 percent.

Inventors

  • 👤 L Wartman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 20:54
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/02; Y; Y10; Y10T; Y10T137/00; Y10T137/0318; Y10T137/0391

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 279 words
A STABLE SLURRY FORMULATION WHICH COMPRISES: A. PARTICULATE WATER-SOLUBLE ETHYLENE OXIDE POLYMER WHICH HAS AN AVERAGE MOLECULAR WEIGHT GREATER THAN ABOUT 500,000 AND A DENSITY OF ABOUT 1.15 TO ABOUT 1.26; B. AN INERT LIQUID VEHICLE BEING A MIXTURE OF AT LEAST TWO MUTUALLY SOLUBLE LIQUIDS, OR A SOLUTION OF A SOLID IN A LIQUID, ONE COMPONENT OF SAID MIXTURE HAVING A DENSITY LOWER THAN gIN A LIQUID, ONE COMPONENT OF SAID MIXTURE HAVING A DENSITY LOWER THAN THAT OF THE ETHYLENE OXIDE POLYMER POLYMER AND BEING SELECTED FROM THE GROUP CONSISTING OF PROPYLENE GLYCOL, 1,3BUTYLENE GLYCOL, 1,6-HEXYLENE GLYCOL, ETHYLENE GLYCOL, 2METHYL-PENTANE-2-4-DIOL, DIPROPYLENE GLYCOL, BUTANE DIOL, TO ABOUT 600, AND WATER-SOLUBLE POLY(ALKYLENE OXIDES) ABOUT 200 TO ABOUT 20,000 MOLECULAR WEIGHT AND THE OTHER COMPONENT OF SAID MIXTURE HAVING A DENSITY HIGHER THAN THAT OF THE ETHYLENE OXIDE POLYMER AND BEING SELECTED FROM THE GROUP CONSISTING OF GLYCERINE, 1, 2, 3, 4 BUT 5,6 HEXANE HEXOL, 1, 2, 3, 4 BUTANE TETROL, PENTAERYTHRITOL AND ETHYLENE CARBONATE CHARACTERIZED IN THAT THE DENSITY OF THE LIQUID VEHICLE IS FROM ABOUT 96.5 PERCENT TO ABOUT 103.5 PERCENT OF THE DENSITY OF SAID ETHYLENE OXIDE POLYMER, SAID VEHICLE BEING PRESENT AT A TOTAL VOLUME PER UNIT VOLUME OF POLYMER POWDER WHICH EXCEEDS THE VOID VOLUME OF SAID ETHYLENE OXIDE POLYMER BY AT LEAST 3 PERCENT BUT BY LESS THAN 500 PERCENT PREFERABLY BY AT LEAST 45 PERCENT BUT BY NOT MORE THAN 350 PERCENT, AND C. A THICKENING AGENT WHICH IS NON-REACTIVE WITH SAID ETHYLENE OXIDE POLYMER AND SAID LIQUID VEHICLE AND WHICH IS EMPLOYED IN AN AMOUNT OF ABOUT 0 PERCENT TO ABOUT 3 1/2 BASED ON LTHE WEIGHT OF THE SLURRY FORMULATION.
Claim 2
Dependent Claim 279 words
A STABLE SLURRY FORMULATION WHICH COMPRISES: A. PARTICULATE WATER-SOLUBLE ETHYLENE OXIDE POLYMER WHICH HAS AN AVERAGE MOLECULAR WEIGHT GREATER THAN ABOUT 500,000 AND A DENSITY OF ABOUT 1.15 TO ABOUT 1.26; B. AN INERT LIQUID VEHICLE BEING A MIXTURE OF AT LEAST TWO MUTUALLY SOLUBLE LIQUIDS, OR A SOLUTION OF A SOLID IN A LIQUID, ONE COMPONENT OF SAID MIXTURE HAVING A DENSITY LOWER THAN gIN A LIQUID, ONE COMPONENT OF SAID MIXTURE HAVING A DENSITY LOWER THAN THAT OF THE ETHYLENE OXIDE POLYMER POLYMER AND BEING SELECTED FROM THE GROUP CONSISTING OF PROPYLENE GLYCOL, 1,3BUTYLENE GLYCOL, 1,6-HEXYLENE GLYCOL, ETHYLENE GLYCOL, 2METHYL-PENTANE-2-4-DIOL, DIPROPYLENE GLYCOL, BUTANE DIOL, TO ABOUT 600, AND WATER-SOLUBLE POLY(ALKYLENE OXIDES) ABOUT 200 TO ABOUT 20,000 MOLECULAR WEIGHT AND THE OTHER COMPONENT OF SAID MIXTURE HAVING A DENSITY HIGHER THAN THAT OF THE ETHYLENE OXIDE POLYMER AND BEING SELECTED FROM THE GROUP CONSISTING OF GLYCERINE, 1, 2, 3, 4 BUT 5,6 HEXANE HEXOL, 1, 2, 3, 4 BUTANE TETROL, PENTAERYTHRITOL AND ETHYLENE CARBONATE CHARACTERIZED IN THAT THE DENSITY OF THE LIQUID VEHICLE IS FROM ABOUT 96.5 PERCENT TO ABOUT 103.5 PERCENT OF THE DENSITY OF SAID ETHYLENE OXIDE POLYMER, SAID VEHICLE BEING PRESENT AT A TOTAL VOLUME PER UNIT VOLUME OF POLYMER POWDER WHICH EXCEEDS THE VOID VOLUME OF SAID ETHYLENE OXIDE POLYMER BY AT LEAST 3 PERCENT BUT BY LESS THAN 500 PERCENT PREFERABLY BY AT LEAST 45 PERCENT BUT BY NOT MORE THAN 350 PERCENT, AND C. A THICKENING AGENT WHICH IS NON-REACTIVE WITH SAID ETHYLENE OXIDE POLYMER AND SAID LIQUID VEHICLE AND WHICH IS EMPLOYED IN AN AMOUNT OF ABOUT 0 PERCENT TO ABOUT 3 1/2 BASED ON LTHE WEIGHT OF THE SLURRY FORMULATION.
Claim 3
Dependent Claim 31 words
The stable slurry formulation of claim 1 wherein the density of said liquid vehicle is from about 98 percent to about 102 percent of the density of said ethylene oxide polymer.
Claim 4
Dependent Claim 26 words
The stable slurry formulation of claim 1 wherein the density of said liquid vehicle is about 100 percent of the density of said ethylene oxide polymer.
Claim 5
Dependent Claim 44 words
The stable slurry formulation of claim 1 wherein said particulate ethylene oxide polymer possesses an average molecular weight in the range from about 1,000,000 to about 12,000,000 and is of the group consisting of poly(ethylene oxide) and copolymers of ethylene oxide and olefin monoxides.
Claim 6
Dependent Claim 25 words
The stable slurry formulation of claim 4 wherein said ethylene oxide polymer is of the group consisting of poly(ethylene oxide) and ethylene oxide/propylene oxide copolymers.
Claim 7
Dependent Claim 15 words
The stable slurry formulation of claim 5 wherein said ethylene oxide polymer is poly(ethylene oxide).
Claim 8
Dependent Claim 44 words
The stable slurry formulation of claim 1 wherein said vehicle is present at a total volume per unit volume of polymer powder which exceeds the void volume of said ethylene oxide polymer by at least 45 percent but by not more than 350 percent.
Claim 9
Dependent Claim 19 words
The stable slurry formulation of claim 1 wherein the liquid vehicle is a mixture of propylene glycol and glycerol.
Claim 10
Dependent Claim 31 words
The stable slurry formulation of claim 8 wherein the density of said liquid vehicle is from about 98 percent to about 102 percent of the density of said ethylene oxide polymer.
Claim 11
Dependent Claim 157 words
A stable slurry formulation which comprises: a. poly(ethylene oxide) having an average molecular weight greater than about 500,000 and a density of about 1.15 to about 1.26; b. an inert liquid vehicle containing a mixture of propylene glycol and glycerol each of said propylene glycol and glycerol being employed in amounts such as to provide a density of said liquid vehicle which is from about 98 percent to about 102 percent of the density of said poly(ethylene oxide) said vehicle being present at a total volume per unit volume of polymer powder which exceeds the void volume of said ethylene oxide polymer by at least 45 percent but by not more than 350 percent; and c. a thickening agent which is non-reactive with said liquid vehicle and said poly(ethylene oxide) polymer and which is employed in an amount of from about 0 percent to about 3 1/2 percent based on the total weight of the slurry formulation.
Claim 12
Dependent Claim 157 words
A stable slurry formulation which comprises: a. poly(ethylene oxide) having an average molecular weight greater than about 500,000 and a density of about 1.15 to about 1.26; b. an inert liquid vehicle containing a mixture of propylene glycol and glycerol each of said propylene glycol and glycerol being employed in amounts such as to provide a density of said liquid vehicle which is from about 98 percent to about 102 percent of the density of said poly(ethylene oxide) said vehicle being present at a total volume per unit volume of polymer powder which exceeds the void volume of said ethylene oxide polymer by at least 45 percent but by not more than 350 percent; and c. a thickening agent which is non-reactive with said liquid vehicle and said poly(ethylene oxide) polymer and which is employed in an amount of from about 0 percent to about 3 1/2 percent based on the total weight of the slurry formulation.
Claim 13
Dependent Claim 23 words
The stable slurry formulation of claim 10 wherein the density of said vehicle is 100 percent of the density of said poly(ethylene oxide).
Claim 14
Dependent Claim 14 words
The stable slurry formulation of claim 11 wherein said thickening agent is colloidal silica.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-10-21 1978-04-22 1978-10-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-10-21 1982-04-22 1982-10-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-10-21 1986-04-22 1986-10-22 $7700.00 Window Closed / Lapsed

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