Silver halide emulsion containing ketomethylene photographic color-forming couplers

Claim 2

A LIGHT-SENSITIVE PHOTOGRAPHIC ELEMENT COMPRISING A PHOTOGRAPHIC SUPPORT HAVING COATED THEREON AT LEAST ONE PHOTOSENSITIVE SILVER HALIDE EMULSION LAYER CONTAINING AT LEAST ONE COLOR COUPLER CAPABLE OF FORMING A YELLOW DYE WHEN REACTED WITH OXIDIZED PRIMARY AMINO COLOR DEVELOPING AGENT, SAID COLOR COUPLER BEING REPRESENTED BY THE FORMULA:

Claim 3

A light-sensitive photographic element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing at least one color coupler capable of forming a yellow dye when reacted with oxidized primary amino color developing agent; said color coupler being represented by the formula:

Claim 4

A light-sensitive photographic element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing at least one color coupler capable of forming a yellow dye when reacted with oxidized primary amino color developing agent; said color coupler being represented by the formula:

Claim 5

A photographic element as in claim 2, wherein said element has the structure of formula (1) and Z is hydrogen, R is hydrogen and Y is an alkyl group.

Claim 6

A photographic element as in claim 2, wherein said element has the structure of formula (2) and Z is H or chlorine, R is H, R'' is H and R'''' is a substituted phenyl group.

Claim 7

A photographic element as in claim 2, wherein said element has the structure of formula (2) and n is O, R is H, R'' is H and R'''' is alkyl.

Claim 8

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-(carbethoxy) methyl-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 9

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-(carbethoxy) methyl-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 10

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-((4-ethoxyphenyl)carbamyl)methyl-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 11

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-((4-ethoxyphenyl)carbamyl)methyl-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 12

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-(carbethoxy)methyl-6-chloro-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 13

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-(carbethoxy)methyl-6-chloro-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 14

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-(phenylcarbamyl)methyl-6-chloro-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 15

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-(phenylcarbamyl)methyl-6-chloro-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 16

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-((2-chloro-5-methylphenyl)carbamyl)methyl-6-chloro-1,2,4-benzothiadiazine -1,1-dioxide.

Claim 17

A photographic light-sensitive element comprising a photographic support having coated thereon at least one photosensitive silver halide emulsion layer containing 3-((2-chloro-5-methylphenyl)carbamyl)methyl-6-chloro-1,2,4-benzothiadiazine -1,1-dioxide.

Claim 18

A light-sensitive silver halide emulsion containing a non-diffusible color coupler compound of the formula

Claim 19

A light-sensitive silver halide emulsion containing a non-diffusible color coupler compound of the formula

Claim 20

A light-sensitive, photographic silver halide emulsion containing a non-diffusible color coupler compound of the formula:

Claim 21

A light-sensitive, photographic silver halide emulsion containing a non-diffusible color coupler compound of the formula:

Claim 22

A light-sensitive, photographic silver halide emulsion as in claim 12, wherein said R'''' is a mono-substituted phenyl group or a di-substituted phenyl group in which the substituents are halo, alkyl, carboxyl or sulfonamido radicals.

Claim 23

A light-sensitive, photographic silver halide emulsion as in claim 12, wherein said R'''' is phenyl.

Claim 24

A light-sensitive, photographic silver halide emulsion as in claim 12, wherein said R'''' is an alkoxy group.

Claim 25

A light-sensitive, photographic silver halide emulsion as in claim 12, wherein said color coupler is 3-(carbethoxy) methyl-1, 2,4-benzothiadiazine-1,1-dioxide.

Claim 26

A light-sensitive, photographic silver halide emulsion as in claim 12, wherein said color coupler is 3-((4-ethoxyphenyl)carbamyl)methyl-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 27

A light-sensitive, photographic silver halide emulsion as in claim 12, wherein said color coupler is 3-(carbethoxy)methyl-6-chloro-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 28

A light-sensitIve, photographic silver halide emulsion as in claim 12, wherein said color coupler is 3-(phenylcarbamyl)methyl-6-chloro-1,2,4-benzothiadiazine-1,1-dioxide.

Claim 29

A light-sensitive, photographic silver halide emulsion as in claim 12, wherein said color coupler is 3-((2-chloro-5-methylphenyl)carbamyl)methyl-6-chloro-1,2,4-benzothiadiazine -1,1-dioxide.

Claim 30

A photographic element comprising a photographic support having coated thereon at least three emulsion layers containing photosensitive silver halide, each of said emulsion layers being sensitized to a different wavelength region of the visible spectrum, and one of said emulsion layers containing from about 25 to about 200 mg per square foot of said support of a ballasted, non-diffusible coupler compound capable of forming a yellow dye when reacted with 4-amino-3-methyl-N- Beta -(methane-sulfonamide) ethylaniline; said coupler compound being represented by the formula:

Claim 31

A photographic element comprising a photographic support having coated thereon at least three emulsion layers containing photosensitive silver halide, each of said emulsion layers being sensitized to a different wavelength region of the visible spectrum, and one of said emulsion layers containing from about 25 to about 200 mg per square foot of said support of a ballasted, non-diffusible coupler compound capable of forming a yellow dye when reacted with 4-amino-3-methyl-N- Beta -(methane-sulfonamide) ethylaniline; said coupler compound being represented by the formula: