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US3839189A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrorefined lube oil and process of manufacture

Assignee: Sunoco Inc
•
Filing: 1972-02-24
•
Granted: 1974-10-01
•
Expires: 1992-02-24
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Abstract

Abstract A novel hydrorefined oil of improved stability under severe conditions of use has a viscosity in the range of 150-12,000 SUS at 100*F., contains 10-44 percent gel aromatics and less than 10 p.p.m. (preferably less than 5 p.p.m., more preferably less than 2 p.p.m. of basic nitrogen). Typically, such an oil can contain more than 10 p.p.m. of total nitrogen (e.g., 15-600 p.p.m.) depending on the viscosity of the oil. Preferably the hydrorefined oil is naphthenic or aromatic (by VGC classification). The basic nitrogen in such severely hydrorefined lube oils (typically 15-400 p.p.m.) can be reduced to less than 10 p.p.m. by a process comprising contacting the hydrorefined oil with an acidic adsorbent (such as an adsorbent comprising an acid-activated clay), preferably at 50*-150*F., or by contacting the hydrorefined oils with sufficient quantities of a mineral acid (e.g. 90-120 percent H2SO4) followed by a basic wash finished by adsorbent contact (as with a fuller''s earth bleaching clay).

Inventors

  • 👤 I Mills
  • 👤 G Dimeler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 11:28
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/20; H01B3/22; C; C10; C10M; C10M1/00; C10M1/08; C10G; C10G2400/00; C10G2400/10; C10M2203/00; C10M2203/10; C10M2203/1006; C10M2203/102; C10M2203/1025; C10M2203/104; C10M2203/1045; C10M2203/106; C10M2203/1065; C10M2203/108; C10M2203/1085; C10M2207/00; C10M2207/02; C10M2207/023; C10M2207/026; C10N; C10N2040/00; C10N2040/14; C10N2040/16; C10N2040/17

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 62 words
A SEVERELY HYDROFINED OIL HAVING IMPROVED STABILITY UNDER SEVERE CONDITIONS OF USE AND HAVING A VISCOSITY IN THE RANGE OF 2050-12,000 SUS AT 100*F, SAID SEVERELY HYDROREFINED OIL CONTAINING 10-44 WT PERCENT GEL AROMATICS AND LESS THAN 10 PPM OF BASIC NITROGEN, AND WHEREIN SAID SEVERELY HYDROREFINED OIL HAS A VISCOSITY GRAVTIY CONSTANT IN THE RANGE OF AT LEAST 0.84 TO 0.92.
Claim 2
Dependent Claim 62 words
A SEVERELY HYDROFINED OIL HAVING IMPROVED STABILITY UNDER SEVERE CONDITIONS OF USE AND HAVING A VISCOSITY IN THE RANGE OF 2050-12,000 SUS AT 100*F, SAID SEVERELY HYDROREFINED OIL CONTAINING 10-44 WT PERCENT GEL AROMATICS AND LESS THAN 10 PPM OF BASIC NITROGEN, AND WHEREIN SAID SEVERELY HYDROREFINED OIL HAS A VISCOSITY GRAVTIY CONSTANT IN THE RANGE OF AT LEAST 0.84 TO 0.92.
Claim 3
Dependent Claim 16 words
A hydrorefined oil according to claim 1 and containing more than 10 p.p.m. of total nitrogen.
Claim 4
Dependent Claim 15 words
A hydrorefined oil according to claim 1 and containing from 15-600 p.p.m. of total nitrogen.
Claim 5
Dependent Claim 16 words
A hydrorefined oil according to claim 3 and containing less than 2 p.p.m. of basic nitrogen.
Claim 6
Dependent Claim 22 words
A hydrorefined oil according to claim 1 wherein said hydrorefined oil has a viscosity in the range of 8,100-12,000 SUS at 100*F.
Claim 7
Dependent Claim 22 words
A hydrorefined oil according to claim 1 wherein said hydrorefined oil has a viscosity in the range of 2050-2950 SUS at 100*F.
Claim 8
Dependent Claim 81 words
Process for preparing a hydrorefined oil containing less than 10 ppm of basic nitrogen, said process comprising obtaining a severely hydrorefined oil having a viscosity-gravity constant of at least 0.84, a viscosity at 100*F in the range of 2050-12,000 SUS and containing more than 10 ppm of basic nitrogen, and contacting said oil with an acidic adsorbent or a mineral acid and recovering as a product of said contact a severely hydrorefined oil containing less than 10 ppm of basic nitrogen.
Claim 9
Dependent Claim 81 words
Process for preparing a hydrorefined oil containing less than 10 ppm of basic nitrogen, said process comprising obtaining a severely hydrorefined oil having a viscosity-gravity constant of at least 0.84, a viscosity at 100*F in the range of 2050-12,000 SUS and containing more than 10 ppm of basic nitrogen, and contacting said oil with an acidic adsorbent or a mineral acid and recovering as a product of said contact a severely hydrorefined oil containing less than 10 ppm of basic nitrogen.
Claim 10
Dependent Claim 21 words
Process according to claim 7 wherein the basic nitrogen content of said severely hydrorefined oil is determined prior to said contacting.
Claim 11
Dependent Claim 18 words
Process according to claim 7 and wherein said contacting is with an adsorbent comprising an acidactivated adsorbent clay.
Claim 12
Dependent Claim 17 words
Process according to claim 8 wherein said contacting is at a temperature in the range of 50*-150*F.
Claim 13
Dependent Claim 21 words
Process according to claim 9 and wherein said adsorbent comprises acid-activated adsorbent clay and a naturally occurring fuller''s earth bleaching clay.
Claim 14
Dependent Claim 16 words
Process according to claim 10 and wherein said naturally occurring fuller''s earth bleaching clay is attapulgite.
Claim 15
Dependent Claim 13 words
Process according to claim 7 wherein said mineral acid is 90-120 percent H2SO4.
Claim 16
Dependent Claim 23 words
A process according to claim 7 wherein the total nitrogen in said hydrorefined oil prior to said contacting is greater than 50 p.p.m.

References Cited (Backward Citations)

CA743525A Cited
US3406111A Cited
US3232863A Cited
US3145161A Cited
US3224955A Cited
US3434994A Cited
US3196102A Cited
US3502567A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-09-30 1978-04-01 1978-10-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-09-30 1982-04-01 1982-10-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-09-30 1986-04-01 1986-10-01 $7700.00 Window Closed / Lapsed

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