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US3839055A Expired / Lapsed US ⏱️ 0.0 years remaining

Tetrasilicic mica glass-ceramic article

Assignee: Corning Glass Works
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Filing: 1973-03-14
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Granted: 1974-10-01
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Expires: 1993-03-14
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Abstract

Abstract This invention relates to tetrasilicic fluorine mica glassceramic compositions consisting essentially, in weight percent on the oxide basis as calculated from the batch, of about 45-70 percent SiO2, 8-20% MgO, 8-15% MgF2, a total of 5-35% (R2O + RO), wherein R20 ranges from about 5-25% and consists of one or more oxides selected in the indicated proportions from the group consisting of 0-20% K2O, 0-23% Rb2O, and 0-25% Cs2O, and wherein RO ranges from 0-20% and consists of one or more oxides selected from the group consisting of SrO, BaO, and CdO, a total of 0-10% of oxides selected from the group consisting of As2O5 and Sb2O5, and up to about 5% of glass colorants. Tetrasilicic mica glassceramic articles produced from these compositions exhibit good machinability with steel tools, good mechanical strength, moderate thermal expansion, and good chemical durability. The use of the optional constituents As2O5, Sb2O5, and the glass colorants permits the production of translucent glass-ceramics and glass-ceramics having the appearance of marble.

Inventors

  • 👤 D Grossman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:11
CPC Classifications
C; C03; C03C; C03C10/00; C03C10/16; Y; Y10; Y10S; Y10S106/00; Y10S106/03

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 166 words
A GLASS-CERAMIC ARTICLE CONSISTING ESSENTIALLY OF TETRASILICIC FLUORMICA CRYSTALS DISPERSED IN A GLASSY MATRIX, SAID CRYSTALS CONSTITUTING AT LEAST 50% BY VOLUME OF THE ARTICLE AND BEING ESSENTIALLY FREE OF AL+3 AND B+3 AS CRYSTAL CONSTITUENTS, AND SAID ARTICLE BEING FORMED BY THE CRYSTALLIZATION IN SITU OF A GLASS BODY CONSISTING ESSENTIALLY, IN WEIGHT PERCENT ON THE OXIDE BASIS AS CALCULATED FROM THE BATCH, OF ABOUT 55-65% SIO2, 12-20% MGO, 9-13% MGF2, 5-35% (R2O + RO) WHEREIN R2O RANGES FROM 5-25% AND CONSISTS OF AT LEAST ONE OXIDE SELECTED IN THE INDICATED PROPORTION FROM THE GROUP CONSISTING OF 0-20% K2O, 0-23% RB2O AND 0-25% CS2O, AND WHEREIN RO RANGES FROM 0-20% AND CONSISTS OF AT LEAST ONE OXIDE SELECTED FROM THE GROUP CONSISTING OF SRO, BAO AND CDO, 0-10% TOTAL OF OXIDES SELECTED FROM THE GROUP CONSISTING OF AS2O5 AND SB2O5, AND 0-2% TOTAL OF GLASS COLORANTS SELECTED FROM THE GROUP CONSISTING OF K2CR2O7, KMNO4, NIO, CUO, CR2O3, FE2O3, FEO, V2O5, COO, ND2O3 AND ELEMENTAL AU.
Claim 2
Dependent Claim 166 words
A GLASS-CERAMIC ARTICLE CONSISTING ESSENTIALLY OF TETRASILICIC FLUORMICA CRYSTALS DISPERSED IN A GLASSY MATRIX, SAID CRYSTALS CONSTITUTING AT LEAST 50% BY VOLUME OF THE ARTICLE AND BEING ESSENTIALLY FREE OF AL+3 AND B+3 AS CRYSTAL CONSTITUENTS, AND SAID ARTICLE BEING FORMED BY THE CRYSTALLIZATION IN SITU OF A GLASS BODY CONSISTING ESSENTIALLY, IN WEIGHT PERCENT ON THE OXIDE BASIS AS CALCULATED FROM THE BATCH, OF ABOUT 55-65% SIO2, 12-20% MGO, 9-13% MGF2, 5-35% (R2O + RO) WHEREIN R2O RANGES FROM 5-25% AND CONSISTS OF AT LEAST ONE OXIDE SELECTED IN THE INDICATED PROPORTION FROM THE GROUP CONSISTING OF 0-20% K2O, 0-23% RB2O AND 0-25% CS2O, AND WHEREIN RO RANGES FROM 0-20% AND CONSISTS OF AT LEAST ONE OXIDE SELECTED FROM THE GROUP CONSISTING OF SRO, BAO AND CDO, 0-10% TOTAL OF OXIDES SELECTED FROM THE GROUP CONSISTING OF AS2O5 AND SB2O5, AND 0-2% TOTAL OF GLASS COLORANTS SELECTED FROM THE GROUP CONSISTING OF K2CR2O7, KMNO4, NIO, CUO, CR2O3, FE2O3, FEO, V2O5, COO, ND2O3 AND ELEMENTAL AU.
Claim 3
Dependent Claim 78 words
A glass-ceramic article consisting essentially of tetrasilicic fluormica crystals dispersed in a glassy matrix, said crystals constituting at least 50% by volume of the article and being essentially free of Al 3 and B 3 as crystal constituents, and said article being formed by crystallization in situ of a glass body consisting essentially, in weight percent on the oxide basis as calculated from the batch, of about 55-65% SiO2, 12-20% MgO, 9-13% MgF2, 7-18% K2O and 0.5-8% As2O5.
Claim 4
Dependent Claim 78 words
A glass-ceramic article consisting essentially of tetrasilicic fluormica crystals dispersed in a glassy matrix, said crystals constituting at least 50% by volume of the article and being essentially free of Al 3 and B 3 as crystal constituents, and said article being formed by crystallization in situ of a glass body consisting essentially, in weight percent on the oxide basis as calculated from the batch, of about 55-65% SiO2, 12-20% MgO, 9-13% MgF2, 7-18% K2O and 0.5-8% As2O5.
Claim 5
Dependent Claim 38 words
A glass-ceramic article according to claim 2 which additionally contains from a trace to about 2% of glass colorants selected from the group consisting of K2Cr2O7, KMnO4, NiO, CuO, Cr2O3, Fe2O3, FeO, V2O5, CoO, Nd2O3 and elemental Au.

References Cited (Backward Citations)

GB848447A Cited
US3022179A Cited
FR1268125A Cited
US3756838A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1977-09-30 1978-04-01 1978-10-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1981-09-30 1982-04-01 1982-10-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1985-09-30 1986-04-01 1986-10-01 $7700.00 Window Closed / Lapsed

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